Vdm Metals International Gmbh

Outokumpu Vdm Gmbh

Voestalpine Grobblech Gmbh

Forschungszentrum Julich Gmbh

Zenergy Power Gmbh

Vdm Metals Gmbh

Thyssenkrupp Vdm Gmbh

Heike Hattendorf

Jutta Kloewer

Bodo Gehrmann

Ralf Hojda

Nicole De Boer

Werner Theisen

Christina Schmidt

Stefan Gilges

Michael Bäcker

Willem Quadakkers

Andreas Heckmann

Nilofar Nabiran

Frank Scheide

Larry Paul

Claudius Schindler

Jörg Eickemeyer

Juergen Kiese

Jürgen Kiese

Benedikt Nowak

Franz Winter

Bernd Kuhn

Thomas Eckardt

Franz-Josef Wahlers

Tilmann Beck

Angelika Kolb-Telieps

Rainer Rüffert

Osman Ibas

Janine Lindemann

Juergen Webelsiep

Jutta KLÖWER

Jürgen Webelsiep

Willem Joe Quadakkers

A nickel-chromium-aluminum alloy includes (in mass %) 12 to 30% chromium, 1.8 to 4.0% aluminum, 0.1 to 7.0% iron, 0.001 to 0.50% silicon, 0.001 to 2.0% manganese, 0.00 to 1.00% titanium, 0.00 to 1.10% niobium, 0.00 to 0.5% copper, 0.00 to 5.00% cobalt, in each case 0.0002 to 0.05% magnesium and/or calcium, 0.001 to 0.12% carbon, 0.001 to 0.050% nitrogen, 0.001 to 0.030% phosphorus, 0.0001 to 0.020% oxygen, max. 0.010% sulfur, max. 2.0% molybdenum, max. 2.0% tungsten, and a remainder of nickel with a minimum content of ≥50% and the usual process-related impurities for use in solar power towers, using chloride and/or carbonate salt melts as a heat transfer medium, wherein in order to ensure a good processability, the following condition must be met: Fv≥0.9 with Fv=4.88050−0.095546*Fe−0.0178784*Cr−0.992452*AI−1.51498*Ti−0.506893*Nb+0.0426004*AI*Fe, where Fe, Cr, AI, Ti, and Nb are the concentration of the respective elements in mass %.

Nickel-chromium-aluminum alloy with good processability, creep resistance, and corrosion resistance, and use thereof

A roll-bonded clad metal sheet and a method for producing a roll-bonded clad metal sheet is provided. The roll-bonded clad sheet includes a metallic base material layer and a metallic cladding material layer which are joined to one another by a metallurgical bond. The metallic cladding material layer includes a nickel-based material whose chemical composition includes, in % by mass, a proportion of more than 50% of Ni and a proportion of 3.1% of Nb. The metallurgical bond is obtained by a thermomechanical rolling process including a first rolling phase for prerolling, a second rolling phase for final forming and a cooling time between the first rolling phase and the second rolling phase, wherein a final rolling temperature of the second rolling phase is set to a value equal to or less than 880&#xb0; C.

Method for producing roll-bonded metal sheets

A high-temperature nickel-base alloy consists of (in wt. %): C: 0.04-0.1%, S: max. 0.01%, N: max. 0.05%, Cr: 24-28%, Mn: max. 0.3%, Si: max. 0.3%, Mo: 1-6%, Ti: 0.5-3%, Nb: 0.001-0.1%, Cu: max. 0.2%, Fe: 0.1-0.7%, P: max. 0.015%, Al: 0.5-2%, Mg: max. 0.01%, Ca: max. 0.01%, V: 0.01-0.5%, Zr: max. 0.1%, W: 0.2-2%, Co: 17-21%, B: max. 0.01%, O: max. 0.01%, with the rest being Ni, as well as melting-related impurities.

High-temperature nickel-base alloy

A nickel-chromium-aluminum alloy as powder is used for additive manufacturing, wherein the powder consists of spherical particles of a size of 5 to 250 pm, and wherein this alloy consists of (in % by weight) 24 to 33% chromium, 1.8 to 4.0% aluminum, 0.10 to 7.0% iron, 0.001 to 0.50% silicon, 0.005 to 2.0% manganese, 0.00 to 0.60% titanium, 0.0 to 0.05% magnesium and/or calcium respectively, 0.005 to 0.12% carbon, 0.001 to 0.050% nitrogen, 0.00001-0.100% oxygen, 0.001 to 0.030% phosphorus, a maximum of 0.010% sulfur, a maximum of 2.0% molybdenum, a maximum of 2.0% tungsten, the remainder nickel and the usual process-related impurities, wherein, with a pore size &#x3e;1 pm, the powder has total inclusions of 0.0-4% of the pore surface area.

Use of a nickel-chromium-iron-aluminum alloy

Hardened nickel-chromium-titanium-aluminum wrought alloy contains, (in mass %) 5-35% chromium, 1.0-3.0% titanium, 0.6-2.0% aluminum, 0.005-0.10% carbon, 0.0005-0.050% nitrogen, 0.0005-0.030% phosphorus, max. of each (next eleven) 0.010% sulfur 0.020% oxygen 0.70% silicon 2.0% manganese 0.05% magnesium 0.05% calcium 2.0% molybdenum 2.0% tungsten 0.5% niobium 0.5% copper 0.5% vanadium, 0-20% Fe, 0-15% cobalt, 0-0.20% Zr, 0.0001-0.008% boron, the remainder nickel and usual impurities. The nickel content is greater than 35%.Cr+Fe+Co&#x2265;26% fh&#x2265;0 fh=6.49+3.88 Ti+1.36 Al&#x2212;0.301 Fe+(0.759&#x2212;0.0209 Co) Co&#x2212;0.428 Cr&#x2212;28.2 C.

Hardened nickel-chromium-titanium-aluminum alloy with good wear resistance, creep resistance, corrosion resistance and workability

A method for producing a metal film from an over 50% nickel alloy melts more than one ton of the alloy in a furnace, followed by VOD or VLF system treatment, then pouring off to form a pre-product, followed by re-melting by VAR and/or ESU. The pre-product is annealed 1-300 hours between 800 and 1350&#xb0; C. under air or protection gas, then hot-formed between 1300 and 600&#xb0; C., such that the pre-product then has 1-100 mm thickness after the forming and is not recrystallized, recovered, and/or (dynamically) recrystallized having a grain size below 300 &#x3bc;m. The pre-product is pickled, then cold-formed to produce a film having 10-600 &#x3bc;m end thickness and a deformation ratio greater than 90%. The film is cut into 5-300 mm strips, annealed 1 second to 5 hours under protection gas between 600 and 1200&#xb0; C. in a continuous furnace, then recrystallized to have a high cubic texture proportion.

Method for producing a metal film

Age-hardening nickel-chromium-cobalt-titanium-aluminum wrought alloy with very good wear resistance combined with very good creep strength, good high-temperature corrosion resistance and good processability, the alloy including (in % by mass) &#x3e;18 to 26% chromium, 1.5 to 3.0% titanium, 0.6 to 2.0% aluminum, 5.0 to 40% cobalt, 0.005 to 0.10% carbon, 0.0005 to 0.050% nitrogen, 0.0005 to 0.030% phosphorus, max. 0.010% sulfur, max. 0.020% oxygen, max. 0.70% silicon, max. 2.0% manganese, max. 0.05% magnesium, max. 0.05% calcium, max. 0.5% molybdenum, max. 0.5% tungsten, max. 0.2% niobium, max. 0.5% copper, max. 0.5% vanadium, optionally 0 to 20% Fe, optionally 0 to 0.20% Zr, optionally 0.0001 to 0.008% boron, optionally 0-0.20% Y, La, Ce, Ce mixed metal, and/or Hf, and/or 0-0.60% Ta, remainder nickel and the conventional process-related impurities are adjusted in contents of max. 0.002% Pb, max. 0.002% Zn, max. 0.002% Sn, wherein the nickel content is greater than 35%, wherein the relationship Cr+Fe+Co&#x2265;25% (1) has to be satisfied in order to achieve good wear resistance, and the relationship fh&#x2265;0 (2a), where fh=6.49+3.88 Ti+1.36 Al&#x2212;0.301 Fe+(0.759&#x2212;0.0209 Co) Co&#x2212;0.428 Cr&#x2212;28.2 C, (2) has to be satisfied in order that an adequate strength at higher temperatures is provided, wherein Ti, Al, Fe, Co, Cr and C are the concentration of the elements in question in % by mass and fh is given in %.

Hardening nickel-chromium-iron-titanium-aluminium alloy with good wear resistance, creep strength, corrosion resistance and processability

An iron-chromium-aluminum alloy with improved heat resistance, low chromium vaporization rate and good processability, comprising (in % by mass), 2.0 to 4.5% Al, 12 to 25% Cr, 1.0 to 4% W, 0.25 to 2.0% Nb, 0.05 to 1.2% Si, 0.001 to 0.70% Mn, 0.001 to 0.030% C, 0.0001 to 0.05% Mg, 0.0001 to 0.03% Ca, 0.001 to 0.030% P, max. 0.03% N, max. 0.01% S, remainder iron and the usual melting-related impurities.

Heat-resistant iron-chromium-aluminum alloy with low chromium vaporization rate and elevated thermal stability

A nickel-based alloy, consisting of (in mass %) 1.5-3.0% Si, 1.5-3.0% Al, and &#x3e;0.1-3.0% Cr, where Al+Si+Cr is &#x2265;4.0 and &#x2264;8.0 for the contents of Si, Al, and Cr in %; 0.005-0.20% Fe, 0.01-0.20% Y, and &#x3c;0.001-0.20% of one or more the elements Hf, Zr, La, Ce, Ti, where Y+0.5*Hf+Zr+1.8*Ti+0.6*(La+Ce) is &#x2265;0.02 and &#x2264;0.30 for the contents of Y, Hf, Zr, La, Ce, and Ti in %; 0.001-0.10% C; 0.0005-0.10% N; 0.001-0.20% Mn; 0.0001-0.08% Mg; 0.0001-0.010% O; max. 0.015% S; max. 0.80% Cu; Ni remainder; and the usual production-related impurities.

Nickel-based alloy with silicon, aluminum, and chromium

A nickel-chromium-aluminum-iron alloy includes (in wt.-%) 24 to 33% chromium, 1.8 to 4.0% aluminum, 0.10 to 7.0% iron, 0.001 to 0.50% silicon, 0.005 to 2.0% manganese, 0.00 to 0.60% titanium, 0.0002 to 0.05% each of magnesium and/or calcium, 0.005 to 0.12% carbon, 0.001 to 0.050% nitrogen, 0.0001 to 0.020% oxygen, 0.001 to 0.030% phosphorus, not more than 0.010% sulfur, not more than 2.0% molybdenum, not more than 2.0% tungsten, the remainder nickel and the usual process-related impurities, wherein the following relations must be satisfied: Cr+Al&#x2267;28 (2a) and Fp&#x2266;39.9 (3a) with Fp=Cr+0.272*Fe+2.36*Al+2.22*Si+2.48*Ti+0.374*Mo+0.538*W&#x2212;11.8*C (4a), wherein Cr, Fe, Al, Si, Ti, Mo, W and C is the concentration of the respective elements in % by mass.

Nickel-chromium-aluminum alloy having good processability, creep resistance and corrosion resistance

The invention relates to a nickel-chromium alloy comprising (in wt.-%) 29 to 37% chromium, 0.001 to 1.8% aluminum, 0.10 to 7.0% iron, 0.001 to 0.50% silicon, 0.005 to 2.0% manganese, 0.00 to 1.00% titanium and/or 0.00 to 1.10% niobium, 0.0002 to 0.05% each of magnesium and/or calcium, 0.005 to 12% carbon, 0.001 to 0.050% nitrogen, 0.001 to 0.030% phosphorus, 0.0001 to 0.020% oxygen, not more than 0.010% sulfur, not more than 2.0% molybdenum, not more than 2.0% tungsten, the remainder nickel and the usual process-related impurities, wherein the following relations must be satisfied: Cr+Al&#x2267;30 (2a) and Fp&#x2266;39.9 (3a) with Fp=Cr+0.272*Fe+2.36*Al+2.22*Si+2.48*Ti+0.374*Mo+0.538*W&#x2212;11.8*C (4a), wherein Cr, Fe, Al, Si, Ti, Mo, W and C is the concentration of the respective elements in % by mass.

Nickel-chromium alloy having good processability, creep resistance and corrosion resistance

The invention relates to a nickel-chromium-aluminum-iron alloy, comprising (in wt %) 12 to 28% chromium, 1.8 to 3.0% aluminum, 1.0 to 15% iron, 0.01 to 0.5% silicon, 0.005 to 0.5% manganese, 0.01 to 0.20% yttrium, 0.02 to 0.60% titanium, 0.01 to 0.2% zirconium, 0.0002 to 0.05% magnesium, 0.0001 to 0.05% calcium, 0.03 to 0.11% carbon, 0.003 to 0.05% nitrogen, 0.0005 to 0.008% boron, 0.0001 to 0.010% oxygen, 0.001 to 0.030% phosphorus, max. 0.010% sulfur, max. 0.5% molybdenum, max. 0.5% tungsten, the remainder nickel and the common contaminants resulting from the process, wherein the following relations must be satisfied: 7.7C&#x2212;x&#xb7;a&#x3c;1.0, wherein a=PN if PN&#x3e;0 or a=0 if PN&#x2266;0. Here, x=(1.0 Ti+1.06 Zr)/(0.251 Ti+0.132 Zr), PN=0.251 Ti+0.132 Zr&#x2212;0.857 N, and Ti, Zr, N, and C are the concentration of the respective element in mass percent.

Nickel&#x2014;chromium&#x2014;iron&#x2014;aluminum alloy having good processability

Nickel-based alloy consisting of (in % by mass) Si 0.8-2.0%, Al 0.001-0.1%, Fe 0.01-0.2%, C 0.001-0.10%, N 0.0005-0.10%, Mg 0.0001-0.08%, O 0.0001-0.010%, Mn max. 0.10%, Cr max. 0.10%, Cu max. 0.50%, S max. 0.008%, balance Ni and the usual production-related impurities.

Nickel-based alloy

An iron-chromium-aluminum alloy having a long service life and exhibiting little change in heat resistance, comprising (as percentages by weight) 4.5 to 6.5% Al, 16 to 24% Cr, 1.0 to 4.0% W, 0.05 to 0.7% Si, 0.001 to 0.5% Mn, 0.02 to 0.1% Y, 0.02 to 0.1% Zr, 0.02 to 0.1% Hf, 0.003 to 0.030% C, 0.002 to 0.03% N, a maximum of 0.01% S, and a maximum of 0.5% Cu, the remainder being iron and the usual steel production-related impurities.

Growing community of inventors

Werdohl, Germany

Heike Hattendorf