Sumitomo Naugatuck Co., Ltd.

Honda Motor Co., Ltd.

Sugitomo Naugatuck Co., Ltd.

Hajime Sakano

Akitoshi Ito

Mikio Kodama

Motoichi Yano

Yasuhiro Honda

Fumio Nakai

Toshihiro Shoji

Miyuki Terada

Isao Yoshida

Yukio Tomari

Takayoshi Fujiwara

Shigemitsu Kawagishi

Yoshitugu Fujimori

Koichi Nakayama

Atsunori Inoue

Yasuo Takabori

A thermoplastic resin composition affording a delustered shaped article which comprises (A) a rubber-modified copolymer with (B) an epoxy group-containing olefin polymer or an unsaturated carboxylic acid-modified olefin polymer (B').

Composition containing rubber-modified graft copolymer and carboxylic

Thermoplastic resin composition

A thermoplastic resin composition excellent in impact resistance and moldability and improved in falling ball impact strength at a weld part which comprises (A) a polycarbonate resin having a reduced viscosity at 25.degree. C. in chloroform of 0.40 to 0.55 and (B) a diene-rubber modified resin comprising 10 to 100% by weight of a graft polymer of a diene rubber chosen from polybutadiene, styrene/butadiene copolymer and butadiene-acrylonitrile copolymer, with an aromatic vinyl compound and at least one of a vinyl cyanide and an alkyl unsaturated carboxylate grafted thereon and 90 to 0% by weight of a copolymer of an aromatic vinyl compound with at least one of a vinyl cyanide and an alkyl unsaturated carboxylate. The diene-rubber modified resin has apparent melt viscosities at 250.degree. C. of 5.times.10.sup.3 to 1.times.10.sup.5 poise at a shear rate of 10.sup.2 sec.sup.-1 and of 1.5.times.10.sup.3 to 1.times.10.sup.4 poise at a shear rate of 10.sup.3 sec.sup.-1, the weight proportion of the components (A) and (B) being from 20:80 to 80:20.

A thermoplastic resin composition improved in weld strength which comprises (A) a polycarbonate resin and (B) a rubber modified copolymer with (C) an epoxy group-containing olefin copolymer.

A thermoplastic composition which comprises a blend comprising 20 to 80% by weight of a polycarbonate resin and 80 to 20% by weight of a graft polymer obtained by grafting at least one aromatic vinyl compound and at least one of vinyl cyanides and alkyl unsaturated carboxylates onto a conjugated diene rubber or its mixture with a copolymer of at least one aromatic vinyl compound and at least one of vinyl cyanides and alky unsaturated carboxylates in an amount of not more than 90% by weight on the basis of the combined amount of the graft polymer and the copolymer, and a polyolefin or a plasticizer having a light transmission of not less than 70% when determined on the film of 20 microns in thickness prepared by the use of a solution of the plasticizer (0.25 g) and acrylonitrile-styrene copolymer (weight ratio of acrylonitrile and styrene, 30:70; 0.75 g) in acetone (10 ml), the weight proportion of the blend and the polyolefin or the plasticizer being 100:0.2-20. The resulting composition is excellent in solvent resistance, welding strength, impact resistance, molding property, etc.

Thermoplastic composition

A thermoplastic resin composition with excellent color development which comprises (A) a graft polymer comprising an ethylene-propylene elastomeric polymer and units of at least two kinds of monomers chosen from aromatic vinyl compounds, vinyl cyanide compounds and other copolymerizable monomers grafted thereon, and if necessary, (A') a copolymer comprising units of at least two kinds of monomers chosen from aromatic vinyl compounds, vinyl cyanide compounds and other copolymerizable monomers in an amount of not more than 95% by weight based on the combined weight of the graft polymer (A) and the copolymer (A'), with (B) a methyl methacrylate polymer, the proportion of the combined weight of the graft polymer (A) and the copolymer (A') and the weight of the methyl methacrylate polymer being from 5:95 to 95:5.

Thermoplastic resin composition excellent in color development

An elastomeric composition having excellent properties such as excellent heat aging characteristics, dimensional stability, processability, fabrication qualities, hydrolytic resistance, yellowing resistance, and weatherability, which comprises

Elastomeric composition

A thermoplastic resin composition excellent in solvent resistance, paintability and moldability which comprises a polycarbonate resin and a conjugated diene rubber copolymer comprising units of a conjugated diene rubber, an aromatic vinyl compound and at least one of vinyl cyanide compounds and optionally hydroxylated alkyl esters of unsaturated carboxylic acids in a weight proportion of 20:80 to 80:20 with a polyamide resin in an amount of 0.1 to 20 parts by weight on the basis of 100 parts by weight of the combined weight of the polycarbonate resin and the conjugated diene rubber copolymer.

Thermoplastic composition containing polycarbonate, polyamide and

A thermoplastic resin composition excellent in heat cycle property which comprises 100 parts by weight of a polycarbonate resin blended or not with an ABS type resin in an amount of not more than 95% by weight based on the combined weight of the polycarbonate resin and the ABS type resin and 0.05 to 3.0 parts by weight of an organo-silicon compound.

Thermoplastic resin composition having good heat cycle property

A thermoplastic resin composition with excellent dwelling thermal stability which comprises 100 parts by weight of a resin composition comprising a polymer (A) obtained by polymerization of at least two kinds of monomers selected from the group consisting of aromatic vinyl compounds, vinyl cyanide compounds and carboxylic acid alkyl esters in the presence of a conjugated diene rubber and a polycarbonate resin (B) in a weight proportion of from 10:90 to 90:10 and 0.05 to 5.0 parts by weight of at least one acid compound (C) chosen from inorganic acids, organic acids and organic acid anhydrides.

Thermoplastic resin composition excellent in dwelling thermal stability

A thermoplastic resin composition excellent in coating property which comprises (A) at least one of polyamide resins and polyacetal resins, (B) at least one of aromatic monovinyl compound/vinyl cyanide copolymers comprising units of aromatic monovinyl compounds and units of vinyl cyanides in a weight ratio of 60:40 to 80:20 and having an intrinsic viscosity of 0.3 to 1.1 and (C) at least one of conjugated diene rubber/vinyl cyanide graft copolymers comprising units of conjugated diene rubbers in an amount of 5 to 45% by weight based on the weight of the graft copolymers in a weight proportion of the components (A), (B) and (C) being 0.1-10: 5-90: 5-94.9.

A foamed urethane composites comprising foaming urethane and a covering material and having excellent in thermal aging-resistance, which is obtained by applying to the covering material surface to be contacted with the foamed urethane (A) an organic solvent solution or aqueous emulsion comprising (A-1) at least one of flexible urethane resins, starting materials for preparation of flexible urethane resins and vinyl chloride resins, further applying thereto (B) an organic solvent solution comprising (B-1) a copolymer of a carboxyl group-containing ethylenically unsaturated monomer(s) with an acrylic and/or methacrylic acid ester(s) and (B-2) at least one of blocked isocyanate compounds, poly-N-alkoxymethylmelamine compounds, polyepoxy compounds, polyoxazoline compounds, polydihydrooxazine compounds and reactive polyamide compounds, and then subjecting the coated product to crosslinking under heating.

Foamed urethane composite

A thermoplastic resin composition having a good heat cycle property which comprises (A) a graft polymer comprising a conjugated diene rubber and an aromatic vinyl compound and a vinylic cyanide grafted thereon in a weight proportion of 5-80:15-140, the weight ratio of the aromatic vinyl compound and the vinylic cyanide being 10-90:5-50, (B) a copolymer comprising an aromatic vinyl compound and a vinylic cyanide in a weight ratio of 40:60 to 90:10 and (C) an organo-silicon compound, the weight proportion of the graft polymer (A) and the copolymer (B) being from 5:95 to 95:5 and the amount of the organo-silicon compound (C) being from 0.05 to 3.0 parts by weight to 100 parts by weight of the combined amount of graft polymer (A) and the copolymer (B).

A method for preparation of a plated product which comprises electroplating a molded product of a resin composition comprising at least one kind of thermoplastic resin and carbon black having an oil absorption amount of not less than 200 ml/100 g and a surface area of not less than 500 m.sup.2 /g in a weight proportion of 100:3-100 and having an intrinsic volume resistivity of not more than 10.sup.3 .OMEGA..cm without previous electroless plating.

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Hirakata, Japan

Hajime Sakano