Aalto University Foundation Sr

Helsingin Yliopisto

Turun Yliopisto

Metsa Fibre Oy

Herbert Sixta

Mika Lastusaari

Michael Hummel

Mikhail Iakovlev

Sanna Hellsten

Ilkka Kilpeläinen

Arno Parviainen

Jussi Helminen

Emma Sairanen

Alistair King

Marja Rissanen

Anne Michud

Sherif Elsayed

Petri Uusi-Kyyny

Simone Haslinger

Joanna Witos

Lauri Hauru

Inge Schlapp-Hackl

Alistair W T King

Iikka Kilpeläinen

Yibo Ma

Ville Alopaeus

Kadvaël Le Boulch

Alistair Wt King

Sami Vuori

Isabella Pönkkä

Wenwen Fang

Lasse Tolonen

According to an example aspect of the present invention, there is provided a process for the production of a cellulose filaments or films, comprising the steps of dissolving a cellulose substrate in an ionic liquid consisting of the superbase cation 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-enium [mTBDH]+ and an anion to produce a solution forming a spinning dope, said anion being derived from an acid which is present at a stoichiometric excess to the superbase, extruding the spinning dope through a spinneret in a coagulation bath containing water to form filaments or films from the solution, withdrawing ionic liquid in an aqueous mixture with water from the coagulation bath, recovering the ionic liquid [mTBDH][OAc] from the aqueous mixture by removing water and optionally recycling the recovered ionic liquid to the dissolution step.

Recycling of acid-superbase conjugate ionic liquids by water removal in the lyocell spinning process

According to an example aspect of the present invention, there is provided A process for making a cellulose fibre or film comprising the steps of dissolving pulp in an ionic liquid containing a cationic 1,5,7-triazabicyclo[4.4.0]dec-5-enium [TBDH]+ moiety and an anion selected from the group according to Formula a), Formula b) and Formula c), wherein each of R, R, R, R, R, R, R, Rand Ris H or an organyl radical and Xis selected from the group consisting of halides, pseudohalides, carboxylates, alkyl sulphite, alkyl sulphate, dialkylphosphite, dialkyl phosphate, dialkyl phosphonites and dialkyl phosphonates, to provide a spinning dope, extruding the spinning dope through a spinneret to form one or more filaments, and a step selected from the group consisting of spinning cellulose fibres from the solution, and extruding a cellulose film from the solution.

Process for making cellulose fibre or film

According to an example aspect of the present invention, there is provided a process for the conversion of cellulosic waste material into a recycled cellulose product comprising the steps of cooking the waste material in a cooking liquor to remove lignin from the waste material and provide a delignified pulp, dissolving the delignified pulp in an ionic liquid to provide a spinning dope suitable for dry jet-wet spinning in an ionic liquid solution, and subjecting the spinning dope to a further processing step to provide a recycled cellulose product, said further step selected from the group of spinning cellulose fibers for use in textiles from the solution, extruding a film product for use in packaging, regenerating the dope as a hydrogel and regenerating the dope as an aerogel.

Method to convert mechanical pulp derived waste material into value added cellulose products

According to an example aspect of the present invention, there is provided a method of separating cellulose and polyester from a material comprising a blend of cellulose and polyester, said method comprising the steps of mixing the material comprising a blend of cellulose and polyester with a first portion of superbase-based ionic liquid to dissolve a first portion of cellulose and form a first cellulose solution and a first residue comprising polyester, removing the first residue comprising polyester from the first cellulose solution, and directing the first cellulose solution to one or more further processing steps.

Separation and upcycling of cellulose-containing blended waste

A method of manufacturing a cellulose-based shaped article. The method comprises subjecting a solution of lignocellulosic material, dissolved in a distillable ionic liquid, to a spinning method, wherein the ionic liquid is a diazabicyclononene (DBN)-based ionic liquid. DBN-based ionic liquids have good dissolution power, high thermal and chemical stability, lack runaway reactions and exhibit low energy consumption, due to low spinning temperatures. The shaped cellulose articles can be used as textile fibers, high-end non-woven fibers, technical fibers, films for packaging, and barriers films in batteries, as membranes and as carbon-fiber precursors.

Process for the production of shaped cellulose articles

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Aalto, Finland

Herbert Sixta