Dynamit Nobel Aktiengesellschaft

Huls Aktiengesellschaft

Huels Aktiengesellschaft

Huels Troisdorf Ag

Gunther Bernhardt

Margret Haas

Heinz Kragl

Horst Hanisch

Gerhard Daum

Jurgen Amort

Werner Trautvetter

Gerald L Larson

Klaus-Dieter Steffen

Rudeger Minke

Egon-Norbert Petersen

Pyridinium salts of the formula ##STR1## are prepared. The compounds are useful as phase transfer catalysts for the preparation of methacryloyloxyalkylalkoxysilanes and acryloyloxyalkylalkoxysilanes.

Pyridinium salts containing alkoxysilyl groups

A quaternary pyridinium halide is used as the phase transfer catalyst in a process for the preparation of an organosilane containing methacryloyloxy or acryloyloxy groups by reacting an alkali metal methacrylate or alkali metal acrylate with a chloroalkylsilane.

Process for the preparation of organosilanes containing methacryloyloxy

The present invention is in the preparation of methacrylic or acryloxyalkylalkoxysilanes by the reaction at a temperature of from 80.degree. and 130.degree. C. of an alkali (meth) acrylate with a halogen alkylalkoxysilane in the presence of a quaternary ammonium salt which has long-chin alkyl moieties, in which the sum of all carbon atoms is between 10 and 40 as a phase-transfer catalyst. In the new procedure no solvents need to be used. The yields are better than 95%.

Method for the preparation of organosilanes containing methacryloxy or

Organosilanes comprising methacryloxy groups or acryloxy groups are stabilized with a mixture consisting of at least one N,N'-di-substituted-p-phenylenediamine and at least one substituted phenol, which yields products with high purity and high yields.

Process for stabilizing organosilanes containing methacryloxy or

Disclosed are casting resins made from acrylic acid esters with a high content of finely dispersed fillers. The casting resins contain a polymeric organosilicon compound having functional and nonfunctional groups. As functional groups, the copolymer contains one or more alkoxysilyl groups and one or more (meth)acryloxysilyl groups. The copolymer furthermore contains by copolymerization at least one nonfunctional comonomer having an ethylenically unsaturated grouping as well as an additional comonomer of the group of the vinyl carboxylic acid esters and (meth)acrylic acid esters, if desired. The addition of these polymeric organosilanes to known casting resins brings about a greater lowering of the viscosity of these resins, which are used, for example, for the manufacture of sanitary appliances.

Casting resins on the basis of acrylic acid esters

The present invention relates to copolymers which can be used as adhesion mediating agents (adhesivers) between polymers and inorganic-oxide material. They are characterized by a reactive alkoxysilyl group and an acrylic or methacrylic acid moiety. Each of these two groups is linked to a fundamental constituent having two chain carbon atoms, this fundamental constituent being constructed on a compound having an ethylenically unsaturated group as monomer. The ratio of the alkoxysilyl groups to the acrylic or methacrylic acid esters in the new copolymers can be established as desired, for example by copolymerizing the copolymers with other compounds having ethylenically unsaturated groups, which do not have the above-named moieties. The present invention also relates to a method of preparing these new copolymers as well as intermediates which occur in the practice of this method, as formerly unknown products.

Adhesivizing agent copolymers containing both acrylate or methacrylate

A process for the preparation of Benzaldehydes substituted in the nucleus is disclosed by oxidation of the corresponding benzyl halides. The process is performed in the presence of water using aminoxides of tertiary amines.

Method of preparing substituted benzaldehydes

A method for preparing benzyl alcohols or substituted benzyl alcohols is disclosed by decarbonylation of formic acid esters of benzyl alcohols or ring substituted benzyl alcohols, the decarbonylation being carried out in the presence of a catalyst.

Method of preparing benzyl alcohols by decarbonylation of formic acid

There is described an essentially two step process for the preparation of benzylalcohols including those benzylalcohols having substituents on the benzyene ring by reaction of a substituted or unsubstituted benzyl halide with a formate typically an alkali or alkaline earth metal formate to form the corresponding substituted or unsubstituted benzyl formate. In the second step of the process the benzyl formate is contacted with an alcohol whereby the same is converted into the desired benzylalcohol. Both steps can be performed employing catalysts. Described in the specification is the realization of the desired product in exceptionally high yields in a short period of time whereby the process is characterized by high space-time yields.

Process for preparing benzylalcohols

A process for the preparation of a terephthalic, isophthalic or phthalic dialdehyde is described by dehydrogenation of the corresponding xylylene glycol in the vapor phase at 250.degree. to 500.degree. C. The process is carried out in the presence of oxygen, water vapor and a dehydrogenation catalyst, suitably a silver dehydrogenation catalyst.

Process for the preparation of terephthalic, isophthalic and phthalic

A method of deacetylation of ethylene-vinyl acetate copolymers to produce the corresponding olefinicaly unsaturated, linear polymers. The ethylene-vinyl acetate copolymers are deacetylated under a vacuum of less than about 50 Torr, by splitting acetic acid from the copolymers, and while continuously stirring the copolymers.

Unsaturated ethylene-vinyl acetate copolymers and unsaturated

Vinyl chloride copolymers of vinyl chloride and a comonomer of the formula ##EQU1## wherein Z contains an alkenyl group and X and Y are H or other substituents. The copolymers can be cross linked to form shaped articles of improved elongation and tenacity.

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St. Augustin, Germany

Gunther Bernhardt