China Petroleum & Chemical Corporation

Research Institute of Petroleum Processing, Sinopec

Hao Sha

Huiping Tian

Zhenyu Chen

Weilin Zhang

Shuai Yuan

Lingping Zhou

Mingde Xu

Qiuqiao Jiang

A modified Y-type molecular sieve has a rare earth content of about 4% to about 11% by weight on the basis of the oxide, a phosphorus content of about 0.05% to about 10% by weight on the basis of PO, a sodium content of no more than about 0.5% by weight on the basis of sodium oxide, a gallium content of about 0.1% to about 2.5% by weight on the basis of gallium oxide, and a zirconium content of about 0.1% to about 2.5% by weight on the basis of zirconia; and the modified Y-type molecular sieve has a total pore volume of about 0.36 mL/g to about 0.48 mL/g, a percentage of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 20% to about 40%.

Modified Y-type molecular sieve, catalytic cracking catalyst comprising the same, their preparation and application thereof

A modified Y-type molecular sieve has a rare earth content of about 4-11% by weight on the basis of rare earth oxide, a sodium content of no more than about 0.5 wt % by weight on the basis of sodium oxide, a zinc content of about 0.5-5% by weight on the basis of zinc oxide, a phosphorus content of about 0.05-10% by weight on the basis of phosphorus pentoxide, a framework silica-alumina ratio of about 7-14 calculated on the basis of SiO/AlOmolar ratio, a percentage of non-framework aluminum content to the total aluminum content of no more than about 10%, and a percentage of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 20-40%. The modified Y-type molecular sieve has a high crystallinity and a high thermal and hydrothermal stability, and is rich in secondary pores.

A modified Y-type molecular sieve has a modifying metal content of about 0.5-6.3 wt % calculated on the basis of an oxide of the modifying metal and a sodium content of no more than about 0.5 wt % calculated on the basis of sodium oxide. The modifying metal is magnesium and/or calcium. The modified Y-type molecular sieve has a proportion of non-framework aluminum content to the total aluminum content of no more than about 20%, a total pore volume of about 0.33-0.39 ml/g, a proportion of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 10-25%, a lattice constant of about 2.440-2.455 nm, a lattice collapse temperature of not lower than about 1040&#xb0; C., and a ratio of B acid to L acid in the total acid content of no less than about 2.30.

Modified Y-type molecular sieve, catalytic cracking catalyst comprising the same, its preparation and application thereof

A modified Y-type molecular sieve has a rare earth content of about 4% to about 11% by weight on the basis of the oxide, a phosphorus content of about 0.05% to about 10% by weight on the basis of PO, a sodium content of no more than about 0.5% by weight on the basis of sodium oxide, and an active element content of about 0.1% to about 5% by weight on the basis of the oxide, with the active element being gallium and/or boron. The modified Y-type molecular sieve has a total pore volume of about 0.36 mL/g to about 0.48 mL/g, a percentage of the pore volume of secondary pores having a pore size of 2-100 nm of about 20% to about 40%; a lattice constant of about 2.440 nm to about 2.455 nm, and a lattice collapse temperature of not lower than about 1060&#xb0; C.

A modified Y-type molecular sieve having a calcium content of about 0.3-4 wt % calculated on the basis of calcium oxide, a rare earth content of about 2-7 wt % calculated on the basis of rare earth oxide, and a sodium content of no more than about 0.5 wt % calculated on the basis of sodium oxide. The modified Y-type molecular sieve has a total pore volume of about 0.33-0.39 ml/g, a proportion of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 10-25%, a lattice constant of about 2.440-2.455 nm, a proportion of non-framework aluminum content to the total aluminum content of no more than about 20%, a lattice collapse temperature of not lower than about 1050&#xb0; C., and a ratio of B acid to L acid in the total acid content of no less than about 2.30.

A modified Y-type molecular sieve has a rare earth content of about 4-11% by weight on the basis of rare earth oxide, a sodium content of no more than about 0.7% by weight on the basis of sodium oxide, a zinc content of about 0.5-5% by weight on the basis of zinc oxide, a phosphorus content of about 0.05-10% by weight on the basis of phosphorus pentoxide, a framework silica-alumina ratio of about 7-14 calculated on the basis of SiO/AlOmolar ratio, a percentage of non-framework aluminum content to the total aluminum content of no more than about 20%, and a percentage of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 15-30%. The modified Y-type molecular sieve has a high crystallinity, a structure comprising secondary pores, and a high thermal and hydrothermal stability.

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Beijing, China

Hao Sha