Enevate Corporation

Heidi Leighette Anderson

Benjamin Yong Park

Liwen Ji

Sung Won Choi

Ian Russell Browne

Frederic C Bonhomme

Hong Gan

Hong Zhao

Younes Ansari

David J Lee

Jill Renee Pestana

Mya Le Thai

Vincent Giordani

Rahul R Kamath

Monika Chhorng

Genis Turon Teixidor

Fred Bonhomme

Sanjaya D Perera

Samuel Keene

Qian Huang

Sung Ju Cho

Myunghwan Jeong

Daniel Sylvinson Muthiah Ravinson

Electrolytes and electrolyte additives for use in energy storage devices, comprising cyclic carbonate compounds.

Silicon-based energy storage devices with cyclic carbonate containing electrolyte additives

Electrolytes and electrolyte additives for energy storage devices comprising crown ether based compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte comprising at least two electrolyte co-solvents, wherein at least one electrolyte co-solvent comprises a crown ether based compound.

Silicon-based energy storage devices with electrolyte containing crown ether based compounds

An energy storage device comprising a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode comprises a self-supporting composite material film, a separator between the first electrode and the second electrode, and an electrolyte in contact with the first electrode, the second electrode, and the separator, wherein the electrolyte comprises at least one of a fluorine-containing cyclic carbonate, a fluorine-containing linear carbonate, and a fluoroether. The composite material film having greater than 0% and less than about 90% by weight of silicon particles, and greater than 0% and less than about 90% by weight of one or more types of carbon phases. At least one of the one or more types of carbon phases can be a substantially continuous phase that holds the composite material film together such that the silicon particles are distributed throughout the composite material film.

Electrolyte compositions for batteries

Methods of forming electrochemical cells are described. In some implementations, the method can include providing an electrochemical cell having an electrode including electrochemically active material with at least about 20% to about 100% by weight of silicon. The method can include charging the electrochemical cell by providing a formation charge current at about 1 C or greater to the electrochemical cell. The method can also include discharging the electrochemical cell. In various implementations, substantially no rest of greater than about 5 minutes occurs between charging and discharging.

Methods of forming electrochemical cells

Methods and system for forming electrochemical cells are provided. An electrochemical cell may be formed by providing an electrochemical cell that includes a first electrode and a second electrode, a separator between the first electrode and the second electrode, and an electrolyte, with at least the first electrode is a silicon-dominant electrode. A formation process may then performed, with the formation processing including charging the electrochemical cell by providing a formation charge current at about 1 C or greater to the electrochemical cell, and discharging the electrochemical cell after a rest step between the charging and the discharging.

Various implementations of a method of forming an electrochemical cell include providing a first electrode, a second electrode, a separator between the first and second electrodes, and an electrolyte in a cell container. The first electrode can include silicon-dominant electrochemically active material. The silicon-dominant electrochemically active material can include greater than 50% silicon by weight. The method can also include exposing at least a part of the electrochemical cell to CO, and forming a solid electrolyte interphase (SEI) layer on the first electrode using the CO.

Surface modification of silicon-containing electrodes using carbon dioxide

Systems and methods for batteries comprising a cathode, an electrolyte, and an anode, wherein sacrificial salts and prelithiation reagents are added to the cathode as functional additives for electrochemical prelithiation.

Sacrificial salts in Li-rich, defect anti-fluorite compounds in cathodes for prelithiation in lithium ion batteries

Systems and methods for batteries comprising a cathode, an electrolyte, and an anode, where prelithiation reagents are utilized to treat one or more of the anode and cathode. In one embodiment, the prelithiation reagent is a Li-organic complex solution comprising naphthalene and metallic lithium dissolved in an inhibitor-free THF.

Prelithiation of free-standing silicon dominant anode batteries

Methods of forming electrochemical cells are described. In some implementations, the method can include providing an electrochemical cell having an electrode with at least about 20% to about 99% by weight of silicon. The method can include providing a formation charge current at a first rate and at a second rate to the electrochemical cell. The first rate can be in a range from about C/100 to about C/10 and the second rate can be greater than about C/10.

Methods of forming electrochemical cells with a combination formation charge rate

Electrolyte formulations for energy storage devices are disclosed. The energy storage device comprises a first electrode and a second electrode, where one or both of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, and an electrolyte composition. Electrolyte formulations as described herein are electrolyte compositions comprising two or more components such as solvents, co-solvents, salts and/or additives. In some embodiments, three or more, four or more, five or more, six or more, seven or more, or eight or more components are included in the electrolyte composition.

Electrolyte formulations for optimal performance in Si-containing lithium ion batteries

Electrolytes and electrolyte additives for energy storage devices comprising phosphorus based compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte comprising at least two electrolyte co-solvents, wherein at least one electrolyte co-solvent comprises a phosphorus based compound.

Silicon-based energy storage devices with phosphorus containing electrolyte additives

Electrolytes and electrolyte additives for energy storage devices comprising an ether compound are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte, and at least one electrolyte additive selected from ether compounds.

Silicon-based energy storage devices with ether containing electrolyte additives

Methods and systems for forming electrochemical cells are provided. An electrochemical cell may be provided, with the electrochemical cell including a first electrode, a second electrode, a separator between the first electrode and the second electrode, and an electrolyte. At least the first electrode is a silicon-dominant electrode. A formation process may be used for the electrochemical cell, with the processing including at least a charge step that includes providing a formation charge current at greater than about 1C to the electrochemical cell, where providing the formation charge current includes charging to a partial formation.

Electrolytes and electrolyte additives for energy storage devices comprising linear carbonate compounds.

Silicon-based energy storage devices with linear carbonate containing electrolyte additives

Electrolytes and electrolyte additives for energy storage devices comprising fluorinated polymers. The electrolytes may be used in an energy storage device comprising a first electrode and a second electrode, where at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, and the electrolyte.

Growing community of inventors

Laguna Beach, CA, United States of America

Heidi Leighette Anderson