Gs Yuasa International Ltd.

Heisuke Nishikawa

Shuji Hitomi

Kaname Nakajima

A nonaqueous electrolyte secondary battery includes a sulfur-containing positive electrode, a negative electrode, a nonaqueous electrolyte, and a cation exchange resin layer which is disposed between the positive electrode and the negative electrode and has a first surface having a roughness factor of 3 or more. A method for producing a nonaqueous electrolyte secondary battery includes a sulfur-containing positive electrode, a negative electrode, and a cation exchange resin layer which is interposed between the positive electrode and the negative electrode and has a first surface having a roughness factor of 3 or more. The method includes injecting a lithium polysulfide-containing positive electrode electrolyte between the positive electrode and the cation exchange resin layer, and injecting a negative electrode electrolyte between the negative electrode and the cation exchange resin layer, the negative electrode electrolyte having a lithium polysulfide concentration lower than that of the positive electrode electrolyte.

Nonaqueous electrolyte secondary battery

One aspect of the present invention provides a nonaqueous electrolyte secondary battery including a sulfur-containing positive electrode, a negative electrode, a cation exchange resin layer interposed between the positive electrode and the negative electrode, a positive electrode electrolyte, and a negative electrode electrolyte. The positive electrode electrolyte contains lithium polysulfide, and a sulfur equivalent concentration of the positive electrode electrolyte is higher than the sulfur equivalent concentration of the negative electrode electrolyte. Another aspect of the present invention provides a nonaqueous electrolyte secondary battery including a sulfur-containing positive electrode, a negative electrode, a cation exchange resin layer interposed between the positive electrode and the negative electrode, and a nonaqueous electrolyte. At least one of the positive electrode and the negative electrode includes a cation exchange resin, and a concentration of an anion contained in the nonaqueous electrolyte is 0.7 mol/l or less.

A sulfur-carbon composite in which sulfur is combined with porous carbon is provided. In the sulfur-carbon composite, a mass loss ratio X at 500&#xb0; C. in thermal mass analysis and a mass ratio Y of sulfur/(sulfur+carbon) in an observation visual field at a magnification of 1000 in SEM-EDS quantitative analysis satisfy the relationship of |X/Y&#x2212;1|&#x2264;0.12, and porous carbon has a mean pore diameter of 1 to 6 nm, and a specific surface area of 2000 mgor more and 3000 mgor less.

Sulfur-carbon composite, nonaqueous electrolyte battery including electrode containing sulfur-carbon composite, and method for producing sulfur-carbon composite

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Kyoto, Japan

Heisuke Nishikawa