Showa Denko K.k.

Hitachi, Ltd.

Shin-etsu Chemical Co., Ltd.

Kawaken Fine Chemicals Co., Ltd.

Hideki Sakurai

Masaki Fushimi

Shigenobu Miyake

Tetuo Nakajo

Hisayoshi Yanagihara

Hitoshi Yokono

Mitsuo Nakatani

Hitoshi Oka

Tokio Isogai

Takeshi Hiiro

Fumihiko Kondo

Disclosed is a catalyst composition for use in the polymerization of olefins, which is comprised of (a) a catalyst component containing magnesium, titanium, a halogen, and an ingredient derived from a keto-ester compound, and (b) an organic aluminum compound. The catalyst activity and capability of providing a highly stereoregular polymer are enhanced by preparing the catalyst component (a) by a process wherein, during or after the formation of a solid catalyst component containing magnesium, titanium, and a halogen, the solid catalyst component is treated with a keto-ester of the formula: ##STR1## wherein R.sup.1, R.sup.2 and Z represent a hydrocarbon group.

Catalyst, process for preparation of same and process for polymerization

Catalyst, process for preparation of same, and process for

Disclosed is a catalyst composition for use in the polymerization of olefins, which is comprised of (a) a catalyst component containing magnesium, titanium, a halogen, and an ingredient derived from an ester compound, and (b) an organic aluminum compound. The catalyst activity and capability of providing a highly stereroregular polymer are enhanced by preparing the catalyst component (a) by a process wherein, during or after the formation of a solid catalyst component containing magnesium, titanium, and a halogen, the solid catalyst component is treated with an ester of the formula:

Catalyst process for preparation of same, and process for polymerization

Metallic images of uniform quality can be formed on substrates having through-holes by a process using a positive type resist characterized by using as a coating solution for the substrate a solution of a photosensitive material of (a) at least one organic compound having at least one linkage of --M--M--M ).sub.n (M=Si, Ge or Sn; n=0, 1 or more) in the molecule or (b) a mixture of at least one organic compound (a) mentioned above and at least one photosensitizer, dissolved in a solvent such as a halogenated hydrocarbon, an aromatic hydrocarbon, a heterocyclic compound, or a mixture thereof, followed by irradiation with an actinic light through a photomask and electroless plating.

Process for forming metallic image

A novel and effective method for the synthetic preparation of dialkylchlorosilanes as an important intermediate in the silicone industry is provided, which is based on the selectivity of a specific combination of a reaction solvent and a reducing agent in the dechlorination-reduction of one of the two silicon-bonded chlorine atoms present in a dialkyldichlorosilane to convert the Si-Cl linkages to Si-H. The reaction solvent used is either N,N'-dimethylimidazolidinone or N,N,N',N',N',N'-hexamethyl-phosphoric triamide, while the reducing agent is sodium borohydride, optionally in combination with sodium hydride.

Method for the preparation of dialkylchlorosilanes

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Sendai, Japan

Hideki Sakurai