Sandoz Gmbh

Ciba-geigy Corporation

Hermann Schneider

Wolfgang H Mueller

Hans Hinsken

Horst Mayerhoefer

Takeo Hokama

Ian S Cloudsdale

Werner Langer

A process for preparation of substituted phthalides, heterocyclic phthalides and derivatives thereof by reacting an aromatic carboxylic acid mono- or di-anion with a reactive derivative of a pyrimidine carboxylic acid.

Process for preparing substituted pyrimidines

The invention provides compounds of formula I ##STR1## wherein R is C.sub.1-4 alkoxy-C.sub.2-4 alkyl of which the C.sub.1-4 alkoxy group is separated by at least 2 C-atoms from the N-atom to which R is bound,

Preparation of N-thienyl-chloroacetamides and

The present invention relates to a process for stabilizing organic polymeric materials comprising incorporating therein a benzofuran (2) one or indolin (2) one compound as stabilizer. Such stabilized polymeric materials are stabilized against degradation during the polymer processing.

Benzofuranone or indolinone compounds useful as stabilizers for organic

Compounds of formula I ##STR1## where R.sub.1, R.sub.2 and R.sub.3 are defined in the text, are useful as light stabilizers for polymeric materials, particularly for thermoplastic polymers and automotive finishes. Preferred compounds are those in which R.sub.1 is hydrogen and R.sub.2 and R.sub.3 are identical (C.sub.8-17 alkyl)carbonyl groups.

4-Aminomethylpolyalkylpiperidines useful as light stabilizers

Compounds obtained by the addition of unsaturated esters to the &gt;NH group of compounds of formula II ##STR1## are useful as light stabilizers for polymeric materials, particularly for thermoplastic polymers and automotive finishes. Preferred compounds are those in which R, R.sub.1 and R.sub.2 are all hydrogen and R.sub.3 and R.sub.4 together with the carbon atom to which they are attached form a cyclododecylidene ring.

1-Oxa-3,8-diazaspiro[4.5]decanes

N-(.beta.-aminoethyl)-3-hydroxy-1,1,6,6-tetramethyl-piperidine and certain of its N- and O-substituted derivatives are useful as light stabilizers for polymeric materials, particularly for thermoplastic polymers and automotive finishes. Preferred compounds include the N-, O-diacyl derivatives.

Hindered piperidine polymer stabilizers

The present invention relates to a process for stabilizing organic polymeric materials comprising incorporating therein a benzofuran(2)one compound or indolin(2)one compound containing at least two benzofuran(2)one or indolin(2)one nuclei.

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Grenzach-Wyhlen, Germany

Hermann Schneider