Dow Corning Corporation

Massachusetts Institute of Technology

Harold L Vincent

Judith M Sylvester

Gary A Vincent

Paul Joseph Popa

Dennis W Broderick

Loren A Haluska

Bizhong Zhu

Dimitris Katsoulis

Randall Gene Schmidt

Gary R Homan

Martin E Cifuentes

Arthur James Tselepis

Frederick J McGarry

Gerald Lawrence Witucki

John Robert Keryk

Keith D Weiss

Cecil L Frye

Dale E Hauenstein

William P Brady

William J Schoenherr

Anh Be

Ramnath Subramanian

Novel rubber-modified rigid silicone resins are disclosed. The novel resins are the copolymerized reaction product of (A) an organosilicon composition selected from the group consisting (I) an organosilicone resin, (II) hydrolyzable precursors of (I), and an hydrolyzate of (II) and (B) an silicone rubber. The novel rubber-modified rigid silicone resins of the invention show remarkably high fracture toughness, K.sub.Ic, and critical strain energy release rate G.sub.Ic.

Rubber-modified rigid silicone resins and composites produced therefrom

Disclosed is a method of forming a coating on a substrate. The method comprises applying a silane and, optionally, a titanium catalyst, onto the substrate and allowing the silane to hydrolyze and condense with atmospheric moisture to form an insoluble coating.

Method for forming an insoluble coating on a substrate

A moisture-curable silicone hot-melt adhesive composition is disclosed, which composition comprises

Oxime-functional moisture-curable hot melt silicone pressure-sensitive

There is disclosed a method for forming a solid, epoxy-functional silicone resin by hydrolyzing and condensing a mixture of at least one organoalkoxysilane and a beta-(3,4-epoxycyclohexyl)-functional trialkoxysilane in the presence of an organotitanate catalyst. The silicone resins prepared according to the instant method find utility in the formulation of powder coatings, either alone or in combination with organic resins.

Epoxy-functional silicone resin

A method for imparting corrosion resistance to a metal substrate comprising coating said substrate with a moisture-curable silicone composition is disclosed. The composition consists essentially of a tetrafunctional or hexafunctional silicone polymer (I) which is modified with a liquid organohydrogenpolysiloxane (II) such that, when the functional groups of (I) are alkoxy radicals, the organohydrogenpolysiloxane contains at least 4 silicon hydride groups per molecule and when the functional groups of (I) are oxime groups, the organohydrogenpolysiloxane contains at least 5 silicon hydride groups per molecule.

Moisture-curable silicone corrosion resistant coatings

An efficient method for preparing an oximosilane-functional vinylic copolymer is disclosed wherein the corresponding alkoxysilane-functional vinylic copolymer is reacted with an organoketoxime in a dry environment. The oximosilane-functional vinylic copolymers produced by the method of the present invention find utility in moisture-curable coating systems.

Method for preparing oximosilane-functional vinylic copolymers

A curable coating composition, which provides excellent corrosion protection to metals, is disclosed. The composition comprises (I) a reaction product (or blend) of a resinous copolymeric siloxane solution with a liquid organohydrogenpolysiloxane, (II) a hydroxy-functional diorganopolysiloxane, (III) an organosilane, (IV) a trialkyl orthoformate, (V) an organic titanate and (VI) a condensation catalyst. High solids compositions of the present invention can be applied by conventional siphon cup spray equipment and have an extended bath life relative to prior art formulations of this type.

Silicone corrosion protection coating having extended bath life

There is disclosed the use of a quaternary ammonium salt of an alkoxysilane as a dispersant for magnetic pigment particles in the preparation of magnetic recording media. The dispersant of the present invention can bind to the pigment particles and may be substituted for conventional phosphate ester dispersants which are incapable of binding to the pigment and tend to migrate to the surface of such media, thereby adversely affecting recording media performance.

Quaternary ammonium salt of an alkoxysilane as a dispersant for magnetic

This invention relates to a stabilized ferromagnetic metal pigment which is produced by treating metal particles with a passivating reaction product comprising a silane-modified phosphate. The treated pigment is employed in the preparation of a magnetic recording medium which is resistant to storage at elevated temperature and humidity.

Method of stabilizing magnetic metal pigment

Stabilized magnetic metal pigment

What is disclosed are organopolysiloxane release coatings which are curable on a substrate and which consist of a base siloxane copolymer containing CH.sub.3 SiO.sub.3/2 units; C.sub.6 H.sub.5 SiO.sub.3/2 units, C.sub.6 H.sub.5 (CH.sub.3)SiO units and (C.sub.6 H.sub.5).sub.2 SiO units; CH.sub.3 SiO.sub.3/2 ; a fluid polysiloxane, and a curing agent. They are especially useful on commercial and household cookware and bakeware.

Hard organopolysiloxane release coating

This invention relates to silicone pressure-sensitive adhesives having improved viscosity stability, film physical property stability upon aging and lap shear stability made by a method comprising the condensation of a benzene-soluble resin copolymer of 0.6 to 0.9 triorganosiloxy units per SiO.sub.4/2 unit which contains silicon-bonded hydroxyl radicals and a polydiorganosiloxane preferably containing silicon-bonded hydroxyl or other hydrolyzable endblocking radicals with a sufficient amount of an ammonia releasing endblocking agent containing endblocking triorganosilyl units such as hexamethyldisilazane to result in a 1:0.8 to 1:3 mole ratio of silicon-bonded hydroxyl radicals and hydrolyzable endblocking radicals to total moles of triorganosilyl units provided by the endblocking agent. The condensation is conducted with heating at 80.degree. C.-160.degree. C. in the presence of 0.1 to 10 moles of water per mole of .dbd.NH present in the endblocking agent, 0.001 to 10 parts by weight per 100 parts by weight of total resin copolymer and polydiorganosiloxane and when necessary, in the presence of an effective amount of an organic solvent such as xylene. Condensation is preferably conducted under solvent reflux conditions. When the condensation reaction is substantially complete, the remaining endblocking agent, water, ammonia scavenger compound and ammonia released by the endblocking agent is stripped from the composition.

Silicone pressure-sensitive adhesive process and product with improved

What is disclosed is a method of reducing the viscosities of aqueous slurries of particulate materials using anionic siliconates of silylorganocarboxylates, sulfonates and phosphonates and the compositions that are obtained thereby. An example is the use of 0.1 weight percent of ##STR1## to lower the viscosity of a 60% solids slurry of TiO.sub.2 from 2320 cps at 25.degree. C. to 80 cps at 25.degree. C.

Growing community of inventors

Midland, MI, United States of America

Harold L Vincent