Bayer Aktiengesellschaft

Harold Heller

Herbert Corte

Otto Netz

Peter M Lange

Alfred Mitschker

Friedrich Werner

Michael Lange

Reinhold M Klipper

Dietmar Schapel

Franz-Rudolf Minz

Heiko Hoffmann

Manfred Dahm

Axel Ingendoh

Werner Struver

Friedrich Martinola

Hans-Karl Soest

Gunter Siegers

Claus Hentschel

Axel Schafer

Herbert V Diehl

Weakly basic anion exchangers of the poly(meth)acrylamide type which have been prepared by aminolysis of poly(meth)acrylonitrile or poly(meth)acrylate with polyamines of defined composition have an improved absorption capacity for sulphate ions and are suitable for selectively removing sulphate ions from aqueous liquids, in particular from sodium chloride brine and from waste waters.

Weakly basic anion exchangers, processes for their preparation by

Process of removing sulfate ions from water with a poly(meth)acrylamide

According to the process according to the invention for the preparation of anion exchange resins of the poly(meth)acrylamide type by aminolysis of bead polymers of cross-linked poly(meth)acrylic acid esters with excess polyamine, subsequent separation of the anion exchange resins from the liquid phase containing the unreacted polyamine, washing the anion exchangers free of amine with water and recovering the polyamines from the washing waters, the liquid phase containing the unreacted polyamine and the polyamine-containing washing waters are immediately mixed with the bead polymer of cross-linked poly(meth)acrylic acid ester to be subjected to aminolysis, the amount of fresh polyamine necessary for the establishment of the desired polyamine excess is added to the mixture, the mixture thus obtained is distillatively dewatered until its water content has fallen to a value of &lt;7% by weight and the mixture remaining after this distillative dewatering is subjected to aminolysis in the customary manner.

Process for the preparation of anion exchange resins of the

The invention relates to an environment-friendly process for the preparation of weakly acid cation exchange resins by hydrolysis of crosslinked acrylonitrile bead polymers with an alkaline hydrolizing agent at elevated temperature, according to which the bead polymer and alkaline hydrolizing agent are brought together at elevated temperature only.

Process for the preparation of weakly acid cation exchange resins

A process for the preparation of a bifunctional anion exchange resin by partial quaternization of a weakly basic anion exchanger containing tertiary amino groups which process comprises (a) partially loading the weakly basic anion exchanger with a strong acid and (b) quaternizing the partially loaded anion exchanger by means of a customary alkylating agent.

Process for the preparation of bifunctional anion exchange resins, new

The invention relate to a process for reducing the wash water required by weakly basic anion exchangers containing primary and/or secondary amino groups when fed with water containing carbon dioxide; in accordance with the process the exhausted, weakly basic anion exchangers are treated with dilute aqueous mineral acids before being regenerated.

Process for reducing the wash water requirement of weakly basic anion

A process for supplying plants with nutrients uniformly and over a long period of time by the addition of nutrient-charged synthetic resin ion exchangers and mineral fertilizers to the culture medium, according to which the nutrient-charged synthetic resin ion exchangers are employed together with those mineral fertilizers with particle size &lt;500 .mu.m which have been coated with massive polyurethanes having a particular water absorbing capacity which is adapted in a particular manner to the water solubility of the mineral fertilizer; furthermore, fertilizers containing nutrient-charged synthetic resin ion exchangers, and the mineral fertilizers coated with the massive polyurethanes having a particular water absorbing capacity.

Ion exchanger fertilizers and a process for supplying plants with

A fertilizer for the long term and uniform supply of plants with nutrient ions comprising a covalently crosslinked hydrogel in which are embedded ion exchangers which are laden with plant nutrients; furthermore a process for the long term and uniform supply of plants with nutrient ions wherein a covalently crosslinked hydrogel in which are embedded ion exchangers which are laden with plant nutrients is applied to the plants or their environment.

Fertilizers

Process for improving the plant growth with the aid of ion exchanger fertilizers, comprising adding to the growth medium weakly basic anion exchangers which are charged with anionic chelate complexes of micronutrient cations and macronutrient and micronutrient anions to the extent of at least 60% of their total capacity together with weakly acid cation exchangers charged with nutrient cations to the extent of at least 60% of their total capacity. Furthermore fertilizers comprising a mixture of weakly basic anion exchanger which are charged with anionic chelate complexes of micronutrient cations and other micronutrient and macronutrient anions to the extent of at least 60% of their total capacity and weakly acid cation exchangers which are charged with nutrient cations to the extent of at least 60% of their total capacity.

Ion exchanger fertilizers

New Synthetic resins useful as inert material for separating layers in ion exchanger mixed bed filters. The new synthetic resins are copolymers of

Synthetic resins based on crosslinked copolymers of monovinyl and

The invention relates to a process for removing oleophilic odor- and tasteproducing substances from water by treating the water with an insoluble, macroporous adsorber resin comprising a matrix based on a crosslinked organic polymer containing aromatic nuclei, the polymer containing chloromethyl groups as substituents; some of the chlorine atoms in the chlormethyl groups can be reacted with ammonia or amines, furthermore the invention relates to the adsorber resins to be used in the claimed process.

Process for treating drinking water and sewage

Nitrogenous fertilizer compositions comprising a cation exchanger in the form of a salt thereof with a basic carbonic acid derivative containing at least 2 nitrogen groupings, e.g., a salt formed by attaching to a cation exchange material, guanidine, diguanidine, guanylurea, biuretdicyanamide, urazone, melamine, guanine or ammeline, are outstandingly effective in providing gradually-acting, long-lasting fertilizing action.

Nitrogenous fertilizer compositions

Anion-exchange resins made by aminoalkylating an alkylatable resin in solvent-swollen condition with bis-carboxyimidomethyl ethers in a reaction mixture containing essentially unhydrated SO.sub.3 that can be added in the form of a solution in H.sub.2 SO.sub.4 or other solvent or as a complex with the alkylating ether, or in undissolved condition. The acylaminoalkylated product thus formed is deacylated as by hydrolysis and can have the resulting amino group alkylated and even quaternized.

Process for the preparation of anion exchangers by aminoalkylation of

The invention relates to a process for removing oleophilic odor- and tasteproducing substances from water by treating the water with an insoluble, macroporous adsorber resin comprising a matrix based on a crosslinked organic polymer containing aromatic nuclei, the polymer containing chloromethyl groups as substituents; some of the chlorine atoms in the chlormethyl groups can be reacted with ammonia or amines; furthermore, the invention relates to the adsorber resins to be used in the claimed process.

Insoluble adsorber resin suitable for treating drinking water and sewage

The invention concerns new, crosslinked, macroporous, vinyl-aromatic plastic materials containing thiourea groups, to processes for their production and to their use for adsorbing metal compounds, especially noble metal and mercury compounds.

Growing community of inventors

Cologne, Germany

Harold Heller