Institut Francais Du Pe'trole

Institute Francais Du Petrole

Gaz De France

Elf Antar France

Henri Delhomme

Paul Mariaggi

Christian R Busson

Nathalie George-Marchal

Dominique Audigier

Alain Forestiere

Fr&eacute;d&eacute;ric Morel

Fr&eacute;d&eacute;rique Jacquemin-Hauviller

Frederique Jacquemin-Hauviller

Marie-Claire Marion

Jean-Pierre Burzynski

Jean-Paul Euzen

Frederic Morel

Gerard Leger

Jean Gaillard

Luc Nougier

Daniele Eber

Philippe Mulard

Pierre Trambouze

Pierre Yout

Laure Gollion

Jean Pierre Cassagne

Dominique Augigier

A thermosetting composition with a glass transition temperature of at least 100&deg; C. comprises at least one epoxy resin formed from at least one polyepoxide containing at least two epoxy groups in its molecule and at least one aromatic polyamine containing at least two primary amino groups in its molecule, at least one alkanoyl substituent containing 1 to 12 carbon atoms located in the position alpha to one of the amino groups. The molar ratio of the amine to the epoxide is such that each amine group corresponds to 1.6 to 2.6 epoxy groups. The composition also includes a flow controller. The composition can be used as a protective coating for any metallic or non metallic surface. The invention also concerns a flexible deployable preform comprising the composition.

Flexible deployable preform

A process for transforming a gas oil cut into a dearomatized fuel with a high cetane number comprises at least one first, deep desulphurization and deep denitrogenation step in which the gas oil cut and hydrogen are passed over a catalyst comprising a mineral support, at least one group VIB metal or metal compound, at least one group VIII metal or metal compound, and phosphorous or at least one phosphorous compound, and at least one subsequent second step, dearomatization, in which the desulphurized and denitrogenated product from the first step is passed with hydrogen over a catalyst comprising a mineral support and at least one group VIII noble metal or noble metal compound.

Process for transforming a gas oil cut to produce a dearomatized and desulphurized fuel with a high cetane number

A process for thermal pyrolysis of a feedstock containing at least 80% ethane to convert to ethylene at a conversion rate of at least equal 80% by feeding the feedstock into a reaction zone in which heating means are arranged approximately perpendicular to the direction of flow of the feedstock. The temperature of the outlet of the heating zone in the reaction zone is between 880 and 960&deg; C. and the dwell time of the feedstock in the heating zone is between 1005 and 3000 milliseconds.

Process for thermal pyrolysis of a feedstock that contains ethane

A process for transforming a gas oil cut into a dearomatised fuel with a high cetane number comprises at least one first, deep desulphurisation and deep denitrogenation step in which the gas oil cut and hydrogen are passed over a catalyst comprising a mineral support, at least one group VIB metal or metal compound, at least one group VIII metal or metal compound, and phosphorous or at least one phosphorous compound, and at least one subsequent second step, dearomatisation, in which the desulphurised and denitrogenated product from the first step is passed with hydrogen over a catalyst comprising a mineral support and at least one group VIII noble metal or noble metal compound.

Process for transforming a gas oil cut to produce a dearomatised and desulphurised fuel with a high cetane number

A thermosetting composition with a glass transition temperature of at least 100&deg; C. comprises at least one epoxy resin formed from at least one polyepoxide containing at least two epoxy groups in its molecule and at least one aromatic polyamine containing at least two primary amino groups in its molecule, at least one alkyl substituent containing 1 to 12 carbon atoms located in the position alpha to one of the amino groups. The molar ratio of the amine to the epoxide is such that each amine group corresponds to 1.6 to 2.6 epoxy groups. The composition also includes a flow regenerator. The composition can be used as a protective coating for any metallic or non metallic surface. The invention also concerns a flexible deployable preform comprising the composition.

Thermosetting composition, uses thereof and a flexible deployable preform comprising the composition

Process for transforming a gas oil cut to produce a dearomatised and

A process for the pyrolysis of hydrocarbons in a reactor with at least two rows which are parallel to each other in which at least one row is supplied with a non hydrocarbon fluid containing steam to decoke the reaction zone at least in part. At least one other row is supplied with a gaseous mixture containing at least one hydrocarbon and water, to pyrolyze said mixture.

Continuous pyrolysis and decoking process for use in the production of

Thermosetting compositions with improved latency are obtained by addition of a molten aromatic polyamine type curing agent to a liquid epoxy resin followed by cooling the mixture, causing the curing agent to form a suspension of fine particles in the epoxy resin by recrystallisation thereof. The compositions obtained can be used for the manufacture of prepregs with high latency for their use in processes requiring intermediate steps at 80.degree. C. over several hours.

Method of using thermosetting compositions with improved latency

A process for the selective hydrogenation of a fraction of hydrocarbons containing 2 to 20 carbon atoms and comprising monounsaturated olefinic hydrocarbons and/or aromatic compounds and at least one polyunsaturated hydrocarbon from the group formed by acetylenic compounds and dienes, in which the hydrocarbon fraction, which is at least partially in the liquid phase, circulates with hydrogen in a given direction in a reactor containing at least one fixed bed of a hydrogenation catalyst in the form of a divided solid, characterized in that said reactor is provided with at least one inlet conduit for a fluid mixture comprising said hydrocarbon fraction and hydrogen and at least one outlet conduit for the hydrogenated hydrocarbon fraction, and in that it comprises at least one static mixer upstream of said outlet for the hydrogenated hydrocarbon fraction.

Selective hydrogenation of hydrocarbon cuts containing monounsaturated

Thermosetting compositions with improved latency, a process for their

The invention concerns a process and catalyst for the production of cyclohexane by hydrogenation of benzene, comprising at least the two following steps: a) gradually introducing the feed of benzene for hydrogenation and a hydrogen-rich gas into a reaction zone containing a cyclohexane-rich liquid and a nickel-based catalyst in colloidal suspension and recovering a gaseous phase containing cyclohexane, hydrogen and benzene; b) introducing the gaseous phase into a reactor operating under hydrogenation conditions and containing at least one fixed bed of a solid nickel-based hydrogenation catalyst, wherein the nickel-based catalyst used in step a) is a product which results from the reduction, by at least one trialkylaluminium compound, of a solution of at least one nickel carboxylate and at least one sodium carboxylate in solution, the Ni:Na molar ratio being between 2:1 and 1000:1 in a hydrocarbon or a hydrocarbon mixture.

Catalyst and a benzene hydrogenation process using said catalyst

The invention relates to an apparatus comprising a reactor, elongated along one axis, preferably of square or rectangular cross section. The reactor has, at one extremity, at least one supply line for at least one reactant and at least one evacuation outlet at the other extremity for removal of produced effluents. In a first zone (near the first extremity of the reactor), a plurality of heat exchangers, substantially parallel to each other, are disposed in substantially parallel layers perpendicular to the reactor axis, thereby defining spaces or passages for circulation of reactant(s) and/or effluents between the heat exchangers and/or layers formed by the heat exchanger. The heat exchangers are adapted to exchange heat in the passages through successive transverse sections, which are independent and substantially perpendicular to the reactor axis. At least some of the heat exchangers comprise a tubular element formed by at least one shell, supplied with a heat exchange gas or gas mixture, and at least one evacuation element for evacuating the circulating gas or gas mixture which has undergone heat exchange with the reactant(s) and/or effluents.

Apparatus for carrying out chemical reactions requiring addition of heat

Compounds with general formula ##STR1## where R.sup.1 represents a hydrogen atom or a hydrocarbon group containing 1 to 40 carbon atoms. R.sup.2 represents a hydrogen atom or a hydrocarbon group containing 1 to 12 carbon atoms, A, B, and C, which may be identical or different, each represent a divalent hydrocarbon group containing 2 to 6 carbon atoms, n is a whole number from 5 to 50, m and p are each zero or a whole number from 1 to 25, and the sum n+m+p is a whole number from 5 to 50. These compounds are used in multifunctional additive compositions for fuels used in internal combustion engines, in particular spark ignition engines, in admixture with at least one compound selected from the group formed by detergent-dispersant compounds, and at least one compound selected from the group formed by mineral or synthetic lubricating oils and polyglycols which are soluble in said fuels.

Gasoline additives containing alkoxylated imidazo-oxazoles

A distillation-reaction apparatus comprises at least one distillation-reaction zone (G,H) having, on a perforated support (5) permitting the passage of fluids at least one element of type J--container (3b) of volume Vt containing a volume Va of solid catalytic particles--and at least one element of type K--(4) of type K1 and/or (3a) of type K2--the element of type K2 being a container not containing solid catalytic particles, the elements having adequate mechanical characteristics to withstand the loading of the elements in the zone and the perforations of the support being sufficiently small to retain the said elements. The apparatus can be used for performing chemical reactions and the fractionation of the reaction mixture, e.g., for the synthesis of ethers from olefins and alcohols.

Growing community of inventors

Sainte Foy les Lyons, France

Henri Delhomme