Hoechst Aktiengesellschaft

Hans-Jurgen Kalz

Hans-Peter Rieck

Jochen M Quack

Hans-Walter Bucking

Thomas Blumenthal

Adolf May

Manfred Hofinger

Johann F Hanauer

Armin Weiss

A crystalline swellable sheet silicate of the saponite type, of the formula

Process for the preparation of a crystalline, swellable sheet silicate

Adsorbents for polar organic compounds can be prepared by reacting 5-80% of an organic ammonium compound with 20-95% of a crystalline alkali metal phyllosilicate belonging to the group comprising phyllosilicates of the formula

Adsorbents based on phyllosilicic acids which have been modified so as

Gel-forming organophilic layer silicate whose exchangeable cations have been wholly or partly replaced by a quaternary ammonium compound of the formula ##STR1## where R.sub.1 and R.sub.2 can be identical or different and denote C.sub.6 C.sub.30 -alkyl or C.sub.6 -C.sub.30 -alkenyl, R.sub.3 denotes C.sub.1 -C.sub.6 -alkyl, R.sub.4 denotes C.sub.1 -C.sub.6 -alkyl, A denotes the group --C.sub.2 H.sub.4 -- or --C.sub.3 H.sub.6 -- and n denotes 1 or 2. These organically modified layer silicates are used as thixotroping agents, for example for surface coatings and antirust primers.

Gel-forming organophilic layer silicate, process for its preparation and

Softener-containing washing agents which, in addition to the customary components of washing agents, contain 0 to 10% by weight of a quaternary ammonium compound and 1 to 30% by weight of a softener system which comprises 10 to 90% by weight of a tertiary amine and 90 to 10% by weight of a crystalline sheet-silicate of the formula

Softener-containing washing agent

The invention provides a process for the manufacture of a crystalline, phosphorus-containing zeolite of the ZSM-5 type by mixing water, a silicon dioxide source, an alkali metal hydroxide and an aluminum compound, and reacting this mixture at a temperature of from 95.degree. to 230.degree. C. until the zeolite has crystallized, which comprises carrying out the reaction without addition of an organic compound but in the presence of aluminum phosphate. The zeolite obtained has the following molar ratios:

Aluminosilicates having a zeolite structure, and process for the

The invention provides a process for the manufacture of zeolites of the ZSM-5 type by heating an aqueous solution or suspension containing a silicon dioxide source, alkali metal hydroxide and optionally an aluminum source until crystallization occurs. Furthermore, the solution or suspension contains an organic phosphorus compound which is selected from the group consisting of OPR.sup.1 R.sup.2 R.sup.3 and PR.sup.1 R.sup.2 R.sup.3, in which R.sup.1, R.sup.2 and R.sup.3, independently from one another, each are alkyl or alkoxy having each from 2 to 10 carbon atoms.

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Liederbach, Germany

Hans-Jurgen Kalz