Eastman Chemical Company

Harold Eugene Dobbs

Thomas Joseph Pecorini

Spencer Allen Gilliam

Mark Allan Treece

Scott Arnold Hanson

Wesley Raymond Hale

Douglas Stephens McWilliams

Robert Ellis McCrary

Alan Keith Phillips

Daniel Christopher Cobb

Emily Tedrow Bell

Ignacio Garcia

William Joseph Burgess

Hubertus Jacobus Moolenaar

Michael Wandell Cradic

Yvette Marie Feay

Michael W Cradic

Gilliam Spencer Allen Allen

Extrusion blow mold assemblies, extrusion blow molded articles exhibiting increased strength and enhanced processability, and processes for making said articles. In some aspects, the articles produced herein can include relatively rigid bottles and other containers that exhibit high drop impact performance, while still being relatively easy to deflash. Such containers can be efficiently produced on a commercial scale and are widely usable in a variety of applications, including those in the food, beverage, cosmetic, and medical industries.

Extrusion blow molding system having enhanced pinch geometry

Extrusion blow molded (EBM) articles comprising a polyester having a dicarboxylic acid component and a glycol component. The dicarboxylic acid component comprises at least 90 mole % terephthalic acid residues. The glycol component comprises at least 75 mole % ethylene glycol residues and 15 to 25 mole % residues of a difunctional glycol such as, for example, 1,4-cyclohexanedimethanol. Such EBM articles can exhibit reduced haze, reduced sharkskin, and/or increased compatibility in PET recycling.

Extrusion blow molded articles

Extrusion profile articles comprising a polyester having a dicarboxylic acid component and a glycol component. The dicarboxlyic acid component comprises at least 90 mole % terephthalic acid residues. The glycol component comprises at least 75 mole % ethylene glycol residues and 15 to 25 mole % residues of a difunctional glycol such as, for example, 1,4-cyclohexanedimethanol. Such extrusion profile articles can exhibit reduced haze, reduced sharkskin, and/or increased compatibility in PET recycling.

Extrusion profile articles

Blends of polycarbonate and copolyester that are capable of being extrusion blow-molded are described. The blends preferably comprise (I) about 1 to 99% by weight of a linear or branched polycarbonate and (II) about 1 to 99% by weight of a mixture of (i) about 40 to 100% by weight of a first copolyester and (ii) about 0 to 60% by weight of a second copolyester. The first copolyester preferably comprises (A) diacid residues comprising terephthalic acid residues, (B) diol residues comprising about 45 to 75 mole percent of 1,4-cyclohexanedimethanol (CHDM) residues and about 25 to 55 mole percent of ethylene glycol residues, and (C) about 0.05 to 1.0 mole percent of the residue of a trifunctional monomer. The optional second copolyester preferably comprises (A) diacid residues comprising terephthalic acid residues and (B) diol residues comprising about 52 to 90 mole percent of CHDM residues and about 10 to 48 mole percent of ethylene glycol residues. Preferably, the average amount of CHDM residues in the copolyester mixture II ranges from 52 to 75 mole percent. It has been surprisingly found that the presence of the trifunctional residues in the first copolyester can impart sufficient melt strength for the blends to be extrusion blow-molded. Containers and shaped articles made from the blends as well as a method of making the articles are also described.

Polyester-polycarbonate blends useful for extrusion blow-molding

A PCT copolyester composition having at least about 70 mole % terephthalic acid and at least about 70 mole % 1,4-cyclohexanedimethanol and an inherent viscosity of greater than about 0.9 dL/g is prepared by solid state polymerizing a copolyester composition having a starting inherent viscosity of from about 0.4 to about 0.8 dL/g for a period of from about 1 minute to 100 hours and at a temperature of from about 140&deg; C. to about 2&deg; C. below the melting point of the copolyester to produce a copolyester having an inherent viscosity of greater than about 0.9 dL/g. Another aspect of the present invention is an extrusion blow molded article made from the copolyester prepared by the solid state polymerization process.

Polyester having improved crystallization behavior and extrusion blow molded articles made therefrom

A process is provided for single screw extrusion of a composition or masterbatch comprising a polymer and an antistatic agent wherein the feed zone temperature is maintained below 385&deg; F. in order to allow processability of the composition.

Single screw extrusion of polymers

A novel composition is provided comprising a copolyester having CHDM moieties in amounts of about 1 to about 20 mole percent, and a particular antistat, that is extrudable.

Extrudable masterbatch

A multi-layer electrostatic dissipative structure that is clear to translucent, washable and thermo-formable comprises at least one outer layer and a core layer. Preferably, two outer layers are utilized with the core layer sandwiched therebetween. The outer layers are a blend of amorphous or semi-crystalline copolyester and an electrostatic dissipative polymer in an amount sufficient to impart a surface resistivity of about 10.sup.5 to 10.sup.12 Ohms/sq. The core layer is a polymer having a haze value of less than five percent, preferably amorphous or semi-crystalline copolyester. The multi-layer structure may additionally have tie layers between the core layer and each of the outer layers.

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Kingsport, TN, United States of America

Harold Eugene Dobbs