Kao Soap Company, Ltd.

Narumi China Corporation

Hidemasa Ohmura

Kazuo Matsuda

Takeyo Sakai

Hirakazu Aritaki

Yukihisa Niimi

Junzo Fukuda

Toshio Sato

Katsuhiko Kita

Masahiro Saito

Sho Suzuki

Takeya Sakai

A color deepening agent comprises an aqueous resin composition obtained by polymerizing a monomer having a polymerizable unsaturated bond, in the presence of a polyurethane emulsion having a thermosetting reactivity, the refractive index of a dry film of said aqueous resin composition being lower than 1.50.

Color deepening agent

Green ceramic tapes are prepared which comprise a finely divided ceramic powder and a water-compatible polyurethane resin binder. The green tapes are prepared by casting a water-based slip containing the ceramic powder and the water-compatible polyurethane resin binder in the form of the tape and then drying the formed tape. The drying is preferably conducted in two stages, in the first of which a relatively humid atmosphere is maintained.

Green ceramic tapes and method of producing them

A curable film-forming cationic polyurethane emulsion containing a compound having an epoxide group, as a curing agent.

Aqueous cationic polyurethane emulsion with glycidyl ether curing agent

An aqueous amphoteric polyurethane emulsion is prepared by reacting an isocyanate-terminated urethane prepolymer with an excess of a polyalkylene polyamine to form a polyurethane-urea-polyamine; reacting a portion of the free amino groups contained in the resulting product with a blocked polyisocyanate having one free isocyanate group; rendering the remaining amino groups contained in the resulting product amphoteric either (I) by reacting said amino groups with a compound selected from the group consisting of 1,3-propane sultone, 1,4-butane sultone, .beta.-propiolactone, .gamma.-butyrolactone, .epsilon.-caprolactone, .delta.-valerolactone and a monohalogenated sodium carboxylate having the formula

Aqueous amphoteric polyurethane having blocked NCO groups and process

An aqueous anionic polyurethane emulsion is prepared by reacting an isocyanate-terminated urethane prepolymer with an excess of a polyalkylene polyamine thereby to form a polyurethane-urea-polyamine, reacting a portion of the free amino groups of said polyurethane-urea-polyamine with a blocked polyisocyanate having a single free isocyanate group, reacting the resulting product with a cyclic dicarboxylic acid anhydride, and mixing the resulting product with an aqueous solution of a basic substance.

Anionic aqueous polyurethane having blocked NCO groups and process

Aqueous cationic polyurethane emulsions are prepared by reacting an isocyanate-terminated urethane prepolymer with an excess of a polyalkylene polyamine to form a polyurethane-urea-polyamine, and then partially reacting the free amino groups in said product with a blocked polyisocyanate having a single free isocyanate group, followed by mixing with an aqueous solution of an acid.

Aqueous cationic polyurethane having blocked NCO groups and process

An aqueous polyurethane emulsion is prepared by reacting a polyhydroxyl component containing 15 to 80% by weight of a polyoxyethylene glycol having a molecular weight of 200 to 10,000 with an excess of an organic polyisocyanate to obtain an isocyanate-terminated urethane prepolymer, reacting that prepolymer with an excess of a polyalkylene polyamine thereby to form a polyurethane-urea-polyamine, reacting the free amino groups in the polyurethane-urea-polyamine with a blocked polyisocyanate having a single free isocyanate group, and mixing the resulting product with water, or reacting said resulting product with a cyclic dicarboxylic acid anhydride followed by mixing with water.

Aqueous polyurethane having blocked NCO groups and process

A process for the preparation of cationic resin aqueous emulsions useful for treating fiber-containing articles, comprising reacting an isocyanate-terminated urethane prepolymer with an excess of a polyalkylene-polyamine to form a polyurethane-urea-polyamine, reacting a part of the amino groups in the thus-formed polyurethane-urea-polyamine with a compound selected from the group consisting of alkyl isocyanates having an alkyl group of 12 to 22 carbon atoms, acyl chlorides having an alkyl group of 12 to 22 carbon atoms and .alpha.-olefin epoxides having 12 to 22 carbon atoms, thereby to introduce a long-chain alkyl group into the molecule of the polyurethane-urea-polyamine, and mixing the alkyl-containing polyurethane-urea-polyamine with an aqueous solution of an acid thereby to convert the remaining amino groups to cations.

Process for preparation of cationic resin aqueous emulsions

A process for preparing non-ionic polyurethane emulsions comprising chain-extending (A) an isocyanate-terminated urethane prepolymer (formed by reaction of a polyhydroxyl reactant having a molecular weight of 200 to 10,000 and a stoichiometric excess of a polyisocyanate), with (B) a polyalkylene polyamine as chain extending compound, thereby to form a polyurethane-urea polyamine product, mixing the said polyamine product with water or reacting the product with a cyclic dicarboxylic acid anhydride and then mixing the reaction product with water; said process being characterized in that a water-soluble polyoxyethylene glycol comprises 15 to 80% by weight of the polyhydroxyl reactant, and the said polyalkylene polyamine used as the chain-extending compound has at least two primary or secondary amino groups and a functional group having the formula --CH(OH)--CH.sub.2 X in which X is Cl or Br.

Process for preparing non-ionic polyurethane emulsions

A process for the preparation of amphoteric resinous aqueous emulsions useful for the treatment of fiber-containing products, comprising reacting an isocyanate-terminated urethane prepolymer with an excess of a polyalkylene polyamine to form a polyurethane-urea-polyamine, then partially reacting the amino groups in the polyurethane-urea-polyamine with a compound selected from the group consisting of alkyl isocyanates in which the alkyl group has 12 to 22 carbon atoms and alpha-olefin epoxides having 12 to 22 carbon atoms, thereby to introduce a long-chain alkyl group into the molecule, reacting the thus-formed product having some unreacted amino groups with a member selected from the group consisting of 1,3-propanesultone, 1,4-butanesultone, .beta.-propiolactone, .epsilon.-caprolactone and .delta.-valerolactone, thereby to render the polymer amphoteric, and mixing the resulting polymer with water.

Process for preparation of amphoteric resinous aqueous emulsions

A process for the preparation of anionic thermosetting resin emulsions, comprising the steps of (1) reacting an isocyanate-terminated urethane prepolymer with an excess of a polyalkylene-polyamine to form a polyurethane-urea-polyamine, (2) then reacting the thus-formed polyurethane-urea-polyamine with an epihalohydrin, (3) reacting the resulting reaction product of step (3) with a cyclic dicarboxylic acid anhydride, and then (4) mixing the resulting reaction product of step (3) with an aqueous solution of a basic substance to form an emulsion.

Process for the preparation of anionic thermosetting resin emulsions

A process for preparing non-ionic polyurethane emulsions comprising chain-extending (A) an isocyanate-terminated urethane prepolymer (formed by reaction of a polyhydroxyl reactant having a molecular weight of 200 to 10,000 and a stoichiometric excess of a polyisocyanate), with (B) a polyalkylene polyamine as chain extending compound, thereby to form a polyurethane-urea polyamine product, mixing the said polyamine product with water or reacting the product with a cyclic dicarboxylic acid anhydride and then mixing the reaction product with water; said process being characterized in that a water-soluble polyoxyethylene glycol comprises 15 to 80% by weight of the polyhydroxyl reactant, and the said polyalkylene polyamine used as the chain-extending compound has at least two primary or secondary amino groups and a function group having the formula --CH(OH)--CH.sub.2 X in which X is Cl or Br.

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Wakayama, Japan

Hidemasa Ohmura