Basf Aktiengesellschaft

Basf Se Corporation

Hendrick Mattenheimer

Ulrich Mueller

Ulrich Müller

Markus Schubert

Gerhard Cox

Stefan Maurer

Stefan Blei

Natalia Trukhan

Emi Leung

Markus Tonigold

The present invention relates to a process for the recovery of an at least bidentate organic compound comprised in a porous metal-organic framework material, the material comprising the at least bidentate organic compound coordinated to at least one metal ion, the process comprising the steps of (a) treating the metal-organic framework material with an acidic or alkaline liquid; (b) optionally separating off solid residue; and (c) isolating the at least bidentate organic compound.

Process for the recovery of components forming a metal-organic framework material

The present invention relates to a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is based on an aluminum ion and the at least one at least bidentate organic compound is based on fumaric acid, by reacting at least one aluminum compound with at least fumaric acid in an alkaline aqueous medium, optionally in the presence of at least one base, at a temperature in the range from 20&#xb0; C. to 100&#xb0; C. at an absolute pressure of not more than 2 bar for from 0.2 to 4 hours.

Process for preparing porous metal-organic frameworks based on aluminum fumarate

The present invention relates to a process for preparing porous organic frameworks by reaction of a reaction mixture in a liquid phase comprising the appropriate starting compounds in the presence of a nonaqueous organic solvent in the presence of and/or with liberation of water, wherein the latter is withdrawn from the liquid phase of the reaction mixture during the reaction. Here, frameworks having relatively high specific surface areas can be obtained in a reproducible way.

Process for preparing porous organic framework materials

The present invention relates to a porous metal-organic framework comprising Aland at least one at least bidentate compound, wherein the at least one at least bidentate organic compound is a six-membered aromatic hydrocarbon ring A in which one or more ring carbons may be replaced by nitrogen and which has three substituents X and optionally one or more substituents selected from the group consisting of R, NRR', OR, SR, F, Cl and Br, where R, R&#x2032; are each, independently of one another, hydrogen, methyl which may optionally be substituted by one or more fluorine atoms or ethyl which may optionally be substituted by one or more fluorine atoms and each X is, independently of the others, C(&#x2550;O)O, C(&#x2550;S)O, C(&#x2550;O)S, C(&#x2550;S)Sor a protonated form thereof. The invention further provides a process for preparing it and provides for the use of the new porous metal-organic framework.

Mesoporous metal-organic framework

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Ludwigshafen, Germany

Hendrick Mattenheimer