Ford Motor Company Limited

Daimler Ag

Ballard Power Systems Corporation

Bdf IP Holdings Ltd.

Herwig Haas

Joy A Roberts

Francine Berretta

Hao Zhang

Christopher J Richards

John Robert Gordon

Mike Davis

Amy Shun-Wen Yang

Jean St-Pierre

Richard Fellows

Simon Farrington

Scott McDermid

Michael P Sexsmith

Carmen Chuy

Marian E Van Der Geest

Volker Peinecke

Abderrahmane Atbi

J&uuml;rgen Stumper

David Alexander Summers

Stephen J Lee

Sumit Kundu

NengYou Jia

Kelvin Keen-Ven Fong

Cara N Startek

Andrew L Christie

Andrew Leow

Stanley Tam

Jorg Von Der Osten-Fabeck

Rajeev Vohra

Andrew J DeSouza

Kelvin K Fong

Radu P Bradean

David D L Adam

Andrew J Desouza

Yvonne Hsieh

Guy Pepin

Use of a selectively conducting anode component in solid polymer electrolyte fuel cells can reduce the degradation associated with repeated startup and shutdown, but can also adversely affect a cell's tolerance to voltage reversal along with its performance. It was shown that these adverse affects can be mitigated against in certain ways. However, improved results can be obtained by employing a selectively conducting component which comprises a mixed layer of a selectively conducting material and carbon. The mixed layer contacts the side of the anode opposite the solid polymer electrolyte.

Fuel cell with selectively conducting anode

Use of noble metal alloy catalysts, such as PtCo, as the cathode catalyst in solid polymer electrolyte fuel cells can provide enhanced performance at low current densities over that obtained from the noble metal itself. Unfortunately, the performance at high current densities has been relatively poor. However, using a specific bilayer cathode construction, in which a noble metal/non-noble metal alloy layer is located adjacent the cathode gas diffusion layer and a noble metal layer is located adjacent the membrane electrolyte, can provide superior performance at all current densities.

Bilayer cathode catalyst structure for solid polymer electrolyte fuel cell

The degradation associated with repeated startup and shutdown of solid polymer electrolyte fuel cells comprising PtCo alloy cathode catalysts can be particularly poor. However, a marked and unexpected improvement in durability is observed as a result of incorporating a selectively conducting component in electrical series with the anode components in the fuel cell.

Durable fuel cell with platinum cobalt alloy cathode catalyst and selectively conducting anode

A membrane electrode assembly (MEA) for a fuel cell which exhibits enhanced reversal tolerance. In particular, a layer of iridium or an iridium compound, preferably metallic iridium or iridium oxide supported on TiO, is provided on the anode to electrolyze available water and pass the majority of the current during a reversal of the fuel cell, thereby preventing damage to the MEA. The iridium or iridium compound is applied to an anode structure according to a predetermined pattern, with only part of the anode active area containing Ir. The parts of the MEA that do not contain Ir are not expected to suffer degradation from Ir cross-over, so that overall degradation of the cell will be diminished. Having less precious metals will also translate into less cost.

Reversal tolerant membrane electrode assembly for a fuel cell

Ruthenium or a Ruthenium compound is applied to an anode structure according to a predetermined pattern, with only part of the anode active area containing Ru. The parts of the MEA that do not contain Ru are not expected to suffer degradation from Ru cross-over, so that overall degradation of the cell will be diminished. Having less precious metals will also translate into less cost.

A plurality of flow field plate assemblies forms a fuel cell stack. Each flow field plate assembly has a first flow field plate positionable on an anode side of a membrane electrode assembly (MEA) of a first fuel cell, a second flow field plate positionable on a cathode side of an MEA of a second fuel cell, adjacent the first fuel cell. At least one back-feed channel is interposed between the first and second flow field plates. At least a portion of the back-feed channel or a reactant manifold opening formed by the first and second flow field plates has a geometry that forms regions of high and low capillary forces, promoting liquid migration toward regions substantially isolated from a flow of reactants, to prevent water collection and ice formation. The migrated liquid is purged during a purge of the fuel cell stack after operation.

Apparatus and method for managing fluids in a fuel cell stack

By incorporating a selectively conducting component in electrical series with the anode components in a solid polymer fuel cell, degradation during startup and shutdown can be reduced. As a result, the startup and shutdown procedures can be simplified and consequently certain system apparatus may be omitted. The anode does not need to be rapidly purged with hydrogen on startup or with air on shutdown. Additionally, the auxiliary load usually employed during such purging is not required.

Fuel cell with selectively conducting anode component

Improved water distribution can be obtained within the cells of a fuel cell series stack by maintaining a suitable temperature difference between the cathode and anode sides of each cell in the stack during shutdown. A method of shutting down a fuel cell stack having at least two fuel cells stacked in series, each fuel cell having a cathode side and an anode side, the method comprising: stopped the generation of electricity from the stack; allowing the stack to cool over a cooldown period; and maintaining a temperature difference between the cathode side and the anode side of each fuel cell during the cooldown period, wherein the direction of the temperature difference in each fuel cell is the same. The fuel cell stack may comprise coolant channels, Peltier devices and anode and cathode reactant flow fields.

Shutdown methods and designs for fuel cell stacks

Improved water distribution can be obtained within the cells of a fuel cell series stack by maintaining a suitable temperature difference between the cathode and anode sides of each cell in the stack during shutdown. This can be accomplished by thermally insulating the 'hot' end and sides of the stack and by providing a thermal mass adjacent to the 'hot' end.

A fuel cell system comprising a fuel cell stack and at least one hydration sensor apparatus for measuring membrane hydration in the fuel cell stack is disclosed. The hydration sensor apparatus comprises (1) an electrically insulated sensor comprising a polymer electrolyte membrane, (2) a power supply, and (3) a load resistor. The sensor, the power supply and the load resistor of the hydration sensor apparatus are electrically connected and the sensor of the hydration sensor apparatus is fluidly connected to the fuel cell stack such that, during operation of the fuel cell system, the polymer electrolyte membrane of the hydration sensor apparatus is exposed to a fuel fluid stream of the fuel cell stack.

Hydration sensor apparatus for measuring membrane hydration in a fuel cell stack

A fuel cell system is operated with the fuel supply pressure greater than the oxidant supply pressure to the fuel cell. This gives improved performance particularly when the fuel cell system is closed on the fuel side. The magnitude of fuel overpressure may be varied in accordance with variations in the fuel cell operating parameters.

Methods of operating fuel cells having closed reactant supply systems

Apparatus and methods of ceasing operation of an electric power generating system improve the cold starting capability of the system. The system comprises a fuel cell stack connectable to an external circuit for supplying power to the external circuit. The stack comprises at least one solid polymer fuel cell, and the system further comprises a fuel passage for directing a fuel stream through the stack and an oxidant passage for directing an oxidant stream through the stack, a sensor assembly connected to the stack for monitoring a parameter indicative of stack performance, a controller for controlling at least one stack operating parameter, and a control system communicative with the sensor assembly and stack operating parameter controller. The method comprises adjusting at least one stack operating parameter to cause the stack to operate under a drying condition that causes a net outflux of water from the stack, operating the stack under the drying condition until the water content in the stack has been reduced, and interrupting supply of power from the stack to the external circuit.

Methods and apparatus for improving the cold starting capability of a fuel cell

In a method of manufacturing a fluid diffusion layer for a solid polymer electrolyte fuel cell, a surface of the fluid diffusion layer is abraded so that the topography of the fluid diffusion layer surface is rendered more uniform. The fluid diffusion layer comprises a porous substrate, and may also comprise a carbon-containing sublayer, as well as hydrophobic material. The particles formed by the abrading operation may be deposited into at least some of the pores of the substrate to form a support structure for the direct depositing of a catalyst onto the abraded surface.

Abraded fluid diffusion layer for an electrochemical fuel cell

The present methods make fluid diffusion layers having reduced surface roughness. The methods used for adhering the loading material to the substrate surface can reduce the average surface roughness of the fluid diffusion layers, thereby reducing leaks in and damage to ion exchange membranes. When fluid diffusion layers and electrodes having reduced surface roughness are employed in membrane electrode assemblies, better reliability and performance are obtained. A method of calculating the surface roughness of a fluid diffusion layer may be used.

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Vancouver, Canada

Herwig Haas