Toyota Jidosha Kabushiki Kaisha

Hideaki Nishimura

Hajime Hasegawa

Norihiro Ose

Yuki Matsushita

Hideyo Ebisuzaki

Shigenori Hama

Mitsuru Tateishi

Yusuke Okuhata

Tomoya Suzuki

Kazuo Yaso

Hisataka Fujimaki

Ayano Kobayashi

Shigetaka Nagamatsu

Takayuki Uchiyama

Naohiro Mashimo

Dai Kato

Jun Yoshida

Mitsutoshi Otaki

Satoshi Wakasugi

Ximeng Li

Shohei Kawashima

Masumi Sato

Tomoya Matsunaga

Sakina Kaneko

So Yubuchi

Satoshi Mizutani

Masataka Tomita

A main object of the present disclosure is to provide an all solid state battery in which occurrence of short circuit is inhibited. The present disclosure achieves the object by providing an all solid state battery comprising an anode including at least an anode current collector, a cathode, and a solid electrolyte layer arranged between the anode and the cathode; wherein a protective layer containing a Mg-containing particle that contains at least Mg, and also containing a polymer, is arranged between the anode current collector and the solid electrolyte layer.

All solid state battery

A main object of the present disclosure is to provide an all solid state battery in which occurrence of short circuit is inhibited. The present disclosure achieves the object by providing an all solid state battery including an anode including at least an anode current collector, a cathode, and a solid electrolyte layer arranged between the anode and the cathode; wherein a protective layer containing a Mg-containing particle that contains at least Mg, and also contains a polymer, is arranged between the anode current collector and the solid electrolyte layer; and a contacting area rate in an interface between the solid electrolyte layer and the protective layer is 50% or more.

A main object of the present disclosure is to provide an all solid state battery in which occurrence of short circuit is inhibited. The present disclosure achieves the object by providing an all solid state battery comprising an anode including at least an anode current collector, a cathode, and a solid electrolyte layer arranged between the anode and the cathode; wherein a protective layer containing a Mg-containing particle that contains at least Mg, and also containing a polymer, is arranged between the anode current collector and the solid electrolyte layer; the solid electrolyte layer contains a solid electrolyte in a granular shape; and when X designates an average particle size Dof the solid electrolyte and Y designates an average thickness of the solid electrolyte layer, X/Y is 0.0125 or more and 0.02 or less.

A main object of the present disclosure is to provide an anode layer with little resistance increase due to charge and discharge. In the present disclosure, the above object is achieved by providing an anode layer comprising: an anode active material including a Nb element, a W element, and an O element; and a solid electrolyte, and an expansion coefficient of the anode active material when charged to 200 mAh per 1 g is 1.4% or more and 5% or less.

Anode layer and all solid state battery

In the stacked battery, a short-circuit current shunt part is electrically connected to the electric elements, and an insulating layer of the short-circuit current shunt part is constituted of material having a predetermined melting point or glass transition temperature. When heat is excessively generated in the battery due to internal short circuits etc. and the temperature of the battery reaches the melting point of the insulating layer, the insulating layer melts and its shape is changed to short-circuit the short-circuit current shunt part, and current flows from the electric elements into the short-circuit current shunt part. To measure the current flowing into the short-circuit current shunt part makes it possible to easily grasp excessive heat generation of the battery to suppress deterioration of the battery due to heat generation.

Stacked battery

An electrode for solid-state batteries, comprising a PTC resistor layer, and a solid-state battery comprising the electrode. The electrode may be an electrode for solid-state batteries, wherein the electrode comprises an electrode active material layer, a current collector and a PTC resistor layer disposed between the electrode active material layer and the current collector; wherein the PTC resistor layer contains an electroconductive material, an insulating inorganic substance and a polymer; and wherein a porosity of the PTC resistor layer is from 5% to 13%.

Electrode for solid-state batteries and solid-state battery

Provided is a method for producing an electrode for solid-state batteries which comprises a PTC resistor layer containing an insulating inorganic substance and in which electronic resistance is low. The production method is a method for producing an electrode for solid-state batteries, wherein the method is a method for producing an electrode for use in a solid-state battery comprising a cathode, an anode and an electrolyte layer disposed between the cathode and the anode; wherein the electrode is at least one of the cathode and the anode, and the electrode comprises a current collector, an electrode active material layer and a PTC resistor layer disposed between the current collector and the electrode active material layer.

Method for producing electrode for solid-state batteries

A main object of the present disclosure is to provide a stacked battery in which an unevenness of short circuit resistance among a plurality of cells is suppressed. The present disclosure achieves the object by providing a stacked battery comprising: a plurality of cells in a thickness direction, wherein the plurality of cells are electrically connected in parallel; each of the plurality of cells includes a cathode current collector, a cathode active material layer, a solid electrolyte layer, an anode active material layer, and an anode current collector, in this order; the stacked battery includes a surface-side cell that is located on a surface side of the stacked battery, and a center-side cell that is located on a center side rather than the surface-side cell; and a contact resistance between the cathode current collector and the anode current collector in the surface-side cell is more than a contact resistance between the cathode current collector and the anode current collector in the center-side cell.

An electrode for solid-state batteries, comprising a PTC resistor layer, and a solid-state battery comprising the electrode. The electrode may be an electrode for solid-state batteries, wherein the electrode comprises an electrode active material layer, a current collector and a PTC resistor layer which is disposed between the electrode active material layer and the current collector and which is in contact with the electrode active material layer; wherein the PTC resistor layer contains an electroconductive material, an insulating inorganic substance and a polymer; and wherein a surface roughness Ra of an electrode active material layer-contacting surface of the PTC resistor layer, is 1.1 &#x3bc;m or less.

An electrode for solid-state batteries, comprising a PTC resistor layer, and a solid-state battery comprising the electrode. The electrode may be an electrode for solid-state batteries, wherein the electrode comprises an electrode active material layer, a current collector and a PTC resistor layer which is disposed between the electrode active material layer and the current collector and which is in contact with the electrode active material layer; wherein the PTC resistor layer contains an electroconductive material, an insulating inorganic substance and a polymer.

A main object of the present disclosure is to provide a stacked battery in which the unevenness of short circuit resistance among a plurality of cells is suppressed. The present disclosure achieves the object by providing a stacked battery comprising: a plurality of cells in a thickness direction, wherein the plurality of cells are electrically connected in parallel; each of the plurality of cells includes a cathode current collector, a cathode active material layer, a solid electrolyte layer, an anode active material layer, and an anode current collector, in this order; the stacked battery includes a surface-side cell that is located on a surface side of the stacked battery, and a center-side cell that is located on a center side rather than the surface-side cell; and the surface-side cell and the center-side cell satisfy at least one of: condition i) an elongation rate of the cathode current collector in the surface-side cell is less than an elongation rate of the cathode current collector in the center-side cell; and condition ii) an elongation rate of the anode current collector in the surface-side cell is less than an elongation rate of the anode current collector in the center-side cell.

An electrode for solid-state batteries, comprising a PTC resistor layer, and a solid-state battery comprising the electrode. The electrode may be an electrode for solid-state batteries, wherein the electrode comprises an electrode active material layer, a current collector and a PTC resistor layer which is disposed between the electrode active material layer and the current collector and which is in contact with the electrode active material layer; wherein the PTC resistor layer contains a carbon-containing electroconductive material, an insulating inorganic substance and a fluorine-containing polymer.

Disclosed is a stacked battery that can flow a larger rounding current in a short-circuit current shunt part than in an electric element when a short circuit occurs in the short-circuit current shunt part and the electric element in nailing, the stacked battery in which an electrical resistance of a current collector tab of the short-circuit current shunt part is smaller than an electrical resistance of a current collector tab of the electric element.

An objective of the present disclosure is to provide a stacked battery that suppresses sneak current caused by an unevenness of a short circuit resistance among a plurality of cells. The present disclosure provides a stacked battery comprising: a plurality of cells in a thickness direction, wherein the plurality of cells are electrically connected in parallel; the stacked battery includes a surface-side cell that is located on a surface side of the stacked battery, and a center-side cell that is located on a center side rather than the surface-side cell; wherein a resistance of the cathode current collecting tab in the surface-side cell is more than a resistance of the cathode current collecting tab in the center-side cell; or a resistance of the anode current collecting tab in the surface-side cell is more than a resistance of the anode current collecting tab in the center-side cell.

An all-solid-state battery including a laminated body with a cathode current collecting layer, cathode active material layer, solid electrolyte layer, anode active material layer, and anode current collecting layer in this order, and a restraining member that applies a restraining pressure to the laminated body in a laminated direction; containing a conductive material, an insulating inorganic substance, and a polymer, is in at least one of a position between the cathode active material layer and the cathode current collecting layer, and a position between the anode active material layer and the anode current collecting layer; the content of the insulating inorganic substance in the PTC layer is 10 volume % or more and 40 volume % or less; and a proportion of a particle size Dof the insulating inorganic substance, D, to a thickness of the PTC layer, T, regarded as D/Tis 0.6 or more and 1.0 or less.

Growing community of inventors

Sunto-gun, Japan

Hideaki Nishimura