Samsung Sdi Co., Inc.

Ulsan National Institute of Science and Technology

Harim Lee

Myungheui Woo

Hyunbong Choi

Hyejin Park

Pavel Shatunov

Miyoung Son

Olga Tsay

Seungtae Lee

Aeran Kim

Wonseok Cho

Jin-Hyeok Lim

Woocheol Shin

Siyoung Cha

Jinhyeok Lim

Jaehong Kim

Sunjoo Choi

Sanghoon Kim

Nam-Soon Choi

Myunghwan Jeong

Yunhee Kim

Suyeol Ryu

Kyoungsoo Kim

Duckjae You

Hana Ra

Taejin Lee

Younghye Kang

AeHui Goh

Jeongmin Shin

Makhmut Khasanov

Inhaeng Cho

Minju Lee

Seonghun Jeong

Arum Yu

Jungjin Moon

MiYoung Son

Jeong-A Lee

Tae Hyon Bae

Saehun Kim

Aehui Goh

An additive for electrolytes includes a compound represented by Formula 1. The silyl moieties at both ends of the compound may coordinate water to suppress or reduce hydrolysis of LiPF, and may also form a SEI film capable of improving battery performance. Additional embodiments of the present disclosure provide an electrolyte including the additive; and a lithium secondary battery including the electrolyte.

Additive for electrolyte, electrolyte including additive, and lithium secondary battery including electrolyte

Provided are an electrolyte additive for lithium secondary batteries, an electrolyte for lithium secondary batteries including the same, and a lithium secondary battery including the electrolyte, the additive including a compound represented by Formula 1 below: In Formula 1, Rto Rare as defined in the detailed description.

Electrolyte additive for lithium secondary battery, electrolyte for lithium secondary battery including the same, and lithium secondary battery including electrolyte

The present disclosure relates to an electrolyte for a lithium secondary battery and a lithium secondary battery comprising same, the electrolyte comprising: a non-aqueous organic solvent; a lithium salt; and an additive, wherein the additive includes a compound represented by Chemical Formula 1 and a negative electrode film forming agent. Formula 1 is as described in the specification. For example, the electrolyte for a lithium secondary battery includes a non-aqueous organic solvent, a lithium salt, and an additive, and the additive includes a compound represented by Chemical Formula 1 and a negative electrode film forming agent. Description of Chemical Formula 1 is as described in the specification.

Electrolyte for lithium secondary battery and lithium secondary battery comprising same

An additive for a lithium secondary battery includes a compound represented by Formula 1 below, where Rto Rare as defined in the disclosure. An electrolyte for a lithium secondary battery includes: a lithium salt; a non-aqueous organic solvent; and the additive. A lithium secondary battery includes: a cathode; an anode; and the electrolyte.

Electrolyte additive for lithium secondary battery and lithium secondary battery including the same

An electrolyte additive for a lithium secondary battery, an electrolyte, and a lithium secondary battery, the additive including a compound represented by Formulabelow:

Additive, electrolyte for lithium secondary battery and lithium secondary battery including the same

An electrolyte additive for a lithium secondary battery, an electrolyte, and a lithium secondary battery, the additive comprising a compound represented by Formula 1 below:

Elecrolyte additive for lithium secondary battery, electrolyte for lithium secondary battery, and lithium secondary battery including electrolyte

A lithium battery includes a cathode including a cathode active material; an anode including an anode active material; and an organic electrolytic solution between the cathode and the anode. The cathode active material includes a nickel-containing layered lithium transition metal oxide. A content of nickel in the lithium transition metal oxide is about 60 mol % or more with respect to a total number of moles of transition metals. The organic electrolytic solution includes a first lithium salt; an organic solvent; and a bicyclic sulfate-based compound represented by Formula 1 below: wherein, in Formula 1, each of A, A, A, and Ais independently a covalent bond, a substituted or unsubstituted C-Calkylene group, a carbonyl group, or a sulfinyl group, in which both Aand Aare not a covalent bond and both Aand Aare not a covalent bond.

Lithium battery

A lithium secondary battery includes: a cathode, an anode; and an electrolyte between the cathode and the anode, wherein the cathode includes a cathode active material represented by Formula 1 below, and the electrolyte includes a lithium salt, a non-aqueous solvent, and a compound represented by Formula 2, where x, y, z, M, A, L, a1, and Rto Rare defined as described in the disclosure. 

Lithium secondary battery

A rechargeable lithium battery includes a positive electrode, a negative electrode, and an electrolyte including a lithium salt, wherein at least one of the positive electrode and the negative electrode includes a current collector, an electrode tab extending from the current collector, an active material layer disposed on the current collector, and a passivation film formed on at least one of the current collector and the electrode tab. The passivation film includes a material represented by Chemical Formula 1:CuX(POF)YZ,&#x2003;&#x2003;Chemical Formula 1wherein, in Chemical Formula 1, X is a Cto Calkylene group, Y is represented by Chemical Formula 2, Z is an anion group of the lithium salt, and n is 1 or 2:NC&#x2014;R&#x2014;CN, (wherein, Ris a Cto Calkylene group).&#x2003;&#x2003;Chemical Formula 2

Rechargeable lithium battery

A lithium battery includes a cathode including a cathode active material, an anode including an anode active material, and an organic electrolytic solution between the cathode and the anode, wherein the organic electrolytic solution includes a first lithium salt, a second lithium salt, an organic solvent, and a bicyclic sulfate-based compound represented by Formula 1 below: 

Disclosed herein is an additive for a lithium secondary battery, the additive including a compound represented by Formula 1. An electrolyte for a lithium secondary battery includes: a lithium salt; a non-aqueous organic solvent; and the additive represented by Formula 1. A lithium secondary battery includes: a cathode; an anode; and the electrolyte including the additive represented by Formula 1. 

Disclosed is an electrolyte for a rechargeable lithium battery including a non-aqueous organic solvent, a lithium salt, and an additive, wherein the additive is a compound represented by Chemical Formula 1. In Chemical Formula 1, each substituent is the same as in the detailed description. A rechargeable lithium battery includes: a positive electrode; a negative electrode; and the electrolyte. 

Electrolyte for rechargeable lithium battery and rechargeable lithium battery

A lithium battery includes a cathode including a cathode active material, an anode including an anode active material, and an organic electrolytic solution between the cathode and the anode. The organic electrolytic solution includes a first lithium salt, a second lithium salt different from the first lithium salt, an organic solvent, and a bicyclic sulfate-based compound represented by Formula 1 below: wherein, in Formula 1, each of A1, A2, A3, and A4 is independently a covalent bond, a substituted or unsubstituted C1-C5 alkylene group, a carbonyl group, or a sulfinyl group, wherein both A1 and A2 are not a covalent bond and both A3 and A4 are not a covalent bond.

A lithium battery includes a cathode including a cathode active material, an anode including an anode active material, and an organic electrolytic solution between the cathode and the anode. The anode active material includes a metal-based anode active material. The organic electrolytic solution includes a first lithium salt; an organic solvent; and a bicyclic sulfate-based compound represented by Formula 1 below: wherein, in Formula 1, each of A1, A2, A3, and A4 is independently a covalent bond, a substituted or unsubstituted C1-C5 alkylene group, a carbonyl group, or a sulfinyl group, wherein both A1 and A2 are not a covalent bond and both A3 and A4 are not a covalent bond.

A lithium battery includes a cathode including a cathode active material; an anode including an anode active material; and an organic electrolytic solution between the cathode and the anode, wherein the anode active material includes natural graphite and artificial graphite, an amount of the artificial graphite being about 50 wt % or more based on a total weight of the anode active material, and the organic electrolytic solution includes: a first lithium salt; an organic solvent; and a bicyclic sulfate-based compound represented by Formula 1 below: 

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Yongin-si, South Korea

Harim Lee