Conoco Inc.

Conocophillips Company

Pyrotek Incorporated

H Ernest Romine

John A Rodgers

James R McConaghy

Mark W Carel

Edward J Nanni

W Mark Southard

Zhenhua Mao

Walter M Kalback

Xavier M Bourrat

Andrea K Zimmerman

Lorita Davis

A process for the production of coated carbonaceous particles including: providing a carbon-residue-forming material; providing particles of a carbonaceous material; mixing the carbon-residue-forming material and the particles of a carbonaceous material at an elevated temperature; depositing a coating of the carbon-residue-forming material onto the surface of the particles; and stabilizing the coated particles by subjecting the particles to an oxidation reaction. These coated carbonaceous particles are particularly useful in the manufacture of electrodes in electrical storage cells, particularly in rechargeable electrical storage cells.

Coated carbonaceous particles particularly useful as electrode materials in electrical storage cells, and method of making the same

A process for the production of coated carbonaceous particles including: providing a carbon residue forming material; providing particles of a carbonaceous material; mixing the carbon residue forming material and the particles of a carbonaceous material at an elevated temperature; depositing a coating of the carbon residue forming material onto the surface of the particles; and stabilizing the coated particles by subjecting the particles to an oxidation reaction. These coated carbonaceous particles are particularly useful in the manufacture of electrodes in electrical storage cells, particularly in rechargeable electrical storage cells.

Coated carbonaceous particles particulary useful as electrode materials in electrical storage cells, and methods of making the same

A solvating component for a solvated mesophase pitch. The solvated component includes a mixture of aromatic hydrocarbons having boiling points in the atmospheric equivalent boiling point range of about 285&deg; to about 500&deg; C. (about 550&deg; F.-932&deg; F.). At least 80% of the carbon atoms of the hydrocarbons are aromatic as characterized by carbon 13 NMR. The aromatic hydrocarbons are selected from a group consisting of aromatic compounds having 2 to 5 aromatic rings, substituted aromatic compounds having 2 to 5 aromatic rings wherein said substituents are alkyl groups having 1 to 3 carbons, hydroaromatic compounds having 2 to 5 rings, substituted aromatic compounds having 2 to 5 rings wherein said substituents are alkyl groups having 1 to 3 carbons, and mixtures thereof.

Solvating component and solvent system for mesophase pitch

The present invention provides a process for thermosetting pitch fibers in reduced times, at low concentrations of oxygen and at higher temperatures than previously possible. Additionally, the present invention provides a pitch fiber which has an oxygen diffusion rate to the center of the fiber which is competitive with the rate of oxidation at the fiber's surface. Further, the present invention provides a high density pitch fiber batt which thermosets without loss of fiber structure.

High temperature, low oxidation stabilization of pitch fibers

Organometallic containing mesophase pitches for spinning into pitch carbon fibers

An improved process is disclosed for producing a unique metals-containing anisotropic pitch suitable for carbon fiber manufacture. Soluble, aromatic-organometallic compounds are added to a carbonaceous feedstock which is substantially free of mesophase pitch and the resulting composition is heat soaked to produce an isotropic pitch product containing mesogens and soluble, aromatic-organometallic compounds. Next, the pitch product is solvent fractionated to separate mesogens which contain metals from the organometallic compounds. The metals-containing mesogens are heated to a temperature sufficient to cause fusion to produce a metals-containing mesophase pitch. In another method, the carbonaceous feedstock is heat soaked to produce an isotropic pitch product containing mesogens and high molecular weight, soluble, aromatic-organometallic compounds are added to the mesogen containing isotropic pitch product prior to solvent fractionation. Metals-containing carbon fibers produced from the mesophase pitch exhibit enhanced stabilization, tensile strength and modulus properties. Alternatively, the solvent fractionation or separation is conducted under supercritical extraction conditions to produce a metals-containing mesophase pitch. Organometallic compounds may be added to the carbonaceous feedstock either prior to or after the heat soak step.

Organometallic containing mesophase pitches for spinning into pitch

This invention relates to low melting solvated mesophase pitches which are suitable for spinning into carbon fibers. The solvated mesophase pitches have a lower melting point than conventional mesophase pitch but remain substantially anisotropic. The solvated mesophase can be produced as an intermediate during solvent fractionation or supercritical solvent fractionation of mesogen-containing isotropic pitches. The process is enhanced through the ability to recover pseudomesogens with an increased average molecular weight which, in combination with the solvent content, provides a fusible mesophase capable of being spun directly into infusible oriented anisotropic carbon fibers.

Solvated mesophase pitches

This invention provides a process for preparing a solvated isotropic pitch having a fluid temperature at least 40.degree. C. lower than the same pitch in the non-solvated state. Additionally, the present invention provides a solvated isotropic pitch which may be formed into carbon artifacts which do not require oxidative stabilization prior to carbonization.

Self-stabilizing pitch for carbon fiber manufacture

The present invention provides a process for obtaining a very clean mesophase pitch from isotropic pitch. This invention utilizes a solvent fractionation process which does not involve the process steps, yield loss and waste generation associated with fluxing and filtering the isotropic pitch. Additionally, this invention provides a liquid/liquid extraction process that avoids the solids handling and the high temperatures and pressures of supercritical fluid extraction. Finally, this invention controls the hardness of the mesophase product.

Process for isolating mesophase pitch

This invention relates to a process for producing mesophase pitch in high yields. The process of the invention comprises isolating a heavy fraction of a heat soaked pitch by a solvent extraction, heat soaking the isolated heavy fraction to increase the size and number of larger heavy aromatics, and isolating the larger heavy aromatics by solvent extraction to obtain a larger heavy aromatic solvated mesophase pitch.

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Ponca City, OK, United States of America

H Ernest Romine