Zhejiang University

Hao Song

Xiang Gao

Zhongyang Luo

Kefa Cen

Mingjiang Ni

Weihong Wu

Hongmin Yu

Mengxiang Fang

Qinhui Wang

Chunjiang Yu

Jinsong Zhou

Chenghang Zheng

Shurong Wang

Zhenglun Shi

Dian Xu

Kunzan Qiu

Lemin Cheng

Xinbo Zhu

Disclosed are a catalyst for synergistic control of oxynitride and mercury and a method for preparing the same. The catalyst includes the following components by mass percentage: a carrier: TiO2 72%-98.6%, active components: V2O5 0.1%-5%, WO3 1%-10%, Cr2O3 0.1%-5% and Nb2O5 0.1%-5%, and a co-catalyst of 0.1%-3%. The present invention can be used for reducing the oxynitrides in a flue gas, meanwhile oxidizing zero-valent mercury into bivalent mercury and then controlling the reactions, has relatively high denitration performance and also has high mercury oxidation performance; compared with current commercial SCR catalysts, the mercury oxidation rate of the catalyst is improved to a great extent, which can adapt to the requirements for mercury removal in China's coal-fired power plants, the conversion rate of SO2/SO3 is relatively low, and the catalyst has a better anti-poisoning ability, and is a new catalyst with a low cost and high performance.

Catalyst for synergistic control of oxynitride and mercury and method for preparing the same

Disclosed is a method for regenerating a SCR denitration catalyst assisted by microwaves. The method comprises: (1) a poisoned SCR denitration catalyst is immersed in deionized water, and the SCR denitration catalyst is cleaned by a bubbling method; (2) the SCR denitration catalyst is transferred to a container containing a pore-expanding solution for a soaking treatment; (3) the SCR denitration catalyst is transferred to a microwave device and treated for 1-10 minutes; (4) the SCR denitration catalyst is transferred to a container with an activating liquid and impregnated for 1-4 hours; (5) the SCR denitration catalyst is dried with microwaves for 1-20 minutes; and (6) the SCR denitration catalyst is calcined under conditions of 500-600&#xb0; C. for 4-7 hours. The present invention has readily available raw materials, is simple and energy-saving in device and process, and is suitable for industrial scale regeneration. The catalyst treated by the method of the present invention has the advantages of loose pore channels, obviously optimized pore structures, significantly improved catalyst surface conditions, high activity, and good economic benefits.

Method for regenerating SCR denitration catalyst assisted by microwaves and device therefor

Growing community of inventors

Hangzhou, China

Hao Song