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Henkel Kommanditgesellschaft

Hansawerke Lurmann, Schutte & Co.

Gunter Beer

Wolfgang Pesch

Wolfgang Friedemann

Manfred Kupfer

A binder composition for coatings, adhesives, and the like is afforded comprising an aqueous mixture of at least one alkali silicate and at least one maleic acid anhydride ethylene or methylvinyl ether copolymer.

Binder compositions based on alkali metal silicate solutions

A method for the production of a more water-resistant foamed element from waterglass consisting essentially of the steps of mixing together a major amount of an alkali metal silicate solution, with inorganic fillers, at least one alkali-resistant wetting agent in an amount sufficient to form a stable foam, at least one compound capable of hardening a waterglass foam in an amount sufficient to cause said alkali metal silicate to harden, and sufficient natural latex dispersion to cause the foamed element to have a greater water resistance, mechanically foaming said mixture by the incorporation of an inert gas thereon, filling the resultant foam into an element form capable of disassembly, curing said foam in said form, and recovering a more water-resistant foamed and cured element. Preferably the natural latex dispersion is employed in a 50% dispersion in an amount of from 0.2% to 30% by weight, preferably from 0.2% to 10% by weight, based on the total mixture. The alkali metal silicate solution used has, in the case of sodium silicate, a solids content of about 27% to 43% by weight at an SiO.sub.2 /Na.sub.2 O molar ratio of about 4 : 1 to 3 : 1 and in the case of potassium silicate a solids content of about 20% to 36% by weight at an SiO.sub.2 /K.sub.2 O molar ratio of about 4 : 1 to 3.4 : 1, it being possible to use any desired mixture ratios of the mentioned alkali metal silicates. The mixture may optionally contain an addition of 0.1% to 2.5% by weight, preferably from 1% to 2% by weight of B.sub.2 O.sub.3. Preferably the wetting agent added to the mixture is an anionic tenside, such as a sodium C.sub.14-16 alkylsulfonate, in an amount of from 0.1% to 10% by weight, preferably from 4% to 6% by weight in the form of a 30% aqueous solution. The fillers to be added to the mixture are inorganic compounds of light specific gravity in a grain size up to 0.1 mm and in an amount of up to 50% by weight, preferably from 10% to 20% by weight. The hardeners are preferably proportioned into the mixture during foaming in amounts of from 1% to 10% by weight, preferably from 2% to 6% by weight. The preferred hardener is glycerine triacetate.

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Duisburg, Germany

Gunter Beer