Rohm and Haas Company

Colgate Palmolive Company

H Scott Killam

Kuo-Yann Lai

Jean Dupre

Robert C Pierce

A foaming light duty aqueous liquid detergent composition especially useful for hand dishwashing containing 5 to 50 wt. % of non-cationic detergent active material, optional foam boosters and hydrotropes, and 0.1 to 10 wt. % of a cationic foam-stabilizing copolymer containing a major weight proportion of units derived from acrylamide and/or methacrylamide, about 0.5 to 2 wt. % of quaternary nitrogen as present in quaternary ammonium groups, and about 0.1 to 10 wt. % of pendant C.sub.8-24 hydrophobic, preferably alkyl groups. Said quaternary ammonium group-containing monomer has the formula ##STR1## wherein R.sub.1 is H or CH.sub.3, R.sub.2 and R.sub.3 are independently C.sub.1-4 alkyls,

Liquid detergent composition with a cationic foam stabilizing copolymer

An effective amount of a vinylbenzyltrialkylammonium salt, prepared from a vinylbenzyl halide and a tertiary amine, is polymerized with various other monomers to afford stable latex polymers which have the latex stabilizing surfactant incorporated into the polymer backbone. The use of a vinylbenzyltrialkylammonium salt lessens or avoids the usual problems associated with the conventional anionic, nonionic or cationic emulsifiers employed in aqueous polymerizations. The copolymers prepared with the quaternary ammonium compounds are useful as sizing agents, as extender/binders for cationic water repellents; in addition, the polymers are depositable on pulp without requiring any deposition aids or defoamers.

Fibrous material made with polymers stabilized by polymerizable vinyl

A non-ionic copolymer composed of (in weight percent) 5 to 30% N-vinyl pyrrolidone, 15 to 60% acrylamide, and 30 to 70% methyl methacrylate is disclosed. The copolymer is added in minor amount to paper pulp, especially pulp containing black liquor contamination, to improve the paper making operation and the dry strength of the paper.

Non-ionic, water-soluble polymers for improving the dry-strength of paper

An effective amount of a vinylbenzyltrialkyl ammonium salt, prepared from a vinylbenzyl halide and a tertiary amine, is polymerized with various other monomers to afford stable latex polymers which have the latex stabilizing surfactant incorporated into the polymer backbone. The use of a vinylbenzyltrialkyl ammonium salt lessens or avoids the usual problems associated with the conventional anionic, nonionic or cationic emulsifiers employed in aqueous polymerizations, that is, the latex stabilizing surfactant incorporated into the polymer backbone is the sole emulsifier. The copolymers prepared with the quaternary ammonium compounds are useful as sizing agents, as extender/binders for cationic water repellents; in addition, the polymers are depositable on pulp without requiring any deposition aids or defoamers.

Method of treating fibrous materials with polymers stabilized with

An effective amount of a vinylbenzyltrialkylammonium salt, prepared from a vinylbenzyl halide and a tertiary amine, is polymerized with various other monomers to afford stable latex polymers which have the latex stabilizing surfactant incorporated into the polymer backbone. The use of a vinylbenzyltrialkylammonium salt lessens or avoids the usual problems associated with the conventional anionic, nonionic or cationic emulsifiers employed in aqueous polymerizations; that is, the latex stabilizing surfactant incorporated into the polymer backbone is the sole emulsifier employed. The copolymers prepared with the quaternary ammonium compounds are useful as sizing agents, as extender/binders for cationic water repellents; in addition, the polymers are depositable on pulp without requiring any deposition aids or defoamers.

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Holland, PA, United States of America

H Scott Killam