Sk on Co., Ltd.

Gwi Ok Park

Sun Young Kim

Jik Soo Kim

Ju Ho Chung

Eun Jun Park

Seok Keun Yoo

Joon-Sup Kim

Dong Il Jang

In Ae Lee

Hyo Shik Kil

Hansu Kim

Eunjun Park

Donghan Youn

Dong Jae Chung

Dong Gun Lee

Joon Sup Kim

Suk Chin Lee

Min Kyung Seon

Jeongbae Yoon

Jun Soo Son

Ji Sang Jeong

Joon Hyung Moon

Provided are a negative electrode active material which includes negative electrode active material particles which includes a silicon oxide (SiO, 0<x≤2); and at least one lithium silicate selected from LiSiO, LiSiO, and LiSiOin at least a part of the silicon oxide. A signal generated in a region of 200 to 600 cmaccording to a Raman spectrum is subjected to deconvolution into three peaks, which are set to peak A, peak B, and peak C from lowest to highest of an absolute value of a wavenumber. Also disclosed are a method of preparing the same, and a negative electrode and a lithium secondary battery including the negative electrode active material.

Lithium-doped silicon-based oxide negative electrode active material, method of preparing the same, and negative electrode and secondary battery including the same

Provided are a negative electrode for a lithium secondary battery and a method of manufacturing the same. The negative electrode for a lithium secondary battery according to an embodiment of the present invention includes a silicon-based material doped with lithium having a content A, iron having a content B, and aluminum having a content C,

Negative electrode for lithium secondary battery and method of manufacturing the same

Provided are a binder composition for a secondary battery, a negative electrode including the same, and a secondary battery including the same. More particularly, the binder composition for a secondary battery having a three-dimensional structure, which is prepared by mixing a copolymer having specific repeating units and a polymer-type additive containing nitrogen (N) bonded to two or three carbons (C) in the repeating unit, has excellent mechanical properties and may effectively improve a binding force. The negative electrode and the secondary battery including the binder composition for a secondary battery effectively suppress expansion of a negative electrode to manufacture a secondary battery having excellent charge/discharge cycle characteristics and battery performance.

Binder composition for secondary battery, negative electrode for secondary battery including the same, and lithium secondary battery including the same

An anode active material for a lithium secondary battery includes a carbon-based particle including pores therein, a silicon-containing coating layer formed at an inside the pores of the carbon-based particle or on a surface of the carbon-based particle, and a carbon coating layer formed on the silicon-containing coating layer. A full width at half maximum (FWHM) of an O1s peak of a surface measured by an X-ray photoelectron spectroscopy (XPS) is 2.0 or more. A lithium secondary battery including the anode active material having improved initial discharge capacity and capacity efficiency is provided.

Anode active material for lithium secondary battery and lithium secondary battery including the same

The present invention relates to a binder for an anode for a secondary battery, an anode including the binder, and a secondary battery including the anode. More particularly, the present invention relates to a binder for an anode for a secondary battery that has excellent heat resistance and mechanical properties and an improved binding force because a copolymer is used for the binder, and an anode for a secondary battery. In addition, expansion and shrinkage of the anode may be efficiently suppressed, such that charge and discharge life characteristics and performance of the secondary battery may be improved.

Binder for anode for secondary battery, anode for secondary battery including binder, and lithium secondary battery including anode

Provided are a negative electrode for a lithium secondary battery and a method of manufacturing the same. The negative electrode for a lithium secondary battery according to an embodiment of the present invention includes a negative electrode active material including: a silicon oxide, lithium, and sodium or potassium, wherein in ICP analysis of a negative electrode active material layer including the negative electrode active material, contents of elements in the negative electrode active material layer satisfy the following Relations (1) and (2):300≤10/()≤12.0*10  (1)800≤≤140,000  (2)

Provided are a negative electrode for a lithium secondary battery and a method of manufacturing the same. The negative electrode for a lithium secondary battery according to an embodiment of the present invention includes a silicon-based negative electrode active material including iron and aluminum, wherein in ICP analysis of a negative electrode active material layer including the silicon-based negative electrode active material, contents of elements in the negative electrode active material layer satisfy the following Relations (1) to (3):/()≤4,500  (1)5≤≤1,500  (2)3≤≤1,000  (3)

Provided is a lithium secondary battery including a silicon-based anode active material for a lithium secondary battery and an anode formed using the same. The silicon-based anode active material for a lithium secondary battery according to exemplary embodiments includes a surface coated with carbon and doped with lithium. A ratio of a peak area at 102.5 eV to a total area of a peak area at 100 eV, the peak area at 102.5 eV, and a peak area at 104 eV, which appear in an Si2p spectrum when measuring by X-ray photoelectron spectroscopy (XPS), is 40% or less, thereby allowing an electrode to be stably manufactured without changing physical properties of the slurry during manufacturing the electrode. In addition, the anode active material for a secondary battery may be usefully used to manufacture a lithium secondary battery having high discharge capacity and high energy density characteristics.

Provided are a negative electrode active material which includes negative electrode active material particles which includes a silicon oxide (SiO, 0<x≤2); and at least one lithium silicate selected from LiSiO, LiSiO, and LiSiOin at least a part of the silicon oxide. The negative electrode active material particles have a maximum peak position by a Raman spectrum of more than 460 cmand less than 500 cm. Also provided are a method of preparing the same, and a negative electrode and a lithium secondary battery including the negative electrode active material.

Provided are a negative electrode active material which includes a negative electrode active material particles which includes a silicon oxide (SiO, 0<x≤2); and at least one lithium silicate selected from LiSiO, LiSiO, and LiSiOin at least a part of the silicon oxide. The negative electrode active material has a content of a nitrogen element according to X-ray photoelectron spectroscopy (XPS) of 1.45 atom % or less. Also provided are a negative electrode and a lithium secondary battery including the same.

An anode active material for a lithium secondary battery and a lithium secondary battery are provided. The anode active material includes a carbon-based particle including pores formed in at least one of an inside of the particle and a surface of the particle and having a pore size of the carbon-based particle is 20 nm or less, and silicon formed at an inside of the pores of the carbon-based particle or on the surface of the carbon-based particle. Silicon has an amorphous structure or a crystallite size of silicon measured by an XRD analysis is 7 nm or less. Difference between volume expansion ratios of carbon and silicon can be reduced to improve life-span property of the secondary battery.

Anode active material for lithium secondary battery, method of forming the same and lithium secondary battery including the same

According to embodiments of the present invention, there is provided an anode active material for a lithium secondary battery including a silicon oxide which includes a carbon coating layer on a surface thereof and is doped with magnesium. A ratio of peak area at 1303 eV to a sum of a peak area at 1304.5 eV and a peak area at 1303 eV, which appear in a Mg1s spectrum when measuring by X-ray photoelectron spectroscopy (XPS), is 60% or less.

Anode active material for lithium secondary battery, anode active material slurry and lithium secondary battery including the same

An anode active material for a lithium secondary battery and a lithium secondary battery are provided. The anode active material includes a carbon-based particle including pores formed in at least one of an inside of the particle and a surface of the particle and having a pore size of the carbon-based particle is 20 nm or less, and silicon formed at an inside of the pores of the carbon-based particle or on the surface of the carbon-based particle. A peak intensity ratio in a Raman spectrum of silicon defined as I(515)/I(480) is 1.2 or less. Difference between volume expansion ratios of carbon and silicon can be reduced to improve life-span property of the secondary battery.

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Daejeon, South Korea

Gwi Ok Park