Toagosei Company, Ltd.

Panasonic Energy Co., Ltd.

Taogosei Co., Ltd.

Toagosei., Ltd.

Hideo Matsuzaki

Naohiko Saito

Akihiro Gotou

Atsushi Nishiwaki

Takashi Hasegawa

Takaharu Morikawa

Nobuhiro Sakitani

Sho Urata

Akitsugu Shibata

Shinji Hibino

Tomotaka Mizuno

Eiichi Okazaki

Michihiro Kaai

Keiji Maeda

Tomoko Nakano

Kinuko Ogura

Morikatsu Matsunaga

Shinya Kumagai

Kuniniko Mizotani

Kinuko Fujikura

A water-based binder for a non-aqueous electrolyte secondary battery. A binder for a non-aqueous electrolyte secondary battery electrode, includes a crosslinked polymer having a carboxyl group or a salt thereof, and the crosslinked polymer includes a structural unit derived from an ethylenically unsaturated carboxylic acid monomer; and a structural unit derived from a macromonomer including at least one compositional monomer selected from compounds represented by following formula (1):[C1]HC═CR—X  formula (1)

Binder for nonaqueous electrolyte secondary battery electrode

A binder for a non-aqueous electrolyte secondary battery electrode that includes a crosslinked polymer having a carboxyl group or a salt thereof, wherein the crosslinked polymer includes 50% by mass or more and 100% by mass or less structural unit derived from an ethylenically unsaturated carboxylic acid monomer relative to all structural units, wherein a total amount of the ethylenically unsaturated carboxylic acid monomer and a salt thereof in terms of a non-neutralized form which is converted from the ethylenically unsaturated carboxylic acid monomer and a salt thereof relative to a total amount of the crosslinked polymer and a salt thereof is 5.0% by mass or less.

A method for manufacturing polymer fine particles having a narrow particle diameter distribution without any particular limitations on the raw materials and the like. To achieve this purpose, this method for manufacturing polymer fine particles includes polymerizing a vinyl monomer using a dispersion polymerization method, wherein the amount of water in the reaction liquid in the polymerizing is no more than 30,000 ppm, the reactor for carrying out the polymerizing is a stirring tank reactor, the stirring blade attached to the stirring rotation shaft of the stirring tank reactor is one type selected from a large wide blade and a large lattice blade, and the tip speed of the stirring blade is no more than 1.0 m/sec.

Polymer fine particles manufacturing method

A binder for a nonaqueous electrolyte secondary battery electrode and use thereof are described. The binder contains a crosslinked polymer or salt thereof, the crosslinked polymer having an ethylenically unsaturated carboxylic acid and a crosslinkable monomer in constituent monomers thereof, or salt thereof, wherein the crosslinked polymer includes the ethylenically unsaturated carboxylic acid in an amount of 20 to 99.95 mass % of the total constituent monomers, and the crosslinked polymer includes at least one compound selected from the group made of trimethylolpropane diallyl ether and trimethylolpropane triallyl ether as the crosslinkable monomer.

Crosslinked polymer binder from crosslinkable monomer for nonaqueous electrolyte secondary battery and use thereof

A binder for a nonaqueous electrolyte secondary battery electrode, containing a crosslinked polymer or salt thereof having a carboxyl group and a use thereof, and a method of manufacturing the polymer or salt. The polymer has a structural unit derived from an ethylenically unsaturated carboxylic acid monomer in an amount of 50 to 99 mass % of total structural units and a structural unit derived from a nonionic ethylenically unsaturated monomer in an amount of 1 to 50 mass % of the total structural units, the monomer is a compound having a substituent with a carbon atom number of 6 or more, and a particle diameter of the crosslinked polymer is 0.1 to 7.0 &#x3bc;m in a volume-based median diameter when the crosslinked polymer is neutralized to a neutralization degree of 80 to 100 mol %, subjected to water swelling in water, and then dispersed in a 1 mass % NaCl aqueous solution.

Binder for nonaqueous electrolyte secondary battery electrode, manufacturing method thereof, and use thereof

Provided is a binder for a nonaqueous electrolyte secondary battery electrode. The binder contains a crosslinked polymer having a carboxyl group, or salt thereof, a use therefor, and a method for manufacturing a carboxyl group-containing crosslinked polymer or salt thereof for use in the binder. The crosslinked polymer contains a structural unit derived from an ethylenically unsaturated carboxylic acid monomer in the amount of 50 to 100 mass % of total structural units, and after the crosslinked polymer neutralized to a degree of a neutralization of 80 to 100 mol % has been subjected to water swelling in water and then dispersed in a 1 mass % NaCl aqueous solution, the particle diameter thereof is 0.1 to 7.0 &#x3bc;m in a volume-based median diameter.

Binder for nonaqueous electrolyte secondary battery electrode, manufacturing method therefor and use therefor

An electrode mixture layer composition for a nonaqueous electrolyte secondary battery contains an active material, water and a binder. The binder contains a crosslinked polymer of a monomer component including an ethylenically unsaturated carboxylic acid monomer, and a salt thereof. The crosslinked polymer is a polymer that is crosslinked with allyl methacrylate, and an amount of the allyl methacrylate used is 0.1 to 2.0 parts by weight relative to total 100 parts by weight of non-crosslinking monomers, and a content of the crosslinked polymer and salt thereof is 0.5% to 5.0% by weight of the active material.

Electrode mixture layer composition for nonaqueous electrolyte secondary battery, manufacturing method thereof and use therefor

A nonaqueous electrolyte secondary battery electrode is obtained by coating and drying a slurry including an active material, a crosslinking water-absorbing resin particle, a binder, and water, on a current collector surface to form a mixture layer and then compressing the mixture layer, and a nonaqueous electrolyte secondary battery includes the electrode, a separator, and a nonaqueous electrolytic solution.

Electrode for nonaqueous electrolyte secondary battery, method of manufacturing same, and nonaqueous electrolyte secondary battery

The present invention relates to an additive for use in the molding of a ceramic material, which exhibits satisfactory water absorption performance in a ceramic green ceramic clay, can highly achieve both high fluidability and low loading performance during extrusion molding and high shape-retaining performance after extrusion at the same time, and comprises polymer microparticles. This additive for use in the molding of a ceramic material comprises polymer microparticles, is characterized in that the polymer microparticles have an average particle size between 10 and 150 &#x3bc;m when the polymer microparticles are swollen with ion exchange water until the swollen polymer microparticles reach a saturated state and can absorb 10-60 mL/g of ion exchange water under ordinary pressure, and is also characterized in that an aqueous dispersion prepared by dispersing 1 part by mass of the polymer microparticles in 110 parts by mass of ion exchange water has an electrical conductivity of 1500 &#x3bc;S/cm or less at 25&#xb0; C.

Additive for molding of ceramic material

A process for producing polymer microparticles by suspension polymerization of a vinyl-based monomer in which, when polymer microparticles are produced by suspension polymerization of a vinyl-based monomer, a macromonomer having a radically polymerizable unsaturated group at a terminus of a vinyl-based monomer-derived polymer is used as a dispersion stabilizer.

Process for producing polymer microparticles

The object of the present invention is to provide a process for producing a high-quality polymer microparticle having uniform particle size of the order of several micrometers to tens of micrometers by inverse suspension polymerization at high productivity while keeping excellent dispersion stability without causing aggregation among particles. The process is one for the production of polymer microparticles by inverse polymerization of a vinyl monomer and is characterized in that the inverse suspension polymerization is conducted dividing at least two steps, an oil-soluble oxidizing agent and a water-soluble reducing agent are used as a polymerization initiator, and the oil-soluble oxidizing agent is fed after the water-soluble reducing agent is fed.

Process for the production of polymer microparticles

The object of the present invention is to provide a process for producing high-quality polymer microparticles having uniform particle size of the order of several micrometers to tens of micrometers by inverse suspension polymerization at high productivity while keeping excellent dispersion stability without causing aggregation among particles. The process is one for the production of polymer microparticles by inverse polymerization of a vinyl monomer and is characterized in that an oil-soluble oxidizing agent and a water-soluble reducing agent are used as a polymerization initiator and the oil-soluble oxidizing agent is fed after the water-soluble reducing agent is fed.

A process for producing high-quality polymer microparticles having uniform particle size of the order of several micrometers to tens of micrometers by inverse suspension polymerization at high productivity while keeping excellent dispersion stability without causing aggregation among particles. The inverse suspension polymerization involves a vinyl monomer and is performed in at least two steps. A water-soluble oxidizing agent and a water-soluble reducing agent are used as a polymerization initiator, and the water-soluble reducing agent is fed after the water-soluble oxidizing agent is fed.

The object of the present invention is to provide a process for producing high-quality polymer microparticles having uniform particle size of the order of several micrometers to tens of micrometers by inverse suspension polymerization at high productivity while keeping excellent dispersion stability without causing aggregation among particles. The process is one for the production of polymer microparticles by inverse suspension polymerization of a vinyl monomer and includes steps of preparing in a dispersing tank a water-in-oil (W/O) type emulsion in which an organic solvent is a continuous phase and an aqueous solution of a vinyl-based monomer is a dispersing phase, and conducting the inverse suspension polymerization while feeding the water-in-oil (W/O) type emulsion to a continuous stirred tank reactor.

Crosslinkable resin compositions that are cured easily by irradiation with active energy beams and particularly cured quickly with ultraviolet ray are provided, which comprises a polymer containing a maleimido group and an ethylenically unsaturated group. The composition may be an aqueous composition. They provide cured films which are excellent in durability, free from coloring and odors, and also excellent in abrasion resistance, adhesion to substrates, surface smoothness, and chemical resistance.

Growing community of inventors

Nagoya, Japan

Hideo Matsuzaki