Basf Aktiengesellschaft

Helmut Degen

Guenter Hansen

Helmut Reichelt

Reinhold Krallmann

Arno Lange

Udo Bergmann

Karl-Heinz Etzbach

Gunther Lamm

Erwin Hahn

Ernst Schefczik

Wolf-Dieter Kermer

Sabine Gruettner-Merten

Gerhard Wagenblast

Manfred Patsch

Johannes P Dix

Hermann Loeffler

Clemens Grund

Norbert Grund

Gerhard Epple

Ralf Brueckmann

Dieter Wegerle

Uwe Nahr

Helmut Flohr

Volker Walther

Gert Motzkus

Hans Weber

Sabine Greuttner

Norbert Zimmerman

Ernst Becker

Dye mixtures with pyridoneazo dyes

Azo dyes of the formula ##STR1## where L.sup.1, L.sup.2, L.sup.3, L.sup.4, X and K are as defined in the specification, and crystal forms of thienylazobenzene dyes are useful for dyeing or printing textile materials such as polyesters, fibers or fabrics made of cellulose esters or polyamides or blend fabrics from polyester and cellulose fibers with high color strength, good fastness properties and brilliant hues.

Azo dyes with an acetalized diazo component of the thiophene or thiazole

Blue dye mixtures useful for dyeing or printing polyester fabrics contain from 30 to 95% by weight, based on the total weight of the dyes, of one or more dyes based on 1,4-diaminoanthraquinone-2,3-dicarboximides and also from 5 to 70% by weight based on the total weight of the dyes, of one or more thiopheneazo dyes having a coupling component of the aniline series.

Blue dye mixtures of high brilliance

A process for preparing nitrobenzophenones by reaction of benzene or its derivatives with nitrobenzoyl chloride in the presence of a Lewis acid, a color-stable modification of 1,4-dimethyl-5-cyano-3-[4-(2,4-dimethylbenzoyl)phenylazo]-2-hydroxy-6-pyri done and its use for dyeing or printing synthetic fiber material are described.

Preparation of nitrobenzophenones, and a color-stable modification of a

Azo dyes having the formula ##STR1## wherein the substituents are as defined in the specification and are useful for dyeing or printing textile materials.

Thiopheneazo dyes with a coupling component of the diaminopyridine series

Dye mixtures containing from 50 to 95% by weight, of a 4-chloro-2-nitrophenylazohydroxypyridone dye and from 5 to 50% by weight of a chlorinated quinophthalone dye and/or from 5 to 20% by weight of an unsubstituted quinophthalone dye, dye formulations containing the novel dye mixtures and the use of dye mixtures for dyeing polyesters or printing them by the direct printing method.

Dye mixtures containing azo and quinophthalone dyes

Thiopheneazo dye I which are chiefly useful as disperse dyes for dyeing textile material, in particular polyesters, have the formula ##STR1## where the substituents are as defined in the description.

Azo dyes with A2-aminothiophene dye azo component and a coupling

Navy and black dye mixtures contain one or more thiopheneazo dyes whose diazo component comes from the 2-aminothiophene series and whose coupling component comes from the aniline series and one or more dyes F whose absorption maximum is at a wavelength of from 390 to 520 nm, the proportion of the thiopheneazo dyes being from 60 to 99% by weight, based on the total weight of the thiopheneazo dyes and the dyes F in the mixture.

Novel navy and black disperse dye mixtures including amino-phenyl

A vat dye based on monobromofluoranthene is prepared by a process in which monobromofluoranthene which contains no more than 7% of dibromofluoranthene is reacted with 1-amino-4-benzoylaminoanthraquinone, the reaction product is condensed at from 50.degree. to 70.degree. C. in 83-88% strength sulfuric acid to give the carbazole compound, and the latter is then further brominated to a bromine content of from 20 to 23% by weight. The dyes obtained by the novel process are very useful for dyeing cotton.

Vat dye based on flouranthene

Navy and black dye mixtures contain one or more thiophene-azo dyes of the formula ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, X and Y each have defined meanings, and one or more dyes F whose absorption maximum is at a wavelength of from 390 to 520 nm, the proportion of thiophene-azo dyes being from 60 to 99% by weight, based on the total weight of thiophene-azo dyes and dyes F in the mixture.

Navy and black dye mixtures: thiophene azo disperse dye and red, yellow

Mixtures of dyes of the formula I ##STR1## where X is chlorine or bromine, Z is hydrogen, methyl, ethyl, C.sub.1 -C.sub.4 -alkoxy or acetylamino, R is C.sub.1 -C.sub.4 -alkyl, R.sup.1 and R.sup.2 independently of one another are each allyl or methallyl or are each C.sub.1 -C.sub.6 -alkyl which is unsubstituted or substituted by hydroxyl, C.sub.1 -C.sub.4 -alkoxy or alkanoyloxy, or R.sup.1 and R.sup.2 together with the nitrogen atom are morpholino or tetra-, penta- or hexamethyleneimino, and one of the radicals R.sup.1 and R.sup.2 may furthermore be hydrogen.

Navy blue mixtures of disperse mono-azo dyes for cellulose acetate

Navy dye mixtures essentially contain dyes of the formula I ##STR1## where X is hydrogen, chlorine or bromine, the radicals R.sup.1 independently of one another are each methyl or ethyl and R is a radical of the formula ##STR2## where A is ##STR3## B is unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, phenyl-C.sub.1 -C.sub.4 -alkyl, phenoxy-C.sub.2 - or -C.sub.3 -alkyl or cyclohexyl and R.sup.2 is C.sub.1 -C.sub.4 -alkyl, the mixtures containing from 20 to 80 parts of dyes in which R is NH-A-COOB and from 80 to 20 parts of dyes in which R is ##STR4## The novel mixtures are very useful for dyeing synthetic polyesters, and give dyeings which have, in particular, very good heatfastness.

Navy dye mixtures

Dye mixtures which comprise two or more dyes of the formula ##STR1## ps where X is hydrogen, methyl or chlorine, and R is a radical of the formula OR.sup.1, OCOCH.sub.3, OCOC.sub.2 H.sub.5, R.sup.1 being hydrogen or C.sub.1 -C.sub.4 -alkyl, are very useful for dyeing cellulose esters.

Mixtures of benzisothiazole mono-azo dyes for cellulose acetate

Navy mixtures which contain dyes of the formula I ##STR1## where X is chlorine or bromine,

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Frankenthal, Germany

Helmut Degen