Basf Aktiengesellschaft

Heinz Stritzinger

Manfred Ohlinger

Eduard Schoenafinger

Guenter Vaeth

Job-Werner Hartmann

Walter Schneider

Fritz Hammon

Werner Steck

Eberhard Koester

Dieter Schaefer

Hans Henning Schneehage

Manfred Steuerwald

Gerhard Wagner

Ursula Klein

Eugen Wettstein

Gerhard Honecker

Heinz Spaehn

Philipp Pister

Egon Von Gross

Franz Buettner

Wolfgang Guth

Horst Grosselfinger

A flexible multilayer magnetic recording medium exhibiting an improved signal-to-print-through ratio coupled with an improved maximum output level and diminished dc noise, comprising a non-magnetic base and, applied thereto, at least two superposed layers consisting of a binder with magnetizable particles uniformly dispersed therein, the upper magnetic layer containing a magnetic pigment giving a signal-to-print-through ratio of less than 55db and the lower magnetic layer(s) containing a magnetic pigment giving a signal-to-print-through ratio of 55 db or more.

Flexible multilayer magnetic recording medium

Flexible multi-layer magnetic recording media comprising a non-magnetic flexible base and, applied thereto, two superposed magnetizable layers which contain a homogeneous mixture of acicular magnetic chromium dioxide in an organic binder. According to the invention, the magnetizable layer adjacent to the base contains a chromium dioxide having a specific surface area, measured by the BET method, of from 15 to 25 m.sup.2 /g, while the outer magnetic layer contains a chromium dioxide having a specific surface area, measured by the BET method, of from 26 to 35 m.sup.2 /g. Such magnetic recording media are distinguished by uniformly high sensitivity over the entire audible frequency range even if close manufacturing tolerances are not maintained.

Flexible multi-layer magnetic recording media

In order to reduce corrosion of the inside walls of a reactor made of iron or an iron alloy and used for the synthesis of chromium dioxide by hydrothermal conversion of chromium(VI) oxide with chromium oxides of lower valency, lead or bismuth is added at those points of the reactor at which an aqueous phase occurs during conversion and which do not contact the chromium oxides to be converted. The lead or bismuth may be used in metallic form or in the form of their oxides, hydroxides or salts.

Reducing corrosion in reactors used for the synthesis of chromium dioxide

Acicular .gamma.-iron(III) oxide is manufactured by reacting an iron(II) salt solution with aqueous solutions of alkali metal hydroxides and oxidizing the resulting suspension of iron(II) hyroxides in 3 stages. In the first stage not more than 8 percent by weight of the iron(II) hydroxide originally present is oxidized over a period of 0.5 to 4 hours, in the second stage from 25 to 55 percent by weight over a period of 1.5 to 6 hours and the remainder thereof in a third stage. Following this oxidation, the goethite formed is reduced to magnetite, which is then oxidized to acicular .gamma.-iron(III) oxide.

Manufacture of .gamma.-iron(III) oxide

Goethite is obtained by reacting an aqueous solution of an iron (II) salt with an aqueous solution of an alkali metal hydroxide and oxidizing the resulting iron(II) hydroxide. The oxidation is carried out in three stages. In the first stage, from 4 to 15% by weight are oxidized in the course of from 0.4 to 5 hours, in the second stage from 60 to 85% by weight are oxidized in the course of from 1.5 to 6 hours and in a third stage the remaining amount of iron is oxidized.

Manufacture of acicular .gamma.-iron(III) oxide

Acicular gamma-iron(III) oxide is manufactured by reacting an iron(II) salt solution with an aqueous solution of an alkali metal hydroxide and oxidizing the resulting suspension of iron(II) hydroxide in three stages. In a first stage, at most from 0.1 to 4% by weight of the amount of iron(II) hydroxide originally present is oxidized in the course of from 0.1 to 4 hours, in a second stage from 10 to 25% by weight of the said original amount are oxidized in the course of from 1.5 to 6 hours and in a third stage the remaining amount is oxidized. After the oxidation, the goethite formed is reduced to magnetite and the latter is then oxidized to acicular gamma-iron(III) oxide.

Manufacture of gamma-iron(III) oxide

Magnetic recording media comprising a non-magnetizable flexible base and a firmly adhering magnetic coating based on a dispersion, containing a silane, of a magnetic pigment in a polymeric binder, and a process for their manufacture. The silane is an aminoalkylsilane R.sub.n Si(OR').sub.4-n, wherein n is 1, 2 or 3, R' is alkyl of 1 to 8 carbon atoms and R is aminoalkyl of the formula with one or more primary and/or secondary amino groups and from 3 to 11 carbon atoms. Magnetic recording media comprising a magnetic coating containing such a silane exhibit better abrasion resistance and better electromagnetic properties than comparable coatings.

Magnetic recording media

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Ludwigshafen, Germany

Heinz Stritzinger