Bayer Corporation

Bayer Aktiengesellschaft

Lanxess Corporation

Harald Bender

Sharon X Guo

Paul Nguyen

Ezio Campomizzi

Judy Hannay

Gilles J Arsenault

Frederic Guerin

Franz-Josef Mersmann

Rotraud Casper, Legal Representative

Janet Gamlin

Hans Christian Strauch

Hans Rafael Winkelbach

Ignazio Spadola

Polymers of a conjugated diene, an unsaturated nitrile and an &#x3b1;,&#x3b2;-unsaturated carboxylic acid are selectively hydrogenated to reduce carbon-carbon double bonds, without also reducing carboxyl groups and nitrile groups, using a rhodium-containing compound as catalyst. The hydrogenated polymers are novel and display excellent adhesive properties at both room temperature and high temperature, excellent hot tear strength, and excellent abrasion resistance.

Process for hydrogenating carboxylated nitrile rubber, the hydrogenated rubber and its uses

Hydrogenated copolymers of an unsaturated nitrile, butadiene and isoprene, wherein the molar ratio of butadiene to isoprene is less than 3:1, display valuable low temperature properties.

Hydrogenated nitrile rubbers with improved low-temperature properties

A polymer composition useful to produce a vulcanizate having improved hot air aging properties is described. The polymer composition includes two components. The first component is a polymer having a main polymer chain derived from: (i) at least about 30% by weight of a first monomer which introduces at least one of a secondary carbon and a tertiary carbon to the backbone, and (ii) from 0 to about 70% by weight of at least one other monomer. The second component is a salt of a strong base and a weak acid, the salt comprising a metal selected from Group I of the Periodic Table of Elements. The polymer compositions may further comprise optional ingredients such as one or more of: a vulcanization system, a polycarbodiimide and a filler.

Ethylene propylene copolymer composition and process for producing vulcanizates therefor

The present invention is directed to a nitrile polymer vulcanizate having improved hot air aging characteristics. The nitrile polymer vulcanizate may be produced by admixing a composition containing: (i) a nitrile polymer; (ii) a filler; (iii) a metal salt of a secondary amine; (iv) a vulcanization system; and optionally (v) an additive selected from the group consisting of a strong base, a salt of a strong base and a weak acid, a salt of a weak acid, a carbodiimide, a polycarbodiimide and mixtures thereof.

Nitrile polymer vulcanizate and process for the production thereof

A vulcanizate derived from a polymer composition comprising three components exhibits improved hot air aging properties and is useful, for example, for the manufacture of articles subject to dynamic loading, such as belting applications. The first component is a polymer having a main polymer chain derived from: (i) at least about 30% by weight of a first monomer which introduces at least one of a secondary carbon and a tertiary carbon to the backbone, and (ii) from 0 to about 70% by weight of at least one other monomer. Preferred are ethylene-alpha-olefin copolymers. The second component is a salt of a strong base and a weak acid, the salt comprising a metal selected from Group I of the Periodic Table of Elements. The third component is an antioxidant.

Articles for dynamic load applications

A process is provided for the removal of iron- and rhodium-containing residues from a solution of hydrogenated nitrile rubber. The process utilizes an ion-exchange resin having thiourea functional groups. Further, the resin is both macroporour and monodispersed. The process removes both rhodium and iron from viscous rubber solutions. In a preferred embodiment, the process is carried out in an ion-exchange column.

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Pulheim, Germany

Harald Bender