Basf Aktiengesellschaft

Guenter Heil

Werner Lenz

August Lehner

Werner Balz

Jenoe Kovacs

Helmut Barzynski

Heinrich Hartmann

Werner Grau

Gunnar Schornick

Rolf Osterloh

Albert Kohl

Lutz Goethlich

Dieter Lautenbach

Hartmut Hibst

Martin Fischer

Andreas Henne

Hermann Roller

Joachim Hack

Anton Hesse

Herbert Spoor

Guenther Schulz

Michael Bobrich

Uwe Keppeler

Hellmut Kast

Ingolf Buethe

Werner Kuesters

Arend Werner

Rudolf Bachmann

Norbert Holl

Michael Hitzfeld

Manfred Eisert

Heinrich Mannsperger

Karl Klemm

Helfrid Sander

Magnetic recording media consist of a nonmagnetic substrate and at least one magnetizable layer which is applied firmly thereon and is based on a polyurethane binder, not less than 50% by weight of binder consisting of a branched polyurethane elastomer having urea groups at the chain ends.

Magnetic recording medium containing an isocyanate-free branched

Disk-shaped magnetic recording media essentially consisting of a flexible substrate, a thin ferromagnetic metal film applied to one or both sides and a protective or antifriction layer present on this metal film and essentially consisting of carbon, a process for the production of these recording media and information stores containing these recording media.

Disk-shaped magnetic recording media, their production and information

Layer-type magnetic recording media are produced by dispersing a finely divided magnetically anisotropic material in a binder which consists of not less than 30% of a radiation-curable aqueous binder dispersion, applying the dispersion onto a non-magnetic base, orienting the magnetically anisotropic material and drying and crosslinking the applied layer by means of UV or high-energy electron radiation.

Production of layer-type magnetic recording media

Layer-type magnetic recording media are produced by dispersing a finely divided magnetically anisotropic material in a binder which consists of not less than 40% of a radiation-curable aqueous binder dispersion, applying the dispersion onto a non-magnetic base, orienting the magnetically anisotropic material and drying and crosslinking the applied layer by means of UV or high-energy electron radiation.

Magnetic recording media comprise a non-magnetic base and one or more magnetic layers consisting of an organic binder matrix containing finely divided magnetic material, the said binder matrix being obtained by electron beam curing of a mixture of from 60 to 100% by weight of a polyurethane acrylate polymer possessing polymerizable acrylate double bonds and from 0 to 40% by weight of an acrylate monomer and/or an acrylate prepolymer and/or an N-vinyl monomer.

Magnetic recording media

Magnetic recording media comprising a non-magnetic substrate and a magnetic layer comprising a finely divided magnetic material dispersed in an organic solvent soluble, crosslinkable, essentially linear, thermoplastic polyurethane which possesses acrylate side and terminal groups wherein said polyurethane is prepared by reacting poly- and/or diisocyanates with a mixture of (a) methacrylate - or acrylate - diols having molecular weights of from 146 to 3,000, (b) monoesters of methacrylic or acrylic acid and a diol having a molecular weight of from 116 to 300, and (c) other organic polydiol compounds which have molecular weights of from 400 to 5,000.

Magnetic recording media comprise a non-magnetic base and one or more magnetic layers consisting of an organic binder matrix containing finely divided magnetic material, the said matrix being obtained by electron beam curing of a mixture of from 70 to 90% by weight of a polyurethane acrylate polymer possessing polymerizable double bonds and from 10 to 30% by weight of one or more copolymerizable compounds.

Magnetic recording media comprise a non-magnetic base and one or more magnetic layers consisting of an organic binder matrix containing finely divided magnetic material, the said matrix being obtained by electron beam curing of a mixture of from 50 to 100% by weight of a polyurethane acrylate polymer possessing polymerizable double bonds and from 0 to 50% by weight of an acrylate and/or an acrylate prepolymer and/or an N-vinyl monomer and/or an N-vinyl prepolymer.

Magnetic recording media comprising a non-magnetic base and one or more magnetic layers consisting of an organic binder matrix containing finely divided magnetic material, the said matrix being obtained by electron beam curing of a mixture of from 60 to 100% by weight of a polyurethane acrylate polymer possessing polymerizable double bonds and from 0 to 40% by weight of an acrylate and/or an acrylate prepolymer and/or an N-vinyl monomer and/or an N-vinyl prepolymer.

Acylphosphine sulfides of the formula ##STR1## where R.sup.1 is alkyl, cycloalkyl or an unsubstituted or substituted phenyl, naphthyl or heterocyclic radical; R.sup.2 has the meaning of R.sup.1 and can be identical to or different from R.sup.1, or is alkoxy, unsubstituted or substituted phenoxy or phenoxyalkyl, or R.sup.1 or R.sup.2 are linked together to form a ring, which may contain further alkyl substituents and fused-on benzene rings; R.sup.3 is alkyl, a cycloaliphatic radical, substituted phenyl, an unsubstituted or substituted naphthyl or heterocyclic radical or the group ##STR2## where X is unsubstituted or substituted phenylene or an aliphatic or cycloaliphatic divalent radical; and where one or more of R.sup.1, R.sup.2 and R.sup.3 may be olefinically unsaturated. These acylphosphine sulfides can be prepared from acylphosphines and sulfur and can be used as photoinitiators in photopolymerizable compositions.

Photopolymerizable composition with acylphosphine sulfide photoinitiator

Curable coating compositions of olefinically unsaturated compounds A and an N-vinyl compound B. The N-vinyl compounds carry at least 2 N-vinyl groups and at least one carbonyl group bonded to the nitrogen of the N-vinyl group. The coating compositions can be used for the manufacture of paints, printing inks, printing plates and photoresist materials.

Curable coating composition

A process for the preparation of polymerizable, primarily linear thermoplastic polyurethane elastomers with acrylate side groups comprising reacting an organic polyisocyanate with a mixture of

Process for the preparation of polymerizable polyurethane elastomers

Photopolymerizable binders for printing inks, coatings and printing plates, based on olefinically unsaturated compounds, with or without a polymeric binder component, and containing a diaminobenzophenone compound as the photosensitizer, are improved in respect of their toxicity and shelf life if the diaminobenzophenone compound has the formula R.sup.1 R.sup.2 N--C.sub.6 H.sub.4 --CO--C.sub.6 H.sub.4 --NR.sup.3 R.sup.4, where R.sup.1 and R.sup.3 are H(OR.sup.5).sub.x radicals, R.sup.5 being alkylene of 2 or 3 carbon atoms and x being 1, 2 or 3, and R.sup.2 and R.sup.4 are each alkyl of 1 to 4 carbon atoms or are radicals of the type of R.sup.1 and R.sup.3.

Photopolymerizable binders containing diaminobenzophenones

Photopolymerizable binders for UV-curing printing inks and coating compositions, which contain benzophenone-based photoinitiators and photosensitizers including p-dimethylaminobenzaldehyde and esters of p-dimethylaminobenzoic acid.

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Ludwigshafen, Germany

Guenter Heil