Huntsman International LLC

Hans Godelieve Guido Verbeke

Gerhard Jozef Bleys

Jan Willem Leenslag

Hugo Verbeke

Christian Esbelin

Eric Huygens

Rene Alexander Klein

Chris Ian Lindsay

Giacomo Giannini

Christina Marinus

Christiaan Debien

Jan-Willem Leenslag

Marc Vandervesse

Stijn Roekaerts

Ainara Astaburuaga Gutierrez

Danny Anna Edward Geukens

William Andrew Daunch

Danny Anna Eduard Geukens

An in-situ formed polyurethane catalyst for catalyzing the formation of polyurethane in a reactive composition comprising polyisocyanate compounds and isocyanate reactive compounds, said catalyst formed by combining in said reactive composition:

In-situ formation of polyurethane catalysts

Use of compounds selected from polyols derived from dimer fatty acids and/or dimer fatty alcohols as toughening agent in a process for making polyisocyanate polyaddition reaction products, in particular for polyisocyanate polyaddition reaction products having a hardblock &#x3e;40% and a process for making said products.

Method for improving toughness of polyisocyanate polyaddition reaction products

A curable polyisocyanate composition comprising at least one or more polyisocyanate compounds, at least one or more trimerization catalyst compounds, at least one or more aldehyde compounds wherein the aldehyde compound is selected from compounds with the structure R&#x2014;CHO wherein CHO is an aldehyde group and R is a hydrocarbyl group selected from an alkyl, alkenyl or aryl having 1-50 carbon atoms, preferably 1-20 carbon atoms, and at least one or more compounds selected from compounds which comprise a carboxamide group having the structure &#x2014;CO&#x2014;NHand/or from compounds which comprise a group having the structure &#x2014;CO&#x2014;NH&#x2014;CO&#x2014;.

Aldehyde comprising compounds suitable for making curable polyisocyanate compositions

Curable composition obtained by combining and mixing an epoxy resin composition, comprising an epoxy resin and a carboxamide, and a polyisocyanate composition, comprising a polyisocyanate, a lithium halide and a urea compound, wherein the number of moles of lithium halide per isocyanate equivalent ranges of from 0.0001-0.04 and the number of urea+biuret equivalents per isocyanate equivalent of from 0.0001-0.4.

Curable polyisocyanate composition comprising an epoxy

The present invention is concerned with a material comprising: a matrix material comprising a plurality of urethane and/or urea and/or isocyanurate groups and having a hardblock content of more than 75% (hereinafter called matrix A); and a polymeric material which 1) has no groups which are able to form a urethane, urea or isocyanurate group with an isocyanate group, 2) exhibits a phase change as measured by differential scanning calorimetry (DSC) in the temperature range &#x2212;10&#xb0; C. to +60&#xb0; C. with an enthalpy &#x394;Hm of at least 87 kJ/kg, 3) is interpenetrating said matrix A, and 4) has an average molecular weight of more than 700 and comprises at least 50% by weight of oxyalkylene groups, based on the weight of this material, wherein at least 85% of the oxyalkylene groups are oxyethylene groups (hereinafter called polymeric material B); and wherein the relative amount of said matrix A and of said polymeric material B, on a weight basis, ranges from 15:85 to 75:25. Process for preparing such material.

Materials comprising a matrix and process for preparing them

The invention provides a cross-linkable mixture of thermoplastic polyurethanes and ethylenic unsaturated compounds and thermoset materials that can obtained therefrom. The invention also provides application of the cross-linkable mixtures and processes in a solvent-less coating process.

Cross-linkable thermoplastic polyurethanes

A stable partly cured polyisocyanate composition is disclosed which comprises polyisocyanurate (intermediate polyisocyanurate comprising material) and which is further curable. Furthermore a process for making the intermediate (partly cured) polyisocyanurate comprising material and a process for further curing the partly cured polyisocyanurate composition is disclosed. Also polyisocyanurate comprising materials made or obtainable from partly cured intermediate polyisocyanurate comprising material are disclosed and processes for further curing a partly cured polyisocyanurate comprising composition (intermediate material).

Intermediate polyisocyanurate comprising materials

Stable polyisocyanate composition comprising a compound comprising a group having the structure &#x2014;CO&#x2014;NH&#x2014;O&#x2014; in such an amount that the ratio of the number of &#x2014;CO&#x2014;NH&#x2014;CO&#x2014; groups to the number of isocyanate groups is at most equal to 1. Curable composition comprising this polyisocyanate composition, lithium halide, urea and an epoxy resin.

Curable polyisocyanate composition

A process for preparing a polyisocyanurate polyurethane material, which process comprises reacting a polyisocyanate and an isocyanate-reactive composition, wherein the reaction is conducted at an isocyanate index of 1600 to 100,000 and in the presence of a trimerization catalyst, wherein the polyisocyanate comprises a) 75-100% by weight of diphenylmethane diisocyanate comprising at least 40%, preferably at least 60% and most preferably at least 85% by weight of 4,4'-diphenylmethane diisocyanate and/or a variant of said diphenylmethane diisocyanate which variant is liquid at 25&#xb0; C. and has an NCO value of at least 20% by weight (polyisocyanate a), and b) 25-0% by weight of another polyisocyanate (polyisocyanate b), the amount of polyisocyanate a) and polyisocyanate b) being calculated on the total amount of this polyisocyanate a) and polyisocyanate b), and wherein the isocyanate-reactive composition comprises a) 80-100% by weight of a polyether polyol having an average nominal functionality of 2-6, an average equivalent weight of 1100-5000 and an oxyethylene (EO) content of 65-100% by weight and b) 20-0% by weight of one or more other isocyanate-reactive compounds, the amount of polyol a) and isocyanate-reactive compound b) being calculated on the total amount of this polyol a) and compound b).

Process for preparing a polyisocyanurate polyurethane material

Elastomeric material having a density of more than 100 kg/mand comprising

Elastomeric materials having a high hardblock content and process for preparing them

Foamed material having a density of less than 100 kg/mand comprising

Foamed materials comprising a matrix having a high highblock content and process for preparing them

Composition obtained by reacting a polyisocyanate which is a diphenylmethane diisocyanate, optionally comprising a homologue comprising 3 or more isocyanate groups, and/or a variant of such diisocyanate with a monoalkylether of a polyoxyalkylene monoamine having an average molecular weight of 550-3000 and an oxyethylene content of more than 50% by weight, calculated on the weight of the monoamine, and the alkyl group having 1-4 carbon atoms at index of 100-250. It is used as plasticizer, particularly in polyurethane and/or polyurea materials.

Composition from a polyisocyanate and a polyether monoamine

Process for preparing a composition by reacting a polyisocyanate, a monoalkoxy polyoxyalkylene monoamine and water. The composition and its use in making cellular products are claimed as well.

Composition made from a diisocyanate and a monoamine and process for preparing it

Process for preparing an elastomeric polyurethane material by reacting a polyisocyanate, a polyol and a monool.

Elastomeric polyurethane material

Process for preparing a flexible polyurethane foam comprising reacting at an isocyanate index of 70 to 130, 1) 40-65 parts by weight of a polyisocyanate composition comprising a) 80-100% by weight of a diphenylmethane diisocyanate component comprising, based on 100 parts by weight of the diphenylmethane diisocyanate component, i) 75-100 parts by weight of diphenylmethane diisocyanate comprising 15-75 parts by weight of 4,4'-diphenylmethane diisocyanate, and 25 to 85 parts by weight of 2,4&#x2032;-diphenylmethane diisocyanate, and 2,2&#x2032;-diphenylmethane diisocyanate and/or a liquid variant of such diphenylmethane diisocyanate, and ii) 0 to 25 parts by weight of homologues of diphenylmethane diisocyanates having an isocyanate functionality of 3 or more; and b) 20-0% by weight of toluene diisocyanate; 2) 20 to 45 parts by weight of a polyether polyol having an average molecular weight of 4500-10000, an average nominal functionality of 2-6 and comprising oxypropylene and optionally oxyethylene groups, the amount of oxypropylene groups being at least 70% by weight calculated on the weight of this polyol; 3) 3 to 20 parts by weight of a polyether polyol having an average molecular weight of 700-4000, an average nominal functionality of 2-6 and an hydroxyl value of at most 225 mg KOH/g and comprising oxyethylene and optionally oxypropylene groups, the amount of oxyethylene groups being at least 70% by weight calculated on the weight of this polyol; and 4) 2-6 parts by weight of water, wherein the amount of the polyisocyanate composition, polyol 2), polyol 3), and water being 100 parts by weight.

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Lubbeek, Belgium

Hans Godelieve Guido Verbeke