Nippon Oil Company

Nippon Mitsubishi Oil Corporation

Other

Nippon Petroleum Refining Company, Limited

Research Association for Petroleum Alternative Development

Hajime Okazaki

Masaru Ushio

Michiaki Adachi

Toshio Waku

Hisao Sakoda

Shigeo Kure

Kozo Kamiya

Takeshi Ishii

Katuhiko Ishikawa

Kazuya Nasuno

Katsuhiko Ishikawa

Haruki Nagano

Masaoki Ouchi

Manabu Kazato

Takashi Shoda

An object is to provide a reactor for hydrotreating which exhibits a total desulfurizing activity higher than that of the reactor according to the prior art, and which is reduced in the rate of lowering of the desulfurizing activity and therefore can keep the high desulfurizing activity over a long period, and to provide a process by the use of the reactor. A reactor for hydrotreating, which comprises at least four catalyst layers packed respectively with hydrotreating catalysts satisfying the relationship represented by the following formulae: S &lE;S , 1.15V &gE;V wherein S represents the surface area per cubic meter of each hydrotreating catalyst; V represents the pore volume per cubic meter of catalyst; and wherein n is a natural number representing the order of each catalyst layer.

Reactor for hydrotreating and process for producing ultralow sulfur heavy oils by the use of the reactor

Gas oils comprises one or more gas oil bases obtained by subjecting specific fractions from distilled petroleum fractions to hydrogenating treatment under specific conditions and optionally a small amount of a straight kerosene or gas oil. The gas oils have a sulfur concentration of 350 ppm or below.

Low sulfur gas oil

A manufacturing process of a diesel gas oil with a high cetane number and a low sulfur, where the cetane number thereof is at least 45, the sulfur content thereof is less than 350 ppm, and the storage stability is superior, from a petroleum distillate oil with a low cetane number and a high sulfur content is provided. The process includes a first stage of contacting hydrogen with a petroleum distillate oil with a particular low cetane number, a particular high sulfur content, and a particular boiling point, in the presence of a catalyst of a porous solid acid carrier carrying a particular hydrogenation-active metals at a particular temperature and pressure to obtain a hydrogenated oil with a cetane number of at least 45 and a sulfur content of less than 350 ppm; and a second stage of contacting the obtained hydrogenated oil with hydrogen in the presence of a catalyst of a porous carrier carrying a hydrogenation-active metal at a particular temperature and pressure to obtain a hydrogenated oil with a superior storage stability without changing the cetane number and the sulfur content.

Manufacturing process of diesel gas oil with high cetane number and low sulfur

A hydrocracking catalyst for hydrocarbon oil, comprising a complex oxide with at least 2 different elements selected from Group 3b, Group 4a, Group 4b and Group 5b of the Periodic Table, zeolite having a solid Al-NMR spectrum wherein the ratio A/B of the peak area A in a chemical shift of -30 to 18 ppm to the peak area B in a chemical shift of 20-100 ppm is 0.01-0.39 and whose surface area of pores of diameter 10 angstrom or smaller constitutes 10-85% of the total surface area, and at least one metal selected from Group 6a and Group 8 of the Periodic Table. Also, a hydrocracking method characterized by hydrocracking of petroleum distillates with a boiling point of 250-600.degree. C. using the hydrocracking catalyst in the presence of hydrogen, under conditions with a reaction temperature of 100-800.degree. C., a reaction pressure of 3-30 MPa, an LHSV of 0.01-10 h.sup.-1 and a hydrogen/oil ratio of 100-2500 Nm.sup.3 /m.sup.3.

Hydrocracking catalyst and hydrocracking method for hydrocarbon oils

Supply system of petroleum heavy oil containing magnetic fine particles

The present invention is directed to a method for dewaxing hydrocarbon oil which is characterized by bringing the hydrocarbon oil into contact with a catalyst which is prepared by mixing specific crystalline aluminosilicate, defined in claim 1, having an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio between 12 and less than 70 with at least one solid fluorine compound selected from aluminum fluoride, ammonium fluoride, zinc fluoride, cadmium fluoride, manganese fluoride, chromium fluoride, tin fluoride, copper fluoride and silver fluoride; molding the resulting mixture into an optional shape; and calcining the molded mixture at a temperature of 100.degree. to 700.degree. C. for a time of 0.5 hour or more.

Method for dewaxing hydrocarbon oil employing crystalline

Hydrocracking catalysts are disclosed which comprise specified amounts of selected inorganic oxides and specified amounts of selected metal components carried thereon. The carrier is essentially derived from solid-phase modification with specified amounts of a selected class of fluorine compounds. Mineral oils are selectively processable with high catalytic activity and at maximum yield.

Hydrocracking catalysts

Provided is a process for producing gasoline having a high octane number or aromatic hydrocarbons by contacting a feed stock containing at least one aliphatic hydrocarbon having 1 to 12 carbon atoms with a catalyst at an elevated temperature said catalyst comprising a zeolite and a fluorine compound, and optionally Group Ib, IIb, IIIa, VI, VIIb or VIII metal in the Periodic Table.

Hydrocarbon conversion process

A method of producing a metallic-tone coating on a metal substrate, wherein the main paint contains not greater than 40% by weight of solvent plus metal scales of regular shape and size having no shape corner edges, and wherein the viscosity of the paint is adjusted to 10 sec to 30 sec Ford Cup Test at 25.degree. C.

Growing community of inventors

Yokohama, Japan

Hajime Okazaki