Basf Aktiengesellschaft

Badische Anilin- & Soda-fabrik Aktiengesellschaft

Hans Juergen Nienburg

Rudolf Kummer

Wilhelm Kniese

Peter Tavs

Max Strohmeyer

Heinz Hohenschutz

Production of aldehydes and alcohols by hydroformylation of olefinically unsaturated compounds with carbon monoxide and hydrogen at elevated temperature and superatmospheric pressure in the presence of carbonyl complexes of metals of group 8 of the Periodic System which have been modified with trisubstituted phosphines in which two substituents are lower alkyl radicals and the third substituent is a higher aliphatic radical. Aldehydes and alcohols are known to be solvents; they are used on a large scale for the production of plasticizers for polyvinyl chloride.

Production of aldehydes and alcohols by the oxo method

An improved process for the production of aliphatic or cycloaliphatic dialdehydes or acetals of the same by reaction of an aliphatic or cycloaliphatic conjugated diene with carbon monoxide and hydrogen in the presence of a rhodium catalyst which is modified with a tertiary phosphine or phosphite at a temperature of from 70.degree. to 160.degree. C and at a pressure of from 100 to 600 atmospheres, the improvement consisting in using as catalyst a rhodium complex which contains carbon monoxide, a tertiary organic phosphine or tertiary organic phosphite and a halogen atom as ligands. Aliphatic and cycloaliphatic dialdehydes or the acetals of the same are suitable for the production of the corresponding diols which may be used in the production of polymers and particularly of polyurethanes.

Production of bis-(dimethyl) acetals of hexane dialdehydes

Production of aldehydes and alcohols by oxo synthesis involving the reaction of olefinic compounds with carbon monoxide and hydrogen at elevated temperatures and under elevated pressures in the presence of amine-modified carbonyl complexes of cobalt or rhodium. Diamino diphenyl alkanes are used as modifying agents.

Manufacture of aldehydes and alcohols

An improved process for the production of aldehydes and alcohols by the oxo process comprising the reaction of olefinically unsaturated compounds with carbon monoxide and hydrogen at elevated temperatures and elevated pressures in the presence of carbonyl complexes of metals in Group VIII of the Periodic Table modified by trisubstituted organic phosphines and in the presence of alkali or alkaline earth metal salts of carboxylic acids, the improvement comprising the use of modifying agents which consist of trisubstituted organic phosphines containing one or more carboxylic acid groups, at least one of which is present in the form of its alkali metal or alkaline earth metal salt.

Production of alcohols and/or aldehydes

Solutions of cobalt carbonyl and cobalt carbonyl hydride in organic solvents are prepared by treating aqueous solutions of cobalt salts with carbon monoxide and hydrogen at a temperature of from 50.degree. to 200.degree.C and a pressure of from 50 to 500 atmospheres in the presence of solvents which are sparingly water-miscible or are water-immiscible and which have a content of cobalt carbonyl, cobalt carbonyl hydride or mixtures thereof, the starting materials and the organic solvents being passed cocurrently through a zone in which a turbulent flow is maintained. The improvement includes using n-butanol as solvent. Solutions of cobalt carbonyl and cobalt carbonyl hydride in n-butanol are suitable as catalyst solutions for oxo syntheses.

Continuous manufacture of solutions of cobalt carbonyl and cobalt

An improved process for the production of .alpha.,.omega.-dialdehydes by reaction of linear .alpha.,.omega.-diolefins having isolated double bonds with carbon monoxide and hydrogen at elevated temperature and at superatmospheric pressure in the presence of a cobalt carbonyl complex in which the improvement consists in supplying the cobalt to the reaction as cobalt carbonyl hydride dissolved in the .alpha.,.omega.-diolefin to be used or in an inert organic solvent and carrying out the reaction at a temperature of from 70.degree. to 130.degree.C.

Growing community of inventors

Ludwigshafen, Germany

Hans Juergen Nienburg