Lg Chem, Ltd

Heon-Cheol Shin

Je-Young Kim

Je Young Kim

Yo-Han Kwon

Hye-Ran Jung

Hyung-Man Cho

Sang-Wook Woo

Sang-Young Lee

Byung-Hun Oh

Ki Tae Kim

Ki-Tae Kim

Su-Jin Park

Eun-Ji Kim

Woo-Sung Choi

Provided is a method for manufacturing an anode of a cable-type secondary battery having a solid electrolyte layer, including preparing an aqueous solution of an anode active material, making an anode by immersing a core as a current collector having a horizontal cross section of a predetermined shape and extending longitudinally in the aqueous solution, then applying an electric current to form a porous shell of the anode active material on the surface of the core, and forming a solid electrolyte layer on the surface of the anode by passing the anode through a solid electrolyte solution. The anode has a high contact area to increase the mobility of lithium ions, thereby improving battery performance. Also, the anode is capable of relieving stress and pressure in the battery, such as volume expansion during charging and discharging, thereby preventing battery deformation and ensuring battery stability.

Anode of cable-type secondary battery and manufacturing method thereof

The present invention relates to a cable-type secondary battery having a horizontal cross section of a predetermined shape and extending longitudinally, comprising: an inner electrode having an inner current collector and an inner electrode active material layer surrounding the outer surface of the inner current collector; a separation layer surrounding the outer surface of the inner electrode to prevent a short circuit between electrodes; and an outer electrode surrounding the outer surface of the separation layer and having an outer electrode active material layer and an open-structured outer current collector.

Cable-type secondary battery

The present invention relates to a cable-type secondary battery having a horizontal cross section of a predetermined shape and extending longitudinally, comprising: an inner electrode having an inner current collector and an inner electrode active material layer surrounding the outer surface of the inner current collector; a separation layer surrounding the outer surface of the inner electrode to prevent a short circuit between electrodes; and an outer electrode surrounding the outer surface of the separation layer, and having an outer electrode active material layer, an open-structured outer current collector and a conductive paste layer. The outer electrode having a conductive paste layer and an open-structured outer current collector according to the present invention has good flexibility to improve the flexibility of a cable-type secondary battery having the same. Also, the conductive paste layer is made of a light material, and thus can contribute to the lightening of the cable-type secondary battery.

Disclosed is an anode for a lithium secondary battery. The anode includes a current collector in the form of a wire and a porous anode active material layer coated to surround the surface of the current collector. The three-dimensional porous structure of the active material layer increases the surface area of the anode. Accordingly, the mobility of lithium ions through the anode is improved, achieving superior battery performance. In addition, the porous structure allows the anode to relieve internal stress and pressure, such as swelling, occurring during charge and discharge of a battery, ensuring high stability of the battery while preventing deformation of the battery. These advantages make the anode suitable for use in a cable-type secondary battery. Further disclosed is a lithium secondary battery including the anode.

Anode for cable-type secondary battery and cable-type secondary battery including the anode

The present invention provides a cable-type secondary battery comprising an inner electrode which includes at least one first polarity electrode having a first polarity current collector with a long and thin shape, whose cross-section perpendicular to its longitudinal direction is a circular, oval or polygonal form; a first polarity electrode active material layer formed on an outer surface of the first polarity current collector; and an electrolyte layer filled to surround the first polarity electrode active material layer, and at least one wire-type second polarity electrode which wholly surrounds the inner electrode and is winding around the exterior thereof. Thus, the inventive cable-type secondary battery provided with an outer winding electrode has excellent flexibility to prevent the release of the active material.

A method for manufacturing a cable-type secondary battery includes: preparing a first polarity current collector having a long and thin shape; forming at least two first polarity electrode active material layers on the first polarity current collector to be spaced apart from each other in the longitudinal direction; forming an electrolyte layer to surround the at least two first polarity electrode active material layers; forming at least two second polarity electrode active material layers on the electrolyte layer to be spaced apart from each other at positions corresponding to the first polarity electrode active material layers; forming an electrode assembly by surrounding the second polarity electrode active material layers with a second polarity current collector; surrounding the electrode assembly with a cover member; and bending the electrode assembly and the cover member into a serpentine configuration with the active regions spaced apart from one another.

Cable-type secondary battery and method for manufacturing the same

A cable-type secondary battery includes an electrode assembly, which has a first polarity current collector having a long and thin shape, at least two first polarity electrode active material layers formed on the first polarity current collector to be spaced apart in the longitudinal direction, an electrolyte layer filled to surround at least two first polarity electrode active material layers, at least two second polarity electrode active material layers formed on the electrolyte layer to be spaced apart at positions corresponding to the first polarity electrode active material layers, the electrode assembly being continuously bent into a serpentine configuration by a space between the first polarity electrode active material layers; a second polarity current collector configured to surround at least one side of the electrode assembly bent into a serpentine configuration; and a cover member configured to surround the second polarity current collector and the electrode assembly.

A cable-type secondary battery includes an electrode assembly, which has a first polarity current collector having a long and thin shape, at least two first polarity electrode active material layers formed on the first polarity current collector to be spaced apart in the longitudinal direction, an electrolyte layer filled to surround at least two first polarity electrode active material layers, at least two second polarity electrode active material layers formed on the electrolyte layer to be spaced apart at positions corresponding to the first polarity electrode active material layers, and a second polarity current collector configured to surround the outer surfaces of the second polarity electrode active material layers, the electrode assembly being continuously bent into a serpentine configuration by a space between the first polarity electrode active material layers; and a cover member configured to surround the electrode assembly which is continuously bent into a substantially a serpentine configuration.

Provided is a cable-type secondary battery including an anode current collector having a horizontal cross section of a predetermined shape and extending longitudinally, an anode active material pattern layer having anode active material patterns spaced away at a predetermined interval on the anode current collector, an electrolyte layer surrounding the anode active material pattern layer and serving as an ion channel, a cathode active material pattern layer having cathode active material patterns spaced away at a predetermined interval on the electrolyte layer at locations corresponding to those of the anode active material patterns, and a cathode current collector surrounding the cathode active material pattern layer. The cable-type secondary battery having the active material patterns has excellent flexibility to prevent the active material from falling off from the active material layer.

Provided is a cable-type secondary battery including an electrode assembly having a horizontal cross section of a predetermined shape and extending longitudinally, and a wire-type outer current collector wound on the outer surface of the electrode assembly, the electrode assembly including an inner current collector, an anode active material layer, and an electrolyte layer, and a cathode active material layer; the wire-type outer current collector has excellent flexibility and a predetermined level of elasticity, and thus, improves the flexibility of the entire cable-type secondary battery and prevents a short circuit from occurring and the active material from falling off from the active material layer, due to the deformation of the cable-type secondary battery.

Provided is a cable-type secondary battery including an electrode assembly and a cover member surrounding the electrode assembly, the electrode assembly including first and second electrodes of an elongated shape and a separator or an electrolyte interposed between the first and second electrodes, each electrode including a current collector having a cross section of a circular, asymmetrical oval or polygonal shape perpendicular to the lengthwise direction thereof and an electrode active material applied onto the surface of the current collector, wherein the cover member has at least partially a predetermined concavo-convex pattern in the direction of the electrode assembly. The cover member of a concavo-convex pattern may improve the flexibility of the cable-type secondary battery. When the cover member is applied to an electrode active material pattern layer, the flexibility of the cable-type secondary battery may be further improved.

A cable-type secondary battery is disclosed. The cable-type secondary battery includes electrodes, each of which includes a current collector having a horizontal cross section of a predetermined shape and an active material layer formed on the surface of the current collector. The electrodes extend in the lengthwise direction and are arranged in parallel. The current collector includes a polymer core and a metal coating layer formed on the surface of the polymer core. The use of the metal-coated polymer current collectors having high flexibility and conductivity makes the secondary battery highly flexible while maintaining the performance of the secondary battery. In addition, the cable-type secondary battery can be reduced in weight.

Growing community of inventors

Busan, South Korea

Heon-Cheol Shin