Th. Goldschmidt Ag

F.joh.kwizda Gesellschaft M.b.h.

Hans-Joachim Kollmeier

Rolf-Dieter Langenhagen

Helmut Lammerting

Klaus Hoffmann

Burghard Gruning

Gerd Rossmy

Gotz Koerner

Christian Weitemeyer

Georg Burkhart

Dietmar Schaefer

Joachim Giersberg

Helmut Schator

Alfred Walter

Bernd-Jurgen Klietsch

Rudolf Huttinger

Bernd-Juergen Klietsch

Hans-Heinrich Schloens

Wilhelm Wolfes

Wilhelm Zsifkovits

Werner Lidy

Betaine group-containing polysaccharides with recurring anhydroglucose units of the average, general formula ##STR1## are disclosed. In this formula the R.sup.1 groups are the same or different and represent methyl, ##STR2## in which n=2 or 3, m=0 to 10, p=0 to 10 and R.sup.2 is a hydrogen atom or the betaine group ##STR3## in which R.sup.3 and R.sup.4 are the same or different and represent an alkyl group with 1 to 4 carbon atoms and R.sup.5 is a divalent aliphatic hydrocarbon group with 1 to 10 carbon atoms, with the proviso that at least 0.5% of the R.sup.1 groups in the polysaccharide molecule represent the betaine group. Also disclosed is a method for the synthesis of these compounds and their use in cosmetic preparations, expecially for the care of the hair. In addition, novel compounds of the general formula ##STR4## are disclosed as intermediates in which the substituents R.sup.3, R.sup.4 and R.sup.5 have the above meaning.

Betaine group-containing polysaccharides with recurring anhydroglucose

A process of preparing rigid polyurethane foams is disclosed, wherein polysiloxane polyoxyalkylene block copolymers which have at least one aminofunctional group of the general formula, ##STR1## which is linked to a silicon atom, are used in an amount of 0.2 to 5% by weight, based on the polyol or the prepolymer having isocyanate groups, to provide polyurethane foams, which otherwise contain closed cells, with at least partially open the cells.

Use of polysiloxane polyoxyalkylene block copolymers for the preparation

Betaine group-containing polysaccharides with recurring anhydroglucose units of the average, general formula ##STR1## are disclosed. In this formula the R.sup.1 groups are the same or different and represent methyl, (C.sub.n H.sub.2n O).sub.m R.sup.2 or ##STR2## in which n=2 or 3, m=0 to 10, p=0 to 10 and R.sup.2 is a hydrogen atom or the betaine group ##STR3## in which R.sup.3 and R.sup.4 are the same or different and represent an alkyl group with 1 to 4 carbon atoms and R.sup.5 is a divalent aliphatic hydrocarbon group with 1 to 10 carbon atoms, with the proviso that at least 0.5% of the R.sup.1 groups in the polysaccharide molecule represent the betaine group. Also disclosed is a method for the synthesis of these compounds and their use in cosmetic preparations, especially for the care of the hair. In addition, novel compounds of the general formula ##STR4## are disclosed as intermediates in which the substituents R.sup.3, R.sup.4 and R.sup.5 have the above meaning.

A method and composition are disclosed for the preparation of polyurethane and polyurea molded articles, particularly according to the RIM method, in which liquid polybutadiene with an average molecular weight of 1,500 to 6,000 is used as an internal release agent in an amount of 0.5 to 5% by weight, based on the reaction formulation. The release agent is highly effective and demolded products which contain this release agent can be painted over without formation of surface defects.

Method for the preparation of molded polyurethane and polyurea articles

In a method for the preparation of highly elastic, cold curing polyurethane foams, equilibrated organofunctional polysiloxanes of the average general formula ##STR1## wherein R.sup.1 is methyl or R.sup.2,

Method for the production of highly elastic, cold-curing polyurethane

In a process for the preparation of molded polyurethane or polyurea articles, especially by the RIM process, internal release agents of the general formula ##STR1## are used. In this formula R.sup.1 =is alkyl with 20 to 40 carbon atoms,

Release agent and process for the preparation of molded polyurethane or

Betain group-containing derivatives of carboxymethylcellulose are disclosed. They are characterized in that all or a portion of the carboxymethyl groups are or is replaced by groups of the general formula ##STR1## wherein R.sup.1 is hydrogen or methyl group,

Betaine group-containing derivatives of carboxymethylcellulose, their

Derivatives of carboxymethylcellulose are disclosed in which all or a portion of the carboxymethyl groups are replaced by groups of the general formula ##STR1## in which R.sup.1 is a hydrogen or methyl group,

Nitrogen-containing derivatives of carboxymethylcellulose, their

Phosphobetaines of the general formula ##STR1## are disclosed in which R.sup.1 is an alkyl group with 1 to 20 carbon atoms, optionally substituted with OH groups, or the ##STR2## group, in which R.sup.6 is a divalent alkylene group with 1 to 10 carbon atoms, optionally substituted with OH group,

Phosphobetaines, methods for their synthesis and their use especially

An organic phase which comprises a water-insoluble material to be encapsulated, a capsule-forming or matrix-forming monomer or prepolymer and, should this be desirable, a solvent, is dispersed in droplet form in an aqueous phase. The capsule-forming or matrix-forming monomer or prepolymer forms a sheath around the material to be encapsulated. As a capsule-forming or matrix-forming monomer, an organosilicon compound of the general formula ##STR1## is used, wherein R.sup.1 is a linear or branched, saturated or unsaturated, n-functional hydrocarbon moiety, which may be interrupted by groups containing oxygen, nitrogen or sulfur; R.sup.2 and R.sup.3 are the same or different and represent a hydrocarbon moiety with 1 to 6 carbon atoms or X; X is a hydroxyl group or a hydrolyzable group and n is a whole number greater than or equal to 1, with the proviso that, when n=1, R.sup.1 has at least 12 carbon atoms and R.sup.2 and R.sup.3 represent X or a prepolymer hereof. The method can be carried out easily and requires only one compound to form the capsules or micromatrix bodies. In the implementation of the method, no foam occurs and the method results in end products with an acceptable shelf life.

Microcapsule and micromatrix bodies and method for their formation

Process for producing molded polyurethane parts using as internal release agents, compounds of the general formula ##STR1## in amounts of 0.5 to 10 weight percent, based on the reaction formulation, in which at least one R.sup.2 radical in the average molecule represents ##STR2## R.sup.3 is a divalent hydrocarbon radical with 2 to 4 carbon atoms and R.sup.4, R.sup.5 are univalent hydrocarbon radicals or together are part of a morpholine or a piperazine ring. The molded polyurethane parts can be removed from the mold using significantly lower tensional forces without residues being built up on the mold.

Siloxanes containing tertiary amino groups

Process for producing molded polyurethane parts

The invention relates to the use of copolymers of the average formula ##STR1## in which R is an alkyl radical with 1 to 4 carbon atoms or a hydrogen radical;

Use of polyoxyalkylene-polysiloxane copolymers with silicon-linked,

Process for manufacturing of molded objects by hot-pressing lignocellulose-containing materials with polyisocyanates as binders while using an agent to release the molded article from the surface of the metal press used. A mixture of the organosilicon compounds is applied onto the surface of the cauls or molds which faces the material to be pressed, and cured at a temperature from 100.degree. to 200.degree. C., preferably in the presence of known curing catalysts. The mixture of organosilicon compounds comprising

Process for the manufacture of molded objects

Process for the preparation of flexible polyurethane foams using polysiloxane-polyoxyalkylene block copolymers as stabilizers having the general formula: ##STR1## in which A represents A.sup.1 and A.sup.2 polyoxyalkylene blocks, as defined hereinafter, which are linked to silicon over carbon and which have the general formula --R.sup.2 --O--(C.sub.x H.sub.2x O--).sub.y R.sup.3, R.sup.2 being a divalent hydrocarbon radical with 2 to 4 carbon atoms and R.sup.3, x and y are as defined hereinafter,

Growing community of inventors

Essen, Germany

Hans-Joachim Kollmeier