Chevron U.s.a. Inc.

Oerlikon Metco (us) Inc.

Scoperta, Inc.

Grzegorz Jan Kusinski

Thomas M Devine

Justin Lee Cheney

Jan H Kusinski

Alexander F Zazovsky

Seth Thomas Taylor

Toni Zhang Miao

Edwin Hall Niccolls

Luis Phillipe Costa Ferreira Tosi

David Lawrence Cooke

Michael Tung-hai Cheng

Monica Michele Barney

Andres Zoldi

Leslie Douglas Munson

Compositions are provided that exhibit an austenitic nickel microstructure. The compositions comprise Ni, Cr, Mo and at least one element selected from the group consisting of Al, Si, and Ti. Feedstock having the composition may be in the form of a cored wire or wires, a solid wire or wires, or a powder.

Coating compositions

A system for characterizing and optimizing refinery feedstock blends according to their corrosivity is provided. Refinery feedstocks can be characterized based on any of: dissociation of acids in the crude, breakup of naphthenic acid molecular associations, mass changes of carbon steel samples, and/or dissociation of sulfur compounds in the feedstocks. The characterization can be carried out via any of impedance, spectroscopic measurements, and continuous measurements of mass changes of carbon steel samples with a crystal microbalance over a range of temperature, e.g., from ambient to 750&#xb0; F. The system can be employed in any of refinery, terminal, and laboratories, using models and/or hardware to optimize the usage of refinery feedstocks in the blending and valuation of the feedstocks.

Processes and systems for characterizing and blending refinery feedstocks

A method for forming structural equipment employed in sulfur containing environments such as oil refineries and the like. In one embodiment, the method comprises: providing a steel composition containing up to 0.35% of C, 0.30 to 3.5% Si, up to 1.2% Mo, up to 1.35% Mn, up to 5% Al, less than 12.0% Cr, balance of Fe and unavoidable impurities; forming a structural component conforming to prevailing industry standards with respect to design, fabrication, inspection and testing, metallurgical and mechanical properties. The structural equipment has a corrosion rate of less than 15 mpy. In one embodiment, the equipment is formed from a steel composition has a carbon equivalent of less than 0.63, requiring no post weld heat treatment ('PWHT'). In another embodiment, the CE is less than 0.45, requiring no preheat nor PWHT.

Equipment for use in corrosive environments and methods for forming thereof

A method for characterizing and optimizing refinery feedstock blends according to their corrosivity is provided. Refinery feedstocks can be characterized based on any of: dissociation of acids in the crude, breakup of naphthenic acid molecular associations, mass changes of carbon steel samples, and/or dissociation of sulfur compounds in the feedstocks. The characterization is performed as a function of temperature via any of electrical resistivity measurement, vibrational spectroscopic analysis, voltammetry, electrochemical impedance spectroscopy, crystal microbalance measurements of weight changes, and combinations thereof. The method employs models and/or hardware to optimize the usage of refinery feedstocks in the blending and valuation of the feedstocks.

Equipment having a protective coating layer for use in abrasive environments, e.g., sulfur-containing environments, is disclosed. The coating is formed from a single-component feedstock, as a Fe-based alloy composition comprising at least two refractory elements selected from Cr, V, Nb, Mo and W in an amount of up to 30% each and a total concentration of up to 40%. In one embodiment, the coating is applied by thermal spraying, followed by heat treatment for at least a portion of the refractory elements in the coating to fuse into the substrate forming a metallurgically bonded coating. The coating has an adhesion strength of at least 7,000 psi measured according to ASTM D4541. The coating layer is further characterized as being impermeable to corrosive environments showing no pin holes in the ferroxyl test according to ASTM A967 Practice E.

Coating compositions, applications thereof, and methods of forming

A tubular pipe adapted for transporting oil and water may be treated upon its interior surface to reduce frictional pressure of a multiphase oil/water mixture flowing through the pipe. The tubular pipe may have an interior wall and a central cavity. In some instances, the interior surface is provided with a first textured region being adapted for reducing the adhesive forces of transported oil along the interior wall. A second region upon the interior wall may be adapted for reducing the adhesive forces of water along the interior wall of the tubular pipe. In some applications, riblets may be provided upon the interior pipe wall to further reduce the frictional forces of fluid flowing through the central cavity of the pipe.

Method and apparatus for reducing fluid flow friction in a pipe

A method for characterizing refinery feedstocks according to their corrosivity is provided. The characterization is based on any of: dissociation of acids in the crude, breakup of naphthenic acid molecular associations, and/or dissociation of sulfur compounds in the feedstocks. In one embodiment, the characterization is done via vibrational spectroscopic measurements over a range of temperature, e.g., from ambient to 700&#xb0; F. The method can be practiced in any of refinery, terminal, and laboratories. It can be used in conjunction with models and hardware to optimize the usage of refinery feedstocks in the blending and valuation of the feedstocks.

Process for characterizing corrosivity of refinery feedstocks

Refinery feedstocks can be characterized based on any of: dissociation of acids in the crude, breakup of naphthenic acid molecular associations, and/or dissociation of sulfur compounds in the feedstocks. The characterization is performed as a function of temperature via any of electrical resistivity measurement, vibrational spectroscopic analysis, voltammetry, electrochemical impedance spectroscopy (EIS) and combinations thereof. The method can be practiced in any of refinery, terminal, and laboratories. It can be used in conjunction with models and hardware to optimize the usage of refinery feedstocks in the blending and valuation of the feedstocks. In one embodiment, the characterization of refinery feedstocks is via the use of EIS.

A method for determining corrosiveness of naphthenic acid in a crude oil feedstock is provided. The method includes the steps of providing a crude oil feedstock containing naphthenic acid; contacting the crude oil feedstock with iron for a period of time at a sufficient temperature for the iron to react with the naphthenic acid, forming iron salts. Under sufficiently high temperatures, at least a portion of the iron salts decompose to form ketone, which can be quantified. Measurements of the ketone can be used to correlate with the amount of iron lost from corrosion given a certain level of naphthenic acid present, giving a measure of the corrosivity of crude oil feedstock.

Methods for evaluating corrosivity of crude oil feedstocks

A method to improve corrosion, abrasion, resistance to environmental degradation and fire resistant properties of structural components for use in oil, gas, exploration, refining and petrochemical applications is provided. The structural component is suitable for use as refinery and/or petrochemical process equipment and piping, having a substrate coated with a surface-treated amorphous metal layer. The surface of the structural component is surface treated with an energy source to cause a diffusion of at least a portion of the amorphous metal layer and at least a portion of the substrate, forming a diffusion layer disposed on a substrate. The diffusion layer has a negative hardness profile with the hardness increasing from the diffusion surface in contact with the substrate to the surface away from the substrate.

Surface treatment of amorphous coatings

A structural component suitable for use as refinery and/or petrochemical process equipment and piping is provided. The structural component has improved corrosion, abrasion, environmental degradation resistance, and fire resistant properties with a substrate coated with a surface-treated amorphous metal layer. The surface of the structural component is surface treated with an energy source to cause a diffusion of at least a portion of the amorphous metal layer and at least a portion of the substrate, forming a diffusion layer disposed on a substrate. The diffusion layer has a negative hardness profile with the hardness increasing from the diffusion surface in contact with the substrate to the surface away from the substrate.

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Moraga, CA, United States of America

Grzegorz Jan Kusinski