Degussa Aktiengesellschaft

Degussa & Henkel Kommanditgesellschaft Auf Aktien

Henkel Kommanditgesellschaft Auf Aktien (henkel Kgaa)

Henkel Kommanditgesellschaft Auf Aktien

Deutsche Gold- Und Silber-scheideanstalt Vormals Roessler

Henkel Kommanditgessel

Hans Strack

Peter K Kleinschmit

Ehrfried Parr

Dieter Kneitel

Wolfgang Roebke

Rudolf Schwarz

Roland Reuter

Gerhard Sextl

Gunter Turk

Carl Voigt

Rudolf Bode

Arthur Reisert

Gangolf Kriechbaum

Ilona Fuss

Heat insulator and method of making it

A shaped body, preferably plate-shaped, for use as heat insulation, formed of (a) a finely distributed, powdery or fibrous substance, (b) a microporous casing, and (c) a gastight and watertight, metal-free casing. The shaped body is produced by drying a powdery or fibrous substance if necessary, optionally placing it into a microporous casing, optionally pressing and then optionally drying. Thereafter, the powdery substance is placed with the microporous casing into a gastight and watertight, metal-free casing. This gastight and watertight casing is optionally evacuated and sealed. Furthermore, a shaped article, preferably plate-shaped, for use as heat insulation, produced from (a) a finely distributed, powdery or fibrous substance with a water absorption capacity of 4 to 50% by weight at 23.degree. C. and 85% relative humidity, (b) a casing of two parts with asymmetric design which contains this finely distributed, powdery or fibrous substance, the first part of the casing being metal-free and concave in such a manner that it is completely filled by the preferably plate-like shaped article and the second part being metal-free or metallic and planar and connected to the trough in such a manner that a gastight and water-vapor-tight seal is assured and both parts having water-vapor-permeabilities between 0 and 0.2 g/m.sup.2 /d at 23.degree. C. and 85% relative humidity and gas permeabilities for N.sub.2, O.sub.2 and CO.sub.2 of in sum 0 to 0.5 cm.sup.3 /m.sup.2 d/bar at 23.degree. C.; the shaped article having the property of absorbing water up to an amount of 2 to 15% by weight without its thermal conductivity deteriorating more than 25%.

Form body for heat insulation and vacuum insulation panel with

Heat insulator and method of making same

Precipitated silica is mixed with a solution of caustic soda, water and sodium aluminate to form a mixture of the composition:

Process for the production of a seed mixture for the synthesis of

Silicate-bound zeolite granulates are disclosed wherein the zeolite contains a cation which is not present in the binder, and where the zeolite can also contain the binder cation. The granulates are produced by placing powdered zeolite in a mixer, adding sodium silicate solution, mixing until zeolite granulates with a grain size of at least 0.1 mm are obtained, optionally after-rolling the zeolite granulates. The moist zeolite granulates can be initially dried at temperatures of 20 degrees to 39 degrees C., where the carbon dioxide content of the drying air is adjusted to less than 200 ppm. Thereafter, a second drying step can be carried out at temperatures of 40 degrees to 120 degrees C. as well as a third drying stage at 121 degrees to 200 degrees C. under otherwise identical conditions. The products may be activated at temperatures of 600 degrees C. maximum. The zeolite granulates thus obtained are then treated with a first aqueous metal salt solution, washed and then optionally treated with a second aqueous metal salt solution, washed and dried again at 40 degrees to 200 degrees C., preferably 100 degrees to 120 degrees C., and then optionally calcined to 300 degrees to 650 degrees C.

Silicate-bound zeolite granulates, process for their production and use

Magnesium-silicate bound zeolite granulates of type A are disclosed wherein the zeolite component does not contain magnesium exclusively, or contains no magnesium at all, as the cation. The granulates are produced by placing powdered zeolite A in a mixer, adding sodium silicate solution, mixing until zeolite granulates with a grain size of at least 0.1 mm are obtained, optionally after-rolling these zeolite granulates, optionally initially drying the moist zeolite granulates at temperatures of 20 to 39 degrees C., during which the carbon dioxide content of the drying air is adjusted to less than 200 ppm, then optionally drying in a second drying step at temperatures of 40-120 degrees C. and optionally in a third drying stage at 121-200 degrees C. under otherwise identical conditions, and then optionally activating the granulates thus obtained at temperatures of 600 degrees C. maximum. The granulates thus obtained are treated with an aqueous magnesium salt solution, washed, then optionally treated with aqueous metal salt solution, washed, dried at 40-200 degrees C., preferably 100 to 120 degrees C., and then optionally calcined at 300 to 650 degrees C.

Magnesium-silicate bound zeolite granulates of the type of zeolite A,

According to the invention there are produced sodium Zeolite A granulates having the following parameters:

Zeolite granulate, process for its production and use

A seed mixture is produced by reacting an amorphous, synthetic sodium aluminum silicate with an Na.sub.2 O-supplying compound in an aqueous system at temperatures of 10.degree. to 35.degree. C. (room temperature). The seed mixture exhibits a composition of Na.sub.2 O:Al.sub.2 O.sub.3 :SiO.sub.2 :H.sub.2 O=(12.+-.3):1:(15.+-.3):(240.+-.60). This seed mixture can be used in the synthesis of zeolite Y and/or zeolite X.

Process for the production of a seed mixture for faujasite synthesis

There are produced crystalline zeolite powders of Type A with the composition

Process for preparing zeolite powder of type A (IV)

Zeolite granulate, process for its production

There is produced crystalline zeolite powder of Type A having an average particle diameter of 8.5 to 9.0.mu. by introducing the components waterglass and alkali aluminate liquor under defined conditions simultaneously into a receiver containing alkali aluminate, stirring, first adding more alkali aluminate liquor and then more waterglass solution. The thus obtained crystalline zeolite powder of Type A is used as a phosphate substitute in washing agents.

Process for the production of crystalline zeolite A

There is produced a crystalline zeolite powder of Type A which can be employed as a phosphate substitute in washing agents by a precipitation reaction by a specific sequence in which there are simultaneously added to water in a container a waterglass solution and a sodium aluminate liquor and subsequently in succession a waterglass solution and then sodium aluminate liquor. The crystalline product has an average particle size of 6.7 to 8.mu. as well as a narrow particle size distribution curve.

Process for the production of crystalline zeolite powder of type A

There is produced crystalline zeolite powder of Type A having an average particle diameter of 7 to 8.5.mu. by introducing the components waterglass and alkali aluminate liquor under defined conditions simultaneously into a receiver containing water, stirring, subsequently first adding more alkali aluminate liquor and then more waterglass solution. The thus obtained crystalline zeolite powder is used as a phosphate substitute in washing agents.

Process for the production of zeolite A

Crystalline zeolite powder of Type A is employed as a phosphate substitute in washing agents. For this use, it is advantageous if the crystalline zeolite powder of Type A has a specific average particle diameter of 4.3 to 8.5.mu. as well as a specifically narrow particle size distribution. By a specific sequence in the addition of the reactants in the precipitation of zeolites A this requirement of the product is fulfilled. Thereby water is present in a receiver and there are simultaneously added sodium aluminate liquor and waterglass solution and subsequently after a long stirring phase there are added further sodium aluminate liquor and further waterglass solution. The maximum grit content of the zeolite powder of Type A obtained is 0.2%.

For the reduction of the ammonia content in the product gas of the hydrocyanic acid-methane-ammonia (BMA) process and accordingly to increase the yield the reaction gas mixture of this process is brought into contact with zeolite and the ammonia thereafter desorbed from the zeolite preferably again employed in the reaction step. If the desorption is carried out with a flushing gas such as the hydrocarbon used in the reaction then this mixture can be directly supplied again to the BMA reactor. Through this procedure the amount of ammonia previously lost to the process can again be made useful in the process itself.

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Alzenau, Germany

Hans Strack