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Sambu Fine Chemical Co., Ltd.

Park, Heedae

Heedae Park

A present invention related to a method for manufacturing a dot bonding shoe insole using an adhesive resin containing hydrophobic nano-silica, including:

Dot bonding shoe insole using adhesive resin mixed with hydrophobic nano-silica and manufacturing thereof

The present invention relates to a method of manufacturing a foam sheet for shoes containing recycled PU scrap powder, the method of manufacturing the foam sheet, including eco-friend Polyurethane (PU) foam composition prepared by water foam, is provided by first mixing recycled PU scrap powder with polyol and then reacting with the secondary addition of recycled PU scrap powder by controlling the process conditions and processing speed through a side-feeder, it is possible to prevent the viscosity of the raw material from rising, so that even if a larger amount (less than 60 wt %) of recycled material is used than before, the quality of the product is equivalent to that of conventional shoe insoles or shoe uppers.

Producing method of foam sheet for shoe with recycled PU scrap powder

The present invention relates to a manufacturing method for a foam sheet for shoes containing Thermoplastic polyurethane (TPU) powder and recycled Polyurethane (PU) scrap powder, and for an eco-friendly polyurethane foam composition including water foam, firstly the recycled PU scrap powder is mixed with polyol, and then the processing speed in a process is controlled through a side-feeder to react while adding the TPU powder and recycled PU scrap powder secondarily, thereby preventing a rise in viscosity of the raw material, so that even if a larger amount of recycled materials is used than before, it is possible to form foam sheets for shoes, such as shoe insoles or foam packages for shoe uppers, with the same level of product quality as conventional products.

Manufacturing method of foam sheet for shoes with TPU powder and recycled PU scrap powder

A thermoplastic polyurethane coated yarn having excellent adhesive strength in which hydrophobic nano-silica is mixed. The nano-silica is contained in the range of 0.2-5 parts per hundred resin (phr) and the nano-silica having a primary particle size of in a range of 1-100 nm. The thermoplastic polyurethane coating yarn mixed with the hydrophobic nano-silica of the present invention is uniformly coated with a thermoplastic polyurethane resin containing nano-silica containing a hydrophobic functional group on the surface of the core yarn, whereby the core yarn is biased to one side. Since no coating or uncoating occurs, the product quality and productivity are excellent, in addition to excellent durability and wear resistance of the thermoplastic polyurethane, mechanical strength and chemical resistance are improved.

Hydrophobic nano-silica mixed thermoplastic polyurethane coated yarn

The present invention relates to a hot melt film containing a biomass-based thermoplastic polyurethane resin, and is not only environmentally friendly to the human body as it contains a biomass-based thermoplastic polyurethane resin prepared by reacting a biomass-derived polyol with a diol-based chain extender and diisocyanate in a range of 20-70% by weight, accordingly, by containing hydrophobic nano-silica, it is possible to secure properties such as excellent high heat resistance, elasticity, uniform adhesion strength, and excellent durability at the petroleum-based level, and also provides a hot melt film containing a biomass-based thermoplastic polyurethane resin that can prevent overflow during the bonding process and improve the weight and texture of the product.

Hot melt film containing biomass-based thermoplastic polyurethane resin

A present invention related to a method for manufacturing a dot bonding shoe insole using an adhesive resin containing hydrophobic nano-silica, including: melting adhesive resin made of any one selected from thermoplastic polyurethane (TPU) or ethylene vinyl acetate (EVA) containing hydrophobic nano-silica in the range of 0.2 to 5 phr and applying to the surface of the transfer roller in which the intaglio dot pattern is formed in a mesh shape in the shape of the shoe insole; removing the adhesive resin applied other area than the intaglio dot pattern of the surface of the transfer roller; transferring the adhesive resin applied to the intaglio dot pattern of the surface of the transfer roller to either one of the foam or the fabric; bonding the foam and the fabric by compressing; and cutting a shoe insole shape in a package in which the foam and the fabric are bonded.

Disclosed is a method of producing a fabric product, the method comprising preparing an upper; preparing a lining fabric; layering a thermoplastic hot-melt film between the upper and the lining fabric for bonding the upper and the lining fabric; bonding a lining fabric to the upper, wherein the thermoplastic hot-melt film consists of the composition selected from the group consisting of thermoplastic polyurethane, ethylene vinyl acetate, polyamide and polyester compositions, wherein the thermoplastic hot-melt film further contains nanosilica, wherein a content of the nanosilica is 0.1 to 5.0 Parts per Hundred Resin (phr) and a size of the nanosilica is less than 100 nm.

Method for manufacturing TPU hot-melt film and method of producing a fabric product using the TPU hot-melt film

The thermoplastic polyurethane yarn of the present invention is excellent in abrasion resistance and durability because it contains thermoplastic polyurethane and nanosilica particles having hydrophobic functional groups on the surface thereof and is excellent in durability of a fine denier yarn, and can have a yarn in a form of continuous yarn without breaking yarn development during spinning or stretching. In particular, it is excellent in color dispersibility, antifouling property, scratch resistance, moldability, and the like.

Thermoplastic polyurethane yarn

Disclosed is a nanosilica-containing thermoplastic hot-melt film having excellent bonding strength, which may be inserted between fabrics to adhere them to each other and may be distributed uniformly on the surfaces of both the fabrics without excessively penetrating into one of the fabrics after melting by heat and pressure during no-sew pressing even if the yarn density of the fabrics is high or low or even if the hole diameter of the fabrics is large or small, thereby increasing the bonding strength between the fabrics.

Nanosilica-containing thermoplastic hot-melt film having excellent bonding strength

The present invention provides a resin for thermoplastic polyurethane (TPU) yarn using nanosilica and a method for manufacturing the same. Nanosilica having a particle size of 100 nm or less is added as a thickening agent for improving productivity and glossiness of TPU yarns, such as mono-filament TPU yarns having a denier count of 50 to 350 or multi-filament TPU yarns having a denier count of 50 or less. No TPU coating is needed for applying to the surface of polyester or nylon yarns, thereby securing desired workability and properties and realizing continuous drawing of TPU yarns without thread breakage. The content of nanosilica at least from 0.1 or 0.3 to 7 phr, or a non-zero content of 7 phr or less in TPU resin is optimal for productivity of mono- or multi-filament yarns. The content of nanosilica from 0.5 to 1.5 phr is optimum for both productivity and cost reduction.

Core-free thermoplastic polyurethane yarn with added nanosilica

The present invention relates to a thermoplastic hot melt film having excellent adhesive strength in which hydrophobic nanosilica is mixed. The resin composition contains nanosilica having a particle size of 1 to 100 nm and containing hydrophobic functional groups on its surface in the range of 0.1 to 5 phr (Parts per Hundred Resin), and the nanosilica forms nanosilica aggregates with an average size of the aggregates is within 100&#x2dc;1200 nm. The thickness of the thermoplastic hot melt film is 0.02&#x2dc;0.3 mm. The thermoplastic hot melt film of the present invention is mixed with nanosilica containing hydrophobic functional groups, lipophilic, on the surface to improve dispersibility, strengthen water resistance, and increase tensile strength. The material cost is reduced while securing one adhesive strength and excellent durability, and multi-press molding is possible, which has the effect of increasing energy saving and productivity.

Hydrophobic nano silica mixed thermoplastic hot-melt film with excellent adhesive strength

The present invention provides a resin for thermoplastic polyurethane (TPU) yarn using nanosilica and a method for manufacturing the same, where nanosilica having a particle size of 100 nm or less is added as a thickening agent for improving productivity in the production of and glossiness of TPU yarns, such as mono-filament TPU yarns having a denier count of 50 to 350 or multi-filament TPU yarns having a denier count of 50 or less without applying a coating of TPU to the surface of polyester or nylon yarns, thereby securing desired workability and properties and realizing continuous drawing of TPU yarns without thread breakage. The content of nanosilica from 0.3 to 7 phr in TPU resin is optimal for productivity of mono- or multi-filament yarns, whereas the content of nanosilica from 0.5 to 1.5 phr is optimum for both productivity and cost reduction.

Disclosed is a composition for reactive hot melt resin and a reactive hot melt film prepared from the resin, which resin composition includes a polyurethane resin having a linear structure, an isocyanate blocking agent having a plurality of functional groups, a reaction catalyst, a reaction retardant, etc. Preferably, the resin composition includes a polyurethane resin and an isocyanate blocking agent used as a latent curing agent, which are main components; a catalyst for accelerating the reaction; and a reaction retardant for securing long-term storability. Particularly, the composition for reactive hot melt resin further includes a heat-resistance enhancer, preferably nanosilica, for preventing the resin from melting down during no-sew press treatment to provide a performance to help maintenance of adhesion.

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Busan, South Korea

Heedae Park