Exxonmobil Research and Engineering Company

Exxonmobil Technology and Engineering Company

Fuelcell Energy, Inc.

Massachusetts Institute of Technology

Heather A Elsen

Gabor Kiss

Abdelkader Hilmi

Timothy C Geary

Jonathan Rosen

Chuansheng Bai

William G Borghard

Adrienne J Thornburg

Chao-yi Yuh

Jean Willem Beeckman

Timothy Andrew Barckholtz

William Anthony Lamberti

William C Horn

Carl A Willman

Anding Zhang

Adam Franco

Mark M Disko

Thomas M Smith

Mehmet Deniz Ertas

Jeffrey C Grossman

Hossein Ghezel-Ayagh

Lu Han

Lawrence J Novacco

Keith E Davis

David A Purta

Brent Keller

Marc A Portnoff

Faiz Pourarian

Margaret A Nasta

Jingfeng Zhang

Sandipan K Das

Nicola Ferralis

Patricia A Bielenberg

Michael R Harper, Jr

Steven W Levine

Xining Zang

Divyaraj Desai

Jonathan D Saathoff

Owen Morris

Ximena Hasbach

Cody R Cole

Chao-Yi Yuh

Timothy A Barckholtz

William A Lamberti

Cathode collector structures and/or corresponding cathode structures are provided that can allow for improved operation for a molten carbonate fuel cell when operated under conditions for elevated COutilization. A cathode collector structure that provides an increased open area at the cathode surface can reduce or minimize the amount of alternative ion transport that occurs within the fuel cell. Additionally or alternately, grooves in the cathode surface can be used to increase the open area.

Cathode collector structures for molten carbonate fuel cell

The present disclosure is directed to processes for forming or otherwise creating a transparent, conductive film from a heavy hydrocarbon material. It allows for what is often considered to be waste material to be transformed into a useful product, such as a heating element. Such heating elements can be incorporated into many contexts where it can be important to have transparency and/or a thin heating element, such as in windshields. The process involves dissolving a heavy hydrocarbon material in a solvent, casting the heavy hydrocarbon solution that results from the dissolving onto a substrate to form a film, and then annealing the film. The disclosure also provides for objects in which such resulting films can be used, such as Joule heaters.

Processes for forming transparent, conductive films from heavy hydrocarbons, and devices and systems into which such films are incorporated

A redox flow battery may include: a positive half-cell comprising a catholyte; a negative half-cell comprising an anolyte; and an ion permeable membrane, wherein the ion permeable membrane separates the catholyte and the anolyte, and wherein the catholyte, the anolyte, or both comprise a low-transition temperature material comprising: a redox-active phase; and an ionically conducting organic salt.

Redox active liquid electrolytes for organic redox flow battery

Molten carbonate fuel cells (MCFCs) are operated to provide enhanced COutilization. This can increase the effective amount of carbonate ion transport that is achieved. The enhanced COutilization is enabled in part by operating an MCFC under conditions that cause transport of alternative ions across the electrolyte. The amount of alternative ion transport that occurs during enhanced COutilization can be mitigated by using a more acidic electrolyte.

Operation of molten carbonate fuel cells with enhanced COutilization

An elevated target amount of electrolyte is used to initially fill a molten carbonate fuel cell that is operated under carbon capture conditions. The increased target electrolyte fill level can be achieved in part by adding additional electrolyte to the cathode collector prior to start of operation. The increased target electrolyte fill level can provide improved fuel cell performance and lifetime when operating a molten carbonate fuel cell at high current density with a low-COcontent cathode input stream and/or when operating a molten carbonate fuel cell at high COutilization.

Operation of molten carbonate fuel cells with high electrolyte fill level

Exemplary embodiments of the present invention relate to the processing of hydrocarbon-containing feedstreams in the presence of an interstitial metal hydride containing catalyst comprising a surface, and a Group VI/Group VIII metal sulfide coated onto the surface of the interstitial metal hydride. The catalysts and processes of the present invention can improve overall hydrogenation, product conversion, as well as sulfur reduction in hydrocarbon feedstreams.

Interstitial metal hydride catalyst systems and associated processes

Exemplary embodiments of the present invention relate to the processing of hydrocarbon-containing feedstreams in the presence of an active catalyst component comprising a surface, and a metal oxide film coated on the surface of the active catalyst component. The catalysts and processes of the present invention can improve overall hydrogenation, product conversion, as well as improved resistance to catalytic deactivation due to sulfur and nitrogen compounds present in the hydrocarbon feedstreams.

Poison resistant catalyst systems and associated processes

Exemplary embodiments of the present invention relate to the processing of hydrocarbon-containing feedstreams in the presence of an interstitial metal hydride comprising a surface, with a metal oxide integrally synthesized and providing a coating on the surface of the interstitial metal hydride. The catalysts and processes of the present invention can improve overall hydrogenation, product conversion, as well as sulfur and nitrogen reduction in hydrocarbon feedstreams.

Integrated interstitial metal hydride catalyst support systems and associated processes

The present invention relates to new processes for regenerating oxidized interstitial metal hydride containing catalysts prior to the use of such catalysts in a hydroprocessing process. Interstitial metal hydride containing catalysts are easily oxidized in the environment and once oxidized, the hydroprocessing activity of the interstitial metal hydrides is most often severely diminished and this lost activity due to oxidization of the iMeH is not susceptible to recovery under hydroprocessing conditions. As a result, these catalysts in the present art require considerable special handling in inert environments all through processes from fabrication, shipping, loading, use, and maintenance of the catalyst systems to protect the activity of the interstitial metal hydride components. The present invention embodies a process regenerating oxidized interstitial metal hydride containing catalysts prior to their use in a hydroprocessing environment, thereby eliminating the requirement for maintaining the interstitial metal hydride containing catalysts in an inert environment, and allowing the handling of such catalysts in an oxidized condition prior to use.

Interstitial metal hydride catalyst activity regeneration process

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Bethlehem, PA, United States of America

Heather A Elsen