The Penn State Research Foundation

H L Lu

T C Chung

Functionalized copolymers of .alpha.-olefin and para-alkylstyrene having the formula: ##STR1## in which in which R, R' and R', independently, are hydrogen or primary or secondary alkyl groups; X comprises a functional group, such as --COOH, --OH, --SH, --NH.sub.2, --Cl, --Br, --M, --COOM (M=metals, e.g. Li, Na, K and Ca) and anhydrides; P comprises a polymer having the molecular weight of at least about 500, which can be derived from both step and chain polymerization reactions; Y is a chemical linkage between polymer P and para-alkystyrene side chain, which is also a residue derived from graft reaction; and the combination of a+b+c+d represents the empirical formula of a substantially random functional polymer, where a ranges from about 50 to about 100,000, b, c and d range from 0 to about 10,000, and the sum of c+d is at least 1, and processes for preparing the funcitonalized copolymers are disclosed.

Functionalized .alpha.-olefin/para-alkylstryne copolymers

Copolymers comprising poly(.alpha.-olefin) having at least few p-alkylstyrene (para-alkylstyrene) groups or/and p-alkylstyrene derivatives within the structure therein, said polymer having monomer units represented by the structural formula: ##STR1## in which R, R' and R' are, independently, either hydrogen, alkyl, or primary or secondary alkyls. Preferably, R is hydrogen and C.sub.1 to C.sub.10 linear and branched alkyl, and most preferably R is hydrogen, C.sub.1 and C.sub.2. R' and R' are hydrogen, C.sub.1 to C.sub.5 alkyl, or C.sub.1 to C.sub.5 primary or secondary alkyl, and most preferably R' and R' are hydrogen. F comprises a hydrogen or a functional group, such as --COOH, --OH, --NH.sub.2, --Cl, --Br, --M, --COOM (M=metals, e.g. Li, Na, K and Ca) etc., or a mixture of functional group and hydrogen. In the copolymer composition, the .alpha.-olefin mole % (m) is between about 5 and 99.9. Preferably, m is between 85 and 99.9, and most preferably m is between 95 and 99.9. The sum of m and n (mole % of p-alkylstyrene) is 100. The copolymer having a number average molecular weight (Mn) of at least about 1,000, and preferably at least about 10,000. The copolymers also preferably have a ratio of weight average molecular weight (Mw) to number average molecular weight, or Mw/Mn of less than about 8, more preferably less than about 4, most preferably less than about 2.5. Also disclosed are polymerization process, involving transition metal catalysts (especially metallocene compounds with constrained ligand geometry) for producing .alpha.-olefin/p-alkylstyrene copolymers, and subsequently derivatization processes for producing functionalized copolymers of .alpha.-olefin and p-alkylstyrene by the functionalization of benzylic protons in p-alkylstyrene units of copolymer.

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State College, PA, United States of America

H L Lu