Hitachi, Ltd.

Haruhiro Hasegawa

Toshikazu Nishino

Ushio Kawabe

Kazuo Saitoh

Hiroyuki Yamamoto

Kazumasa Takagi

Tokuumi Fukazawa

Mutsuko Hatano

Hisaaki Ochi

Yoshinobu Tarutani

Hideaki Nakane

Toshiyuki Aida

Mitsuo Suga

Tokuo Kure

Michiya Okada

Tsuyoshi Wakuda

Masahiko Hiratani

Takahiko Kato

Fumio Murai

Yutaka Misawa

Katsuzo Aihara

Katsuki Miyauchi

Yoshihide Wadayama

Jiro Kuniya

Masahiro Ogihara

Shinichiroh Saitoh

It is an object of the invention to provide, in a nuclear magnetic resonance spectrometer wherein the direction of the static magnetic field is the horizontal direction, a nuclear magnetic resonance probe coil having a highly uniform magnetic field, which can measure at high sensitivity. The present invention, by selecting the design and shapes of the materials forming the probe coil with a view to suppressing disorder in the magnetic field distribution, and using superconducting thin film coils formed on hollow circular substrates to form a receiver coil and coil support materials having curved surfaces, provides a nuclear magnetic resonance spectrometer of high sensitivity that can improve uniformity of a magnetic field.

Nuclear magnetic resonance spectrometer

Provided is a nuclear magnetic resonance probe coil that is included in a nuclear magnetic resonance apparatus in which the direction of a static magnetic field is horizontal and that can highly sensitively measure multiple nuclear species. A nuclear magnetic resonance apparatus includes a unit that horizontally applies a static magnetic field, a unit that vertically moves a specimen to a predetermined position in the apparatus, and a probe including in the distal part thereof a probe coil that applies a radiofrequency signal to the specimen and that detects a signal produced by the specimen. The probe coil includes multiple pairs of superconducting thin-film rings formed on respective substrates that are disposed in parallel with the static magnetic field while being separated from each other by a predetermined distance, a detection loop that detects a signal received by the superconducting thin-film rings, and a transmission coil that applies the radiofrequency signal to the specimen and that has the normal thereto extended horizontally.

Nuclear magnetic resonance probe coil

A configuration of an NMR apparatus is provided. In the NMR apparatus, a magnetic field space of higher uniformity is generated by split superconducting magnets. At the same time, it is provided with a cryo probe excellent in cooling capability and sensitivity between two superconducting solenoid coils constructed in very close proximity to each other. For this purpose, a probe coil provided between the two superconducting solenoid coils is so constructed that the following is implemented: a certain distance is ensured between a substrate with a coil formed thereon and another, and the substrates and spacer substrates for cooling are alternately laminated. The spacer substrates are cooled by a cold head of sapphire. When the probe coil is inserted in the same direction as a sample tube (direction perpendicular to the static magnetic field), the spacer substrates cannot be coupled directly by the cold head of sapphire. Therefore, they are cooled through a fixed substrate for thermal conduction of sapphire coupled with the cold head.

Nuclear magnetic resonance apparatus

A solenoid-type probe coil wherein superconductive thin film is used, whose quality factor is high, and which is put in an uniform magnetic field and occupies a small space is provided. For that purpose, the coil is made by piling up, in generally parallel, two or more substrates on which superconductive film is formed and connecting superconductors and normal-metal thin films through capacitance or low contact resistance.

An NMR probe having a high-sensitivity solenoid probe coil for receiving free induction decay (FID) signals in nuclear magnetic resonance (NMR) spectroscopy, and an NMR spectrometer which incorporates this probe. The solenoid probe coil is fabricated by a building block approach where it mainly consists of coil substrates having superconducting thin film coils made from superconducting thin film thereon, and side holding plates and a wiring substrate with line pattern of superconducting thin films which are both perpendicular to the coil substrates. The superconducting thin film coils are connected with the line patterns of superconducting thin films by capacitive coupling to make the solenoid coil configuration and solenoid probe coil of superconducting material.

NMR spectrometer and NMR probe

In a superconductive single flux quantum logic circuit having two superconductive closed loops each comprising a Josephson junction and one or more inductors, a load inductance part is comprised of an inductor and a Josephson junction and two or more means for supplying a signal current are included. The load inductance part is made by one or more inductors and means for applying flux via the inductors is included.

Superconductive single flux quantum logic circuit

A superconducting device low in power dissipation and high in operating speed is fabricated by use of a combination of a superconductor material and a semiconductor material. The superconducting device having a low power dissipation and high operating speed characteristic according to the present invention is suitable for configuring a large-scale integrated circuit.

Superconducting device

A superconducting device has a structure of superconductor--normal--conductor (semiconductor)--superconductor. The superconducting regions and the normal-conductor region can be made of the same elements but having different relative proportions of the elements. The device can be fabricated by introducing at least one element into an unmasked region of the superconductor to form a normal conductor region or into unmasked regions of the normal conductor to form superconductor regions.

Method for forming a superconducting weak link device

A superconducting device has a structure of superconductor - normal-conductor (semiconductor) - superconductor. The superconductors constituting the superconducting device are made of a superconducting oxide material of K.sub.2 NiF.sub.4 type crystal-line structure or perovskite type crystalline structure which contains at least one element selected from the group consisting of Ba, Sr, Ca, Mg and Ra; at least one element selected from the group consisting of La, Y, Ce, Sc, Sm, Eu, Er, Gd, Ho, Yb, Nd, Pr, Lu and Tb; Cu; and O.

Superconducting device having superconducting weak coupling

A superconducting field effect transistor which is very small in size and high in dimensional accuracy, has a first layer of material forming a control electrode and a second layer of another material is disposed on said first layer. A width of said first layer in a direction toward a superconducting source electrode and a superconducting drain electrode is narrower than a width of the second layer in the same direction. Polycrystalline silicon may be used as the control electrode while the second layer can be made of silicon nitride. Furthermore, a side surface of the control electrode may be coated with an insulator film. Accordingly, the above transistor has a fine structure gate electrode part that can be fabricated easily and accurately.

Superconducting field effect transistor

An oxide superconducting device has a junction structure composed of at least one oxide superconductor and at least one insulator in which carriers have been generated. As the insulator in which carriers have been generated, there can be used, for example, SrTiO.sub.3 doped with Nb. With such a device, rectifying characteristics can be attained in the junction.

Oxide superconducting device

A superconductive element at least comprising first and second superconductive electrodes composed of an oxide superconductor material and a semiconductor film composed of an oxide semiconductor material put between the first and second superconductive electrodes and disposed in adjacent with the first and the second superconductive electrodes, in which the semiconductor film is formed with an oxide comprising rare earth elements other than Pr, Ba and Cu as the main ingredient element or an oxide comprising predetermined amount of rare earth elements other than Pr, predetermined amount of Pr, Ba and Cu as the main ingredient element. Extremely fine size is no more necessary to enable fabrication with the existent fine fabrication technic.

Superconductive switching element with semiconductor channel

A superconducting device has a structure of superconductor - normal-conductor (semiconductor) - superconductor. The superconductors constituting the superconducting device are made of a super-conducting oxide material of K.sub.2 NiF.sub.4 type crystalline structure or perovskite type crystalline structure which contains at least one element selected from the group consisting of Ba, Sr, Ca, Mg and Ra; at least one element selected from the group consisting of La, Y, Ce, Sc, Sm, Eu, Er, Gd, Ho, Yb, Nd, Pr, Lu and Tb; Cu; and O.

High T.sub.c superconducting device with weak link between two

A process for controlling an oxygen content of a non-superconductive or superconductive oxide is provided, in which a beam of particles such as ions, electrons or neutrons or an electromagnetic radiation is applied to the non-superconductive or superconductive oxide of a perovskite type such as YBa.sub.2 Cu.sub.3 O.sub.7-x, thereby increasing or reducing the oxygen content of the oxide at the sites of oxygen in the crystal lattice of the oxide. Furthermore, a superconductive device such as a superconductive magnet, superconductive power transmission wire, superconductive transformer, superconductive shield, permanent current switch and electronic element is made by utilizing the process for controlling the oxygen concentration of the superconductive oxide.

Process for controlling oxygen content of superconductive oxide,

An oxide-superconductor improved so as to have a high critical temperature (T.sub.c) comprises an oxide having a K.sub.2 NiF.sub.4 crystalline structure similar to a perovskite crystalline structure and represented by the following formula:

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Kokubunji, Japan

Haruhiro Hasegawa