Clariant Corporation

Clariant Finance (Bvi) Limited

Clariant International Ltd

Clariant Produkte (Deutschland) Gmbh

Clariant Plastics & Coatings Ltd

Other

Hoechst Aktiengesellschaft

Hoechst Aktiengellschaft

Clariant Deutschland Gmbh

Clariant Produkte Gmbh

Harald Bauer

Martin Sicken

Werner Krause

Sebastian Hoerold

Josef Holz

G&uuml;nther Schimmel

Sebastian Hörold

Michael Hill

Mathias Dietz

Günther Schimmel

Norbert Weferling

Volker Thewes

Ottmar Schacker

Guenther Schimmel

Gunther R Schimmel

Peter Staniek

Fabian Schneider

Lothar Westermann

Christian Nitsch

Richard Mertens

Hans-Matthias Deger

Juergen Haerer

Alexander Tapper

Wolfgang Wanzke

Thomas Mueller-Kirschbaum

Elke Schlosser

Bernd Nass

Frank Osterod

Wiebke Maas

Rainer Sorg

Andreas Termath

Eva-Maria Leuschner

Peter Hardt

Matthias Berghahn

Muriel Rakotomalala

Sebastian Höerold

Susanne Knop

Harald Volk

Peter Krings

Armelle Pelissou

Frank Eisenträger

Thomas Müller

Hans Rauch

Peter Ittner

Reinhard Helldorfer

Gunter Alberter

Eva Maria Leuschner

Klaus Bender

Oliver Hauenstein

Daniela Eisenhauer

The invention relates to intumescent flame-retardant clearcoat formulations containing 20% to 88.5% by weight of an aqueous synthetic resin formulation, 10% to 60% by weight of a phosphoric partial ester, 0.5% to 20% by weight of a polyol and 1% to 30% by weight of further ingredients, and to the use thereof.

Intumescent flame-retardant clearcoat formulations

The invention provides a flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 20% to 99.7% by weight of phosphinic salt of the formula (I), (I), in which Rand Rare each ethyl, M is Al and m is 3; as component B 0.2% to 16% by weight of aluminium salts of ethylbutylphosphinic acid, of dibutylphosphinic acid, of ethylhexylphosphinic acid, of butylhexylphosphinic acid and/or of dihexylphosphinic acid; as component C 0.1% to 80% by weight of a salt of phosphorous acid having the general formula (II) [HP(═O)O]M(II) in which M is Zn and m is 2; as component D 0% to 80% by weight of a salt of phosphorous acid having the general formula (III) [HP(═O)O]M(III) in which M is Al and m is 3; as component E 0% to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus-containing and/or nitrogen-containing flame retardant; as component F 0% to 10% by weight of an inorganic synergist selected from zinc borate, zinc stannate, boehmite and/or hydrotalcite; as component G 0% to 3% by weight of an organic phosphonite and/or a mixture of an organic phosphonite and an organic phosphite and as component H 0% to 3% by weight of an ester and/or salt of long-chain aliphatic carboxylic acids (fatty acids) typically having chain lengths of Cto C, where the sum total of the components is always 100% by weight.

Flame retardant-stabilizer combination for thermoplastic polymers

Described herein is a flame retardant-stabilizer mixture including as a component A, 5% to 95% by weight of aluminium diethylphosphinate (DEPAL) and/or zinc diethylphosphinate (DEPZN); as a component B, 5% to 95% by weight of titanium phosphinates and/or titanyl phosphinates of the formula (I) (DEPTI) in which x is a number from 0 to 1.9; as a component C, 0% to 10% by weight of aluminium phosphite or zinc phosphite of the formula (II), [HP(═O)O]Zn, and formula (III), [HP(═O)O]Al; as a component D, 0% to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus-containing and/or nitrogen-containing flame retardant; as a component E, 0% to 70% by weight of a filler and reinforcer; as a component F, 0% to 3% by weight of an organic phosphonite and/or an organic phosphite and/or mixtures with phenolic antioxidants; and as a component G, 0% to 3% by weight of an ester and/or salt of long-chain aliphatic carboxylic acids (fatty acids) typically having chain lengths of Cto C. The sum total of components A-G is 100% by weight.

The invention relates to additive mixtures for plastics containing phosphinic acid of the formula (I) as component A, wherein Rand Rmean ethyl, M is Al, Fe, TiOor Zn, m means 2 to &#x3c;4, preferably 2 or 3, and p=(4&#x2212;m)/2 is a compound selected from the group of Al, Fe, TiOor Zn salts of ethylbutylphosphinic acid, dibutylphosphinic acid, ethylhexylphosphinic acid, butylhexylphosphinic acid and/or dihexylphosphinic acid as component B, phosphonic acid salt of formula (II) as component C, wherein Rmeans ethyl, Met is Al, Fe, TiOor Zn, n means 2 to 3, and q=(4&#x2212;n)/2, and antimony, tin and/or indium as component D. Polymer compositions containing said additive mixtures are characterized by exceptional flame protection and by very good laser markability or laser weldability.

Additive mixtures for plastics, laser-markable polymer compositions comprising them and the use thereof

A flame-retardant polyamide composition can be prepared with a glow wire ignition temperature of not less than 775&#xb0; C. Such a composition can include a polyamide having a melting point of not more than 290&#xb0; C. as component A, fillers and/or reinforcers as component B, a phosphinic salt of the formula (I) as component C, a compound selected from the group of the Al, Fe, TiOand Zn salts of ethylbutylphosphinic acid, of dibutylphosphinic acid, of ethylhexylphosphinic acid, of butylhexylphosphinic acid and/or of dihexylphosphinic acid as component D, a phosphonic salt of the formula (II) as component E, and a melamine polyphosphate having an average degree of condensation of 2 to 200 as component F. Additional components can be included in the composition.

Flame-retardant polyamide compositions with a high glow wire ignition temperature and use thereof

The invention relates to diorganylphosphinic salts containing 0.0001% to 99.9999% by weight of iron, to a process for preparation thereof and to the use thereof.

Diorganylphosphinic acid salts, method for the production thereof and the use thereof

The invention relates to a novel flame retardant-stabilizer combination for thermoplastic polymers, comprising, as component A, from 25 to 99.9% by weight of a phosphinic acid salt of the formula (I) wherein R, Rare the same or different and are each C-C-alkyl, linear or branched, C-C-aryl, C-C-arylalkyl or C-C-alkylaryl, or Rand Rform one or more rings with each other, M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; as component B, from 0 to 75% by weight of a synergist or of a phosphorus/nitrogen flame retardant and, as component C, from 0.1 to 30% by weight of telomeric phosphinic acid salts as component D, from 0 to 20% by weight of organo phosphonic acid salt, as component E, from 0 to 5% by weight of phosphonic acid salt, the sum of the components always being 100% by weight, and wherein the angle of repose of said flame retardant-stabilizer combination is between 5&#xb0; and 45&#xb0;. 

The invention relates to a flame retardant mixture comprising 99.9999% to 87% by weight of diorganylphosphinic acid salts as component A) and 0.0001% to 13% by weight of iron as component B), where the sum total of A) and B) is 100% by weight. The invention likewise relates to processes for producing the aforementioned flame retardant mixture and to the use thereof.

Flame retardant mixtures, the production and the use thereof

Flame retardant mixtures comprising as component (A) 30% to 99.9% by weight of dialkylphosphinic salts of the formula (II), a and b may be the same or different and are each independently 1 to 9, and where the carbon chains may be linear, branched or cyclic and M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base and m is 1 to 4, as component (B) 0.1% to 70% by weight of alkyl hydroxyalkylphosphinyl organylcarboxylic acid salts and/or ester salts of the formula (I) where R1CyH2y+1 with y=2 to 8, R2, R3, R4, R5, R6 are the same or different and are each independently H, CxH2x+1, CxH2x&#x2212;1, CxH2x&#x2212;3, CxH2xCO2X, CxH2x&#x2212;2CO2X, CxH2x&#x2212;4CO2X, (C2H3CO2X)u and u=0 to 1000000, CO2X, CxH2x(P(O)(OM)R1), CxH2x&#x2212;2(P(O)(OM)R1)(CO2X) and/or CH2CO2X, where, in the R1, R2, R3, R4, R5 and R6 groups, the carbon chains may be linear, branched or cyclic, M' is Mg, Ca, Al, Sb, Sn, Ge, Fe, Ti, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K, H and/or N-containing cations, x is 1 to 25, X is H, M, CzH2z+1 and z is 1 to 8, with the proviso that at least one of the R2, R3, R4, R5, R6 groups is not H, and the compounds of formula (II) and formula (I) are different compounds.

Flame retardant mixtures and production thereof

A halogen-free flame retardant mixture containing between 1-99 wt. % of a component A and between 1-99 wt. % of a component B. Component A comprises between 85-99.995 wt.-% of a solid diethylphosphinic acid salt of the metals Mg, Ca, Al, Sb, SN, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base and between 0.005-15 wt.-% of non-combustible additives and component B is in the form of an aluminum phosphite.

Halogen-free solid flame retardant mixture and use thereof

The invention relates to mixed alkali-aluminum phosphites of the formula (I)AlM(HPO)(OH)(HO)&#x2003;&#x2003;(I)in whichM represents alkali metal ions,z is 0.01 to 1.5,y is 2.63 to 3.5,v is 0 to 2,w is 0 to 4;to a process for preparation thereof and to the use thereof.

Mixed alkali-aluminum phosphites, method for producing same, and the use thereof

Mixtures of at least one dialkylphosphinic acid with at least one other dialkylphosphinic acid that is different therefrom, method for production thereof, and use thereof. The invention relates to a mixture of at least one dialkylphosphinic acid of the formula (I) in which in which

Mixtures of at least one dialkylphosphinic acid with at least one other dialkylphosphinic acid that is different therefrom, method for production thereof, and use thereof

The invention relates to mixtures of aluminum phosphite with sparingly soluble aluminum salts and nitrogen-free extraneous ions, comprising 80 to 99.898% by weight of aluminum phosphite of the formula (I)Al(HPO)HO&#x2003;&#x2003;(I)in which x is 0 to 4,

Mixtures of aluminum phosphite with sparingly soluble aluminum salts and foreign ions, process for the production thereof and the use thereof

The invention relates to mixtures of at least one dialkylphosphinic acid of the formula (I) in which in which

Mixtures of dialkylphosphinic acids and alkylphosphinic acids, a process for preparation thereof and use thereof

The invention relates to mixtures of aluminum hydrogenphosphites of the formula (I)Al(HPO)(HPO)(HO)&#x2003;&#x2003;(I)and aluminum salts comprising

Mixtures of aluminum hydrogenphosphites with aluminum salts, process for the production thereof and the use thereof

Growing community of inventors

Kerpen, Germany

Harald Bauer