Zimmer Aktiengesellschaft

Davy Mckee Corporation

Davy Mckee Aktiengesellschaft, Borsigalle

Hans-Jochen Rothe

Konrad Wolff

Georg Skupin

Hansdieter Hofmann

Helmut Heinze

Werner Gey

Peter Freund

Production of spinnable polyhexamethylene adipamide of high molecular weight from adiponitrile, hexamethylene diamine, water and additives, preferably continuously in a reaction cascade and in a finisher as the final stage, catalytically accelerated by catalysts as disclosed. The polyamides can be produced from dinitriles, diamines and excess water in the presence of catalysts selected from the group consisting of: alkyl, aryl and alkyl/aryl esters of phosphoric, phosphorous, phosphonic and phosphinic acids. The catalyst is present in the amount of 0.001 to 1.0% based upon the total weight of the reactants.

Method for producing spinnable polyamide from dinitrile with phosphorus

Production of spinnable polyhexamethylene adipamide of high molecular weight from adiponitrile, hexamethylene diamine, water and additives, preferably continuously in a reaction cascade and in a finisher as the final stage, catalytically accelerated by catalysts as disclosed. It has now been discovered that polyamides can be produced from dinitriles, diamines and excess water in the presence of catalysts selected from the group consisting of: (1) oxygen-containing phosphorous compounds; (2) oxygen-containing boron compounds; (3) acidic oxygen-containing sulfur compounds; and (4) hydrogen halide and ammonium or ammonium alkyl salt thereof.

Preparation of spinnable polyamide from dinitrile, diamine, H.sub.2 O

Polyethylene terephthalate having an acetaldehyde content of less than 2.5 ppm and suitable for packing of food and beverages intended for human consumption is produced by heating polyethylene terephthalate having an intrinsic viscosity of about 0.5--0.85 at a temperature of 180.degree.-230.degree. C., preferably 200.degree.-220.degree. C., for about 4 to 12 hours. The polyethylene terephthalate must not include more than 25 ppm of ester interchange catalyst or 20 ppm of phosphorous during this heating.

Process for production of polyester polymer for food packing

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Maintal, Germany

Hans-Jochen Rothe