Canadian Liquid Air Limited

Canadian Liquid Air Ltd - Air Liquidecanada Ltee

Guillermo F Garrido

Robert G Lee

Derek Hornsey

Jose M Dieguez

Olivier Francois

Oil is recovered from an underground formation by the use of steam and a gas rich in oxygen. In a priming stage, high quality saturated steam or superheated steam is injected into the formation to raise the reservoir temperature, in the vicinity of injection, to the combustion temperature of the oil. Then, in a combustion stage, the injection of steam is continued and oxygen-containing gas is injected as well, so that local combustion of oil occurs. This results in further heating of the steam and the generation of hot combustion gases, increasing the mobility of the oil and creating pressure drive. The priming and combustion stages may be part of a cyclic steam stimulation ('huff and puff') method or a steam flooding method. Special expedients are provided for the safe use of oxygen and steam.

Process and device for oil recovery using steam and oxygen-containing gas

The invention is concerned with a substantially nitrogen-free process for chloride-route TiO.sub.2 pigment manufacture in which a TiO.sub.2 -containing feedstock is subjected to a fluidized-bed, high temperature carbochlorination in a chlorinator to produce TiCl.sub.4 which is thereafter converted to TiO.sub.2 by oxidation. The TiO.sub.2 -containing feedstock and a solid carbonaceous reducing agent are fed to the chlorinator under a CO.sub.2 blanketing atmosphere such that the carbochlorination is carried out in a substantially nitrogen-free atmosphere containing CO.sub.2 and a CO.sub.2 -rich flue gas is generated, the CO.sub.2 in the chlorinator assisting in controlling thermal balance of the carbochlorination reaction. The absence of significant concentrations of nitrogen in the flue gas results in a favorable condition enabling either or both the CO and CO.sub.2 contained in the flue gas to be readily recovered, purified and sold as by-products.

Nitrogen-free process for chloride-route TiO.sub.2 pigment manufacture

In a steam generating boiler having a bottom wall supporting a char bed and sidewalls with ports through which air is admitted for combustion of combustible species in the char bed and emanating therefrom, combustion is improved by introducing an oxygen-containing gas into a lower central zone of the boiler, from at least one point remote from the sidewalls to thereby cause intimate mixing of the oxygen contained in the gas with the combustible species.

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St-Bruno, Canada

Guillermo F Garrido