Gm Global Technolgoy Operations, Inc.

Alcatel Lucent

Haijing Liu

Xiaochao Que

Dewen Kong

Meiyuan Wu

Zhe Li

Zhiqiang Yu

Qili Su

Dave G Rich

Mengyan Hou

Mark William Verbrugge

Yong Qing Lu

Si Ruo Chen

Jingyuan Liu

Yong Lu

Lyall Kenneth Winger

Saad Hasan

Sherman H Zeng

Qiang Wu

Michael P Balogh

Jianfeng Wang

Jingjing Wu

Peng Lu

Jianyong Liu

Xiusheng Zhang

Wentian Gu

Li Sun

Xiaosong Huang

Ion C Halalay

He Wang

Jeffrey A Abell

Xiaohong Gayden

Teresa J Rinker

Wu Tao

Daad B Haddad

Aaron B Bloom

Ming Wang

Yiming Sun

Jeffrey Wyka

Lianqi Zhang

Honggu Pan

A manufacturing system for an electrode of a battery cell includes a conveyor belt configured to receive a fiberized powder mixture including an active material, a conductive additive, and a binder. A powder dispensing stage is arranged adjacent to the conveyor belt and configured to dispense the fiberized powder mixture. A pre-forming stage is arranged adjacent to the conveyor belt and configured to receive the fiberized powder mixture dispensed by the powder dispensing stage and to press the fiberized powder mixture into a raw active material layer. N calendaring rollers configured to receive the raw active material layer from the conveyor belt and to calendar the raw active material layer to form an active material layer, where N is an integer greater than one. A pair of laminating rollers is configured to laminate the active material layer to a current collector to form an electrode.

Continuous, solvent-free fabrication of electrodes using dry powder

The present disclosure provides a positive electroactive material for an electrochemical cell that cycles lithium ions. The positive electroactive material includes a nickel-rich material including a plurality of solid-state particles. Each solid-state particle has a heterogeneous structure that includes a core and a shell that at least partially coats the core. The core includes a nickel-cobalt-manganese material, and the shell includes a nickel-cobalt-aluminum material. When the nickel-rich material is represented by LiNiCoMnAlO, the nickel-cobalt-manganese material is represented by LiNiCoMnO, and the nickel-cobalt-aluminum material is represented by LiNiCoAlO, where (i) 1-x-y-z>0.5, (ii) a+b=1, (iii) zx″+bx″=x, and (iv) 1-x″-(y/a)>1-x″-(z/b). In certain variations, the core and the shell define a base structure, and the heterogeneous structure further includes a buffer layer that at least partially coats the base structure.

Positive electroactive materials for all-solid-state battery

In various aspects, the present disclosure provides solvent-free methods of making a solid-state electrode active layer for a solid-state electrode in an electrochemical cell that cycles lithium ions, by using a plurality of solid polymeric binder particles capable of fibrillation with porous fibrillation particles with a first shear force to at least partially fibrillate the solid polymeric binder particles to form a polymeric binder mixture. The disclosure also contemplates a current collector and a porous active layer disposed thereon. The porous active layer includes a fibrous polymeric network having a plurality of solid particles distributed therein. The solid particles may include electroactive material particles, solid-state electrolyte particles, and porous fibrillation particles.

Solvent-free methods of forming solid-state electrodes having polymeric fiber networks by using fibrillation processing additives and solid-state electrodes made therefrom

A battery system comprises N folded bipolar batteries folded in an 'S'-shaped configuration. First and second folded portions of each of the N folded bipolar batteries are arranged on opposite ends of the “S”-shaped configuration. First side portions and second side portions of each of the N folded bipolar batteries are arranged between the first and second folded portions. One or more of the first folded portions on a first one of the N folded bipolar batteries are in direct electrical contact with one or more of the second folded portions on a second one of the N folded bipolar batteries. One or more of the first side portions on a third one of the N folded bipolar batteries are in direct electrical contact with one or more of the second side portions on a fourth one of the N folded bipolar batteries.

High voltage battery including tab-free and weld-free folded bipolar solid-state batteries

A capacitor assisted battery module includes a first diode including an anode and a cathode. A second diode includes an anode and a cathode. The anode of the first diode is connected to the cathode of the second diode at a first node. A first capacitor assisted battery (CAB) block includes a positive terminal, a negative terminal and N CABs, where N is an integer greater than zero. The positive terminal of the first CAB block is connected to the cathode of the first diode. A second capacitor assisted battery (CAB) block includes a positive terminal, a negative terminal and N CABs, wherein the negative terminal of the second CAB block is connected to the anode of the second diode. The negative terminal of the first CAB block and the positive terminal of the second CAB block are connected to a second node.

Battery system including alternating current, fast-chargeable capacitor assisted batteries

A high-power gel-assisted battery stack that cycles lithium ions is provided with two terminal electrodes having opposite polarities and at least one bipolar electrode assembly disposed therebetween. A first electrode is disposed on a first side of a bipolar current collector and a second electrode with an opposite polarity to the first electrode is disposed on a second side of the bipolar current collector. Each electrode includes a porous layer having an electroactive material and a solid-state electrolyte disposed in a polymeric binder. A polymer gel electrolyte is distributed in pores of the porous. The stack also includes at least two free-standing gel separator layers each being disposed between the at least one bipolar electrode assembly and terminal electrodes. Each respective free-standing gel separator layer comprises polyacrylonitrile (PAN) and an electrolyte distributed therein. The high-power gel-assisted battery stack has a maximum voltage rating of ≥about 12V.

Designs of high-power gel-assisted bipolar solid-state battery

The present disclosure provides an electrode for an electrochemical cell. The electrode includes a polymer binder network and a plurality of electroactive material particles. The polymer binder network includes a plurality of fibers defining the polymer binder network. Each of the plurality of fibers includes a plurality of beads and a plurality of filaments. The plurality of filaments extends from at least a portion of the plurality of beads, respectively. The plurality of electroactive material particles is in voids of the polymer binder network. In certain aspects, the present disclosure provides a single- or double-sided electrode component including a current collector and the electrode.

Electrodes including polymer binder networks with bamboo-type fibers

A method for forming a solid-state battery includes stacking two or more cell units, where each cell unit is formed by substantially aligning a first electrode and a second electrode, the first electrode including one or more first electroactive material layers disposed on or adjacent to one or more surfaces of a releasable substrate and the second electrode including one or more second electroactive material layers disposed on or adjacent to one or more surfaces of a current collector. The method may further include disposing an electrolyte layer between exposed surfaces of the first electrode and the second electrode and removing the releasable substrate to form the cell unit.

Methods of manufacturing bipolar solid-state batteries

A pouch-type, capacitor-assisted battery cell includes: N negative electrodes, where N is an integer greater than one, each of the N negative electrodes includes a first current collector, first particulate electrode material, and a first tab; P positive electrodes, where: P-M ones of the P positive electrodes include a second current collector, second particulate electrode material, and a second tab, M ones of the P positive electrodes include a third current collector, third particulate electrode material including activated carbon (AC) arranged on opposite sides of the third current collector, and a third tab, and P=N−1 and M=2; separators arranged between the N negative electrodes and the P positive electrodes; and a pouch enclosure surrounding the N negative electrodes, the P positive electrodes and the separators; where the M ones of the P positive electrodes are located approximately equidistant from a center of the P positive electrodes.

Capacitor-assisted battery cell

An electrochemical cell that cycles lithium ions is provided. The electrochemical cell includes a first electrode, a second electrode, and an electrolyte layer disposed between the first electrode and the second electrode. The first electrode includes a first plurality of solid-state electroactive material particles and a first polymeric gel electrolyte, where the first polymeric gel electrolyte includes a first additive. The second electrode includes a second plurality of solid-state electroactive material particles and a second polymeric gel electrolyte that is different from the first polymeric gel electrolyte, where the second polymeric gel electrolyte includes a second additive. The electrolyte layers include a third polymeric gel electrolyte that is different from both the first polymeric gel electrolyte and the second polymeric gel electrolyte.

Gel electrolyte system for solid state battery

Lithium-based and sodium-based batteries and capacitors using metal foil current collectors, coated with porous layers of particles of active electrode materials for producing an electric current, may be adapted to produce heat for enhancing output when the cells are required to periodically operate during low ambient temperatures. A self-heating cell may be placed in heat transfer contact with a working cell that is temporarily in a cold environment. One or both of the anode current collector and cathode current collector of a heating cell may be formed with shaped extended portions, uncoated with electrode materials, through which cell current may be passed for resistance heating of the extended current collector areas. These extended current collector areas may be used to heat the working area of the cell in which they are incorporated, or to contact and heat an adjacent working cell.

Self-heating battery

The present disclosure provides a solid-state battery including at least one current collector that is in communication with one or more switches configured to move between open and closed positions, where the open position corresponds to a first operational state of the solid-state battery and the closed position corresponds to a second operational state of the solid-state battery; one or more electrodes disposed adjacent to the one or more current collectors; and one or more electrothermal material foils including a resistor material that is in electrical communication with that at least one current collector, where in the first operational state electrons may flow through the one or more electrothermal material foils during cycling of the solid-state battery so as to initiate a heating mode, and in the second operational state electrons may flow through the current collector during cycling of the solid-state battery so as to initiate a non-heating mode.

Self-heating bipolar solid-state battery

A negative electrode for an electrochemical cell that cycles lithium ions includes a particulate component embedded in a polymeric matrix component that comprises polytetrafluoroethylene. The particulate component includes a plurality of composite particles, with each of the composite particles having a core and a selective barrier layer disposed on a surface of the core. The core of each of the composite particles includes an electroactive negative electrode material. The selective barrier layer of each of the composite particles is formulated to prevent or inhibit electrochemical reactions from occurring between lithium stored in the electroactive negative electrode material of the core and the polytetrafluoroethylene in the polymeric matrix component.

Composite negative electrode materials and electrochemical cells including the same

A method for forming a bipolar solid-state battery includes preparing a mixture of gel precursor solution and solid electrolyte. The gel precursor includes a polymer, a first solvent, and a liquid electrolyte. The liquid electrolyte includes a second solvent, a lithium salt, and electrolyte additive. The method includes loading the mixture onto at least one of a first electrode, a second electrode, and a third electrode. Each of the first, second, and third electrodes includes a plurality of solid-state electroactive particles. The method includes removing at least a portion of the first solvent from the mixture to form a gel and positioning one of the first, second, and third electrodes with respect to another of the first, second, and third electrodes. The method includes applying a polymer blocker to a border of the first, second, or third electrodes.

In-situ gelation method to make a bipolar solid-state battery

An active material component of a composition for forming an electrode of a battery in a dry process is provided. The active material component includes a dry powder including a plurality of grains of an active material. The active material component further includes an electrically conductive filler material attached to each of the plurality of grains.

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Shanghai, China

Haijing Liu