Nissin Chemical Industry Co., Ltd.

Shin-etsu Chemical Co., Ltd.

Ricoh Company, Ltd.

Nisshin Chemical Industry Co., Ltd.

Harukazu Okuda

Hiroyuki Ohata

Kunio Itoh

Motoo Fukushima

Tsutomu Nakamura

Norio Nakamura

Masahide Hatanaka

Akira Yamamoto

Kazukiyo Nagai

Tetsuro Suzuki

Hongguo Li

Yuji Gama

Nobuyuki Takahata

Yasuo Suzuki

Masaharu Takahashi

Koji Sakuta

Kazuyuki Matsumura

Toshio Ohba

Yasuo Tarumi

Toshiaki Ihara

Ichiro Tanii

Satoshi Terasaki

Tsutomu Matsuo

An electrophotographic photoconductor including: an outermost layer, wherein the outermost layer comprises an amino group-containing acryl-modified polyorganosiloxane, wherein the amino group-containing acryl-modified polyorganosiloxane is a copolymer in which a polyorganosiloxane represented by the following structural formula (1) and an acrylic monomer are graft-polymerized 

Electrophotographic photoconductor, and image forming apparatus and process cartridge using the same

An aqueous composition used for cosmetics, characterized in that the composition comprises 0.5 to 50 wt %, based on weight of the composition, of a copolymer having main chains comprising the repeating units represented by the following formula (1), the repeating units represented by the following formula (2), and the repeating units represented by the following formula (3), said main chains being crosslinked by a compound or oligomer having 2 to 6 (meth)acryl groups wherein Ris a hydrogen atom or a hydrocarbon group having 1 to 3 carbon atoms, Ris a hydrocarbon group having 1 to 24 carbon atoms, Ris a divalent hydrocarbon group having 1 to 4 carbon atoms, Ris an aliphatic hydrocarbon group having 1 to 6 carbon atoms or a phenyl group, X is a hydrogen atom, an alkaline metal ion, ammonium ion, or an organic ammonium ion, m is an integer of from 0 to 500 on average, and n is an integer of from 1 to 3.

Silicone copolymer and cosmetics comprising the same

A method for preparing a vehicle interior material comprises the steps of feeding 100 parts by weight of phosphorus and nitrogen-containing non-halogen flame retardant particles and 0.1 to 20 parts by weight of hydrophobic inorganic oxide fine particles having hydrophobic groups and having an average particle size of 0.001 to 5 &#x3bc;m to a mixer equipped with a high-speed agitation means having a revolution capability of about 100 to 5,000 rpm, agitating and mixing the phosphorus and nitrogen-containing non-halogen flame retardant particles and the hydrophobic inorganic oxide fine particles to produce the phosphorus and nitrogen-containing non-halogen flame retardant particles coated with the hydrophobic inorganic oxide fine particles, mixing 100 parts by weight as solids of a synthetic resin emulsion and 1 to 300 parts by weight of the phosphorus and nitrogen-containing non-halogen flame retardant particles coated with the hydrophobic inorganic oxide fine particles to produce a coating composition, coating the coating composition onto the vehicle interior material, and drying the coated vehicle interior material.

Method for preparing a vehicle interior material

An emulsion composition for building exterior walls is provided comprising in admixture, [A] a graft copolymerized emulsion obtained by adding to (1) an oil-in-water type emulsion containing at least one organopolysiloxane having an organic group containing a radical reactive group or SH group, (2) a monomer or monomeric mixture containing at least 70 wt % of at least one monomer selected from acrylic and methacrylic monomers and effecting emulsion graft polymerization of component (2) to the organopolysiloxane, and [B] a silicone resin-containing emulsion. The emulsion composition is capable of forming an elastic, flexible coating which is endowed with water resistance, weather resistance, water repellency, adhesion and heat resistance and maintains these properties over a long period of time. It can thus be used as a base in a variety of paints and coating agents.

Building exterior wall-coating emulsion compositions and building exterior walls

A coating composition comprising 100 pbw as solids of a synthetic resin emulsion and 1-300 pbw of a non-halogen flame retardant in which phosphorus and nitrogen-containing non-halogen flame retardant particles are surface coated with a functional group-containing organosilicon resin is applicable to vehicle interior materials such as car seats, floor mats and ceiling members.

Vehicle interior material coating composition and vehicle interior material

A photoconductor comprising a photosensitive layer disposed on a support, wherein the photosensitive layer has a crosslinked layer and the crosslinked layer is produced by curing a dispersion in which at least one of an acryl-modified polyoraganosiloxane having a radical reactivity and an acryl-modified polyoraganosiloxane having an amine structure is dispersed in a radical polymerizable monomer.

Photoconductor, producing method thereof, image forming process and image forming apparatus using photoconductor, and process cartridge

Proposed is an acrylic rubber composition suitable for hot-air vulcanization under normal pressure with a greatly increased vulcanization velocity. The composition comprises:

Acrylic rubber composition

Proposed is an acrylic rubber-based composition suitable for hot-air vulcanization under normal pressure in a continuous process. The rubber composition comprises, besides an acrylic rubber polymer having, in a molecule, at least two silicon-bonded vinyl groups to serve as the crosslinking sites, reinforcing filler and organic peroxide as a vulcanizing agent, an alkoxy silane compound having a vinyl group or (meth)acryloxy group bonded to the silicon atom, such as vinyl triethoxy silane and 3-methacryloxypropyl trimethoxy silane in a specified amount. This unique ingredient serves as a vulcanization accelerator so that the vulcanization reaction is so rapid as to be freed from foaming of the vulcanizate due to the volatile matters and is complete even in the surface layer without the vulcanization-inhibiting influences by the atmospheric oxygen.

Acrylic rubber-based composition

An acrylic rubbery polymer having remarkably improved cold resistance can be prepared by modification with an organopolysiloxane by the emulsion copolymerization of a monomeric mixture of two acrylic monomers, of which one is, for example, an alkyl acrylate and the other is an acrylic compound having, in a molecule, at least one ethylenically unsaturated group other than acrylic group in an aqueous emulsion of an organopolysiloxane having a substantial amount of mercapto-substituted monovalent hydrocarbon groups bonded to the silicon atoms.

Method for the preparation of an acrylic polymer modified with an

The polymeric ingredient of the inventive rubber composition is an acrylic polymer modified with a mercapto-containing organopolysiloxane as prepared by the emulsion polymerization of an acrylic monomer in an aqueous emulsion of the organopolysiloxane. Characteristically, the acrylic monomer is copolymerized with another monomer having an active halogen atom or an epoxy group. By virtue of this unique formulation of the rubbery polymer, the inventive rubber composition prepared by compounding the rubbery polymer with a reinforcing filler and a specified curing or crosslinking agent can be vulcanized to give a vulcanizate having excellent mechanical properties, heat resistance, oil resistance and cold resistance as a combination of the features of silicone rubbers and acrylic rubbers.

Rubber composition

An acrylic rubber composition is proposed which is improved in respect of the extrusion-moldability as well as the surface slipperiness of the vulcanized article obtained therefrom. The composition comprises (a) an acrylic rubbery cooplymer which is a copolymer of a (meth)acrylic ester and a coolymerizable organosilicon compound having a silicon-bonded vinyl group in a molecule, (b) a reinforcing filler, (c) a powder of spherical particles having a specified average particle diameter and (d) an organic peroxide as a vulcanizing agent. The composition can be compounded further with a blowing agent to give a foamable rubber composition capable of being vulcanized into a spongy rubber body exhibiting excellent feeling on touch and slipperiness in contact with human skin to be useful, for example, as a material of cosmetic puffs.

A rubber composition based on a rubbery polymer and a silica-based reinforcing filler can be imparted with a greatly improved workability in roll milling and molding as well as in the mechanical properties of the vulcanizates prepared therefrom when the rubber composition is admixed with an acetylene alcohol or an alkylene-oxide adduct of acetylene alcohol presumably by virtue of the improvement in the dispersibility of the reinforcing filler in the rubbery matrix. The improvement obtained by the addition of the acetylene alcohol compound is not limited to the dispersibility of silica fillers but also to the dispersibility of carbon black when the rubbery polymer is an organopolysiloxane-modified acrylic polymer.

Rubber vulcanizates having excellent oil resistance, heat resistance and cold resistance can be obtained from a rubbery copolymer which is a polymerization product of an acrylic monomer mixture of which the essential components are an organosiloxy-containing acrylate compound such as acryloxymethyl pentamethyl disiloxane and 3-acryloxypropyl pentamethyl disiloxane and an epoxy group- or halogen-containing monomer such as allyl glycidyl ether, glycidyl methacrylate and vinyl chloroacetate, optionally, with addition of an acrylate ester monomer such as ethyl acrylate, n-butyl acrylate and 2-methoxyethyl acrylate.

Monomeric composition and polymer therefrom

The inventive copolymer composition is satisfactorily curable or vulcanizable into, for example, a rubbery elastomer even by an organic peroxide contained therein as a crosslinking agent. The crosslinkable copolymer comprised therein is a polymer having, in a molecule, at least two monomeric units each having a vinyl-containing organosilicon pendant group represented by the general formula (Vi.sub.m R.sup.1.sub.n SiO).sub.a Vi.sub.b R.sup.2.sub.c Si--, in which Vi is a vinyl group, R.sup.1 is a hydrogen atom or a group selected from the class consisting of monovalent hydrocarbon groups free from aliphatic unsaturation, hydroxy group and hydrolyzable groups excepting halogen atoms, R.sup.2 is a hydrogen atom or a monovalent hydrocarbon group, m is 1, 2 or 3, n is zero, 1 or 2, a is 1, 2 or 3, b is zero, 1 or 2 and c is zero, 1 or 2 with the proviso that a+b=1, 2 or 3 and a+b+c=3. Such a copolymer can be prepared by the copolymerization of a first ordinary ethylenically unsaturated monomer and a second monomer having, simultaneously in a molecule, an ethylenically unsaturated linkage copolymerizable with the first monomer and the vinyl-containing organosilicon group of the above given formula.

Growing community of inventors

Takefu, Japan

Harukazu Okuda