Technic, Inc.

Harry H Kroll

Therese R Souza

Florence P Butler

Ronald J Morrissey

Michael D Gernon

Hanoch S Elroi

John L Little

Jean Chevalier

Philip W Schultz

An electroless catalytic gold plating solution is disclosed comprising a water soluble organic thiol gold (I) complex, an alkali metal cyanide, an alkali metal hydroxide, a borohydride reducing agent, and may also contain a stabilizing agent. The electroless gold plating solution will deposit gold on a gold surface several times faster than the conventional electroless gold baths based on potassium aurous cyanide. The use of an organic thiol gold (I) complex eliminates the buildup of inhibitory cyanide ions as a result of replenishment.

Catalytic electroless gold plating baths

Baths and methods for the electroplating of tin, tin-lead, tin-antimony, and/or tin-bismuth are described. Specifically, electrodeposition solutions, based on alkanesulfonic acids, soluble metal salts, other additives, and at least one nonionic surfactant terminated with a ketone group, have been developed. The use of ketone (e.g., --OCH.sub.2 COCH.sub.3) terminated polyoxyalkylene surfactants results in electrodeposition solutions with reduced foam, and the tin and tin alloy electrodeposits from such plating baths are of superior quality.

Polyoxyalklene compounds terminated with ketone groups for use as

This invention relates to alkyl and alkanol sulfonic acid plating baths and to methods for plating tin and tin-lead alloys. It also relates to low foaming wetting systems based on low to moderate foaming surfactants and soluble, non-silicon containing defoamers, and to low volatility brightener systems.

Bath for electroplating bright tin or tin-lead alloys and method thereof

Heteroaromatic compounds having at least two nitrogen atoms may be used to regulate consistency of alloy content and of deposit thickness. Modified nonionic surfactants which lack terminal hydroxy groups are used as grain refiners having low tendency to cause foam build-up in electroplating baths. Dioxolanes may be used to produce deposits having, as desired, a white uniform matte, a semi-bright plate, or a mirror bright surface. Antioxidants are used to prevent oxidation of divalent tin.

Additives for electroplating compositions and methods for their use

Heteroaromatic compounds having at least two nitrogen atoms may be used to regulate consistency of alloy content and of deposit thickness. Modified nonionic surfactants which lack terminal hydroxy groups are used as grain refiners having low tendency to cause foam build-up in electroplating baths. Dioxolanes may be used to produce deposits having, as desired, a white uniform matte, a semi-bright plate, or a mirror bright surface.

Electroplating solutions for the deposition of palladium or the alloys thereof, in which solutions palladium was added in the form of the reaction product of palladium diaminodinitrite with an acid in the presence of a scavenging agent for nitrous acid.

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E. Greenwich, RI, United States of America

Harry H Kroll