Denki Kagaku Kogyo Kabushiki Kaisha

Denki Kagaku Kogyo Kabushiki Kaisha, Chuo-kenkyusho

Hideki Matsumura

Takao Iwasaki

Ikuji Kishi

Takashi Kadowaki

Norio Yagi

Tatsuhiro Aoyagi

Koichi Abe

Akihiko Okuda

Junji Hirano

Yukinori Totake

2,3-Dichlorobutadiene-1,3 is produced by a continuous dehydrochlorination of 1,2,3-trichlorobutene-3 in a water miscible solvent in the presence of an alkali metal hydroxide. An evaporator is connected in the downstream of a reactor for the dehydrochlorination to recover the unreacted 1,2,3-trichlorobutene-3 and said water miscible solvent by an evaporation.

Process for producing 2,3 dichlorobutadiene-1,3

Chloroprene is produced by reacting 3,4-dichlorobutene-1 with a base in the presence of thiodiphenyl amine and 2,6-di-tertiarybutyl-p-cresol and preventing clogging of the equipment. 3,4-Dichlorobutene-1 is produced by an isomerization of the reaction mixture obtained by a chlorination of excess of butadiene wherein higher boiling compounds are separated before a separation of the unreacted butadiene.

Process for producing chloroprene

An aromatic polymer is prepared by polymerizing a diphenolate compound, of a dialkali metal salt of a diphenol with a dihalodiphenyl compound, of a dihalogenobenzenoid compound having an electron withdrawing group in at least one of the positions ortho or para to each of the halogen atoms, at 200.degree. C. to 400.degree. C. in the presence of from 0.1 to 30% by weight of an inert nonpolar aromatic reaction lubricant.

Process for preparing an aromatic polymer in the presence of an inert

In production of chloroprene by dehydrochlorinating 3,4-dichlorobutene-1 in the presence of an aqueous solution of alkali, the mixture of 3,4-dichlorobutene-1 and the aqueous solution of alkali is heated at 85.degree. to 100.degree. C to evaporate a mixture consisting mainly of the resulting chloroprene, unreacted 3,4-dichlorobutene-1 and water rapidly, the evaporated mixture is taken out from the reaction system without subjecting to a distillation and totally condensed, the condensed reaction mixture is separated into an aqueous phase and an organic phase and then the organic phase is fractionally distilled to separate chloroprene from 3,4-dichlorobutene-1. Prior to subjecting the organic phase to the fractional distillation, if the organic phase is previously subjected to a drying means and the water content in the organic phase is reduced to a proper degree, it is possible to avoid formation of polymer of the resulting chloroprene and corrosion of the distillation column.

Method of producing chloroprene

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Machida, Japan

Hideki Matsumura