Dsm IP Assets B.v.

Hao Chen

Alexander Antonius Marie Stroeks

Roman Stepanyan

Marko Dorschu

Martinus Joseph Maria Keulers

James Calvin Miller

The invention relates to a co-extruded film comprising a sealing layer of low density polyethylene and a skin layer, wherein the skin layer comprises a copolyamide which comprises: &#x2022;At least 75 wt % monomeric units derived from caprolactam; &#x2022;Between 5 to 25 wt % monomeric units derived from a diamine and terephthalic acid; wherein the weight percentage is with respect to the total weight of copolyamide in the skin layer. The invention also relates to a process for preparing such a film, as well as applications of the film.

Co-extruded film

The invention relates to a yarn comprising a copolyamide in an amount of at least 90 wt % with respect to the total weight of the yarn, which copolyamide comprises a) at least 95 wt % by weight with respect to the total weight of copolyamide, monomeric units derived from hexamethylene diamine and adipic acid and b1) cyclic monomeric units derived from a diamine X, and cyclic monomeric units derived from a diacid Y, and/or b2) cyclic monomeric units derived from an amino acid Z, in which the summed amount of monomeric units derived from X,Y and Z is between 0.1 to 4.5 wt % by weight with respect to the total weight of the copolyamide and wherein the yarn has a tensile strength of at least 80 cN/tex as measured according to ASTM D885-04. The invention also relates to a process for preparing the yarn.

High strength polyamide yarn

Processes are disclosed for preparing biaxially oriented film by forming a polymer melt of a composition which includes at least 50 wt % with respect to the total amount of the composition of a copolyamide having at least 75 wt. % monomeric units derived from either (i) caprolactam or (ii) hexamethylene diamine and adipic acid, each of which further includes units derived from diamines X and/or diacids Y and/or aminoacids Z in a summed amount of between 0.2 to 25 wt %, followed sequentially by casting and quenching a film of the polymer melt, MD-stretching of the film, TD-stretching the film, cooling the film after TD-stretching, and heat setting the biaxially oriented film. The resulting biaxially oriented film exhibits attributes suitable for use as food packaging.

Process to prepare biaxially oriented film

This invention relates to a process for the preparation of an antiballistic article, the method comprising: a) Providing a transparent uniaxially stretched polymeric film with at least one layer I comprising a semi-crystalline thermoplastic polymer A and at least one layer II comprising an amorphous or semi-crystalline thermoplastic polymer B, of which polymer B has a glass transition temperature less than the melting temperature of polymer A if polymer B is amorphous or of which polymer B has a melting temperature less than the melting temperature of polymer A if polymer B is semi-crystalline; b) Stacking at least two of the uniaxially stretched polymeric films of a) at an angle a of between 45&#xb0; and 135&#xb0;, such that the films are in contact with each subsequent film through at least one layer II, to form an assembly; c) Compressing the thus formed assembly at a temperature above the glass transition temperature of polymer B if polymer B is amorphous, or above the melting temperature of polymer B if polymer B is semi-crystalline, and below the melting temperature of polymer A, to obtain an haze of at most 50% and having an energy absorption for 17 grain FSP according to the STANAG 2920 standard of at least 12 J/(kg/m). The invention also relates to antiballistic articles.

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Echt, Netherlands

Hao Chen