Sk on Co., Ltd.

Sk Innovation Co., Ltd.

Hae Suk Hwang

Hee Gyoung Kang

So Hyun Park

Chan Young Jeon

Jong Hyuk Lee

Hyo Sang Kim

Min Gu Kang

Soo Ho Kim

Sang Jin Kim

Kwang Ho Jeong

Sang Han Lee

Jae Phil Cho

Hyo Mi Kim

Da Bin Chung

Mi Ryeong Lee

Gi Hyeon Moon

Min Ki Jo

An anode active material for a lithium secondary battery according to an embodiment of the present invention includes a first anode active material and a second anode active material, each of which includes a carbon-based active material and has a crystallite size in a range from 50 nm to 60 nm. An XRD orientation ratio of the first anode active material is in a range from 0.9 to 1.2, and an XRD orientation ratio of the second anode active material is in a range from 1 to 5. High-temperature storage and life-span properties are improved while maintaining high capacity using the combination of the first and second anode active materials.

Anode active material for lithium secondary battery and lithium secondary battery including the same

The lithium secondary battery includes a cathode which includes a cathode active material layer including a cathode current collector, a cathode tab protruding from one end thereof in a longitudinal direction of the cathode current collector, a second cathode portion disposed spaced apart from the cathode tab on the cathode current collector, and a first cathode portion disposed adjacent to the cathode tab on the cathode current collector and having an electrode density higher than that of the second cathode portion, and an anode disposed to face the cathode. Life-span characteristics of the lithium secondary battery may be improved by controlling the electrode density in the peripheral part of the cathode tab.

Lithium secondary battery

An anode for a lithium secondary battery according to exemplary embodiments may include an anode current collector and an active material layer formed on at least one surface of the anode current collector and having a value of pore resistance to density within a predetermined range. Accordingly, it is possible to secure both high-capacity characteristics and high speed charging stability, thus to further improve capacity and efficiency of the lithium secondary battery.

Anode for lithium secondary battery and lithium secondary battery including the same

Provided is a negative electrode for a secondary battery including: a current collector, and a negative electrode active material layer formed on the current collector and containing a first negative electrode active material having a large particle size and a second negative electrode active material having a small particle size, wherein the second negative electrode active material is contained in an amount of 10% by weight or less based on the total weight of the negative electrode active material, and the following Relational Equation 1 is satisfied: [Relational Equation 1] 0.4<D2/D1<0.7; wherein D1 and D2 are the particle sizes (D50, μm) of the first and second negative electrode active materials, respectively.

Negative electrode for secondary battery, and secondary battery including same

Provided is a negative electrode for a secondary battery including: a current collector; and a negative electrode active material layer including a negative electrode active material, formed on the current collector, with the negative electrode satisfying Relation 1:3.0<τ*<7.2   [Relation 1] with τ a tortuosity of the negative electrode, and Da pellet density (g/cm) of the negative electrode active material, measured by pressing the negative electrode active material at 8 kN/cm. Also provided is a secondary battery including the same.

Negative electrode for secondary battery and secondary battery including the same

An anode for a lithium secondary battery includes an anode current collector, and an anode active material layer formed on the anode current collector. The anode active material layer including a lower anode active material layer formed on the anode current collector and an upper anode active material layer formed on the lower anode active material layer. Each of the lower anode active material layer and the upper anode active material layer includes a first anode active material and a second anode active material having a hardness less than that of the first anode active material. A total intrusion amount of mercury to pores having a diameter of 3 nm to 10 μm in the anode active material layer measured by a mercury porosimeter is 0.27 ml/g or more.

An anode for a lithium secondary battery includes an anode current collector, and an anode active material layer disposed on the anode current collector. The anode active material layer includes a first anode active material layer including a first anode active material and a first binder that includes an acrylate-styrene butadiene copolymer, and a second anode active material layer disposed on the first anode material layer, the second anode active material layer including a second anode active material and a second binder that includes an acrylate-styrene-butadiene copolymer. A peak intensity ratio according to Raman spectroscopy of the first anode active material is smaller than the peak intensity ratio according to Raman spectroscopy of the second anode active material, and the peak intensity ratio according to Raman spectroscopy is represented as I/I.

Anode including material layers with different I/Iratios, lithium secondary battery including the same

An anode active material according to an embodiment of the present invention includes a first graphite particle and a second graphite particle having a different particle diameter from that of the first graphite particle. A ratio of a pellet density relative to a. tap density of the anode active material is from 1.3 to 1.45. A particle deformation of the anode is suppressed to achieve a lithium secondary battery having improved long-term and high-energy properties.

Anode active material and lithium secondary battery including the same

An anode for lithium secondary battery includes a current collector and an anode active material layer including an anode active material and being formed on the current collector. The anode active material includes a core containing an artificial graphite and a shell formed on a surface of the core, the shell containing an amorphous carbon. An average of a Raman R value of the anode active material layer is in a range from 0.5 to 0.65, and a standard deviation of the Raman R value is less than 0.22. The Raman R value is defined as a ratio (I/I) of a D band intensity (I) relative to a G band intensity (I), and the D band and the G band are obtained from a Raman spectrum of the anode active material layer.

Provided is a metal oxide for a cathode active material of a lithium secondary battery capable of having improved structural and thermal stability, high efficiency, high capacity, and excellent cycle property and life span property, the metal oxide represented by the following Chemical Formula 1:LiNiCoMO&#x2003;&#x2003;[Chemical Formula 1]

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Daejeon, South Korea

Hae Suk Hwang