Allied Corporation

Monsanto Company

Alliedsignal Inc.

Allied Chemical Corporation

Granville G Miller

Ray H Baughman

Ronald L Elsenbaumer

Lawrence W Shacklette

Ronald Richard Chance

Gordhanbhai N Patel

Anthony F Preziosi

Kwok C Yee

Dawn M Ivory

Bernhard M Wessling

Helmut Eckhardt

Chien-Chung Han

Vaman G Kulkarni

James E Toth

Jane E Frommer

James F Wolf

Peter Whang

Zafar Iqbal

MacRae Maxfield

Philippe G Delannoy

Bernhard M WeBling

Bernhard Weszling

An electrically conductive conjugated polymer particle comprising an ionized electrically conductive substituted or unsubstituted conjugated polymer doped with one or more dopant solutes having one or more anionic moieties at least one of said dopants predominating at or near the surface of said particle having at least one aliphatic chain of at least 3 carbon atoms wherein the sum of such chains contain at least 12 aliphatic carbon atoms when an anionic functionality is bonded directly to an aromatic moiety and at least about 6 carbon atoms when the anionic functionality is bonded directly to an aliphatic moiety.

Surface dopants as blend compatibilizers in conjugated polymers

This invention relates to an improved anti-corrosion paint of the type comprising one or more polymeric binders dispersed in a liquid medium, said improvement comprising an anti-corrosion effective amount of one or more non-conductive conjugated polymers.

Corrosion resistant paint

A electrically conductive polyaniline particle comprising a substituted or unsubstituted polyaniline doped with two or more dopants, at least one of said dopants predominating at or near the surface of said particles and at least one other dopant predominating at or near the core of said particle.

Polyaniline compositions having a surface/core dopant arrangement

A method is provided for decreasing radiative heat transfer and adjustably limiting visible light and near infrared radiation transfer and glare through a window. The method comprises the steps of: (a) mounting within a frame of the window a plurality of spaced window panes, a first and second of the panes having opposing faces; (b) assembling between the opposing faces a conductive polymer cell, the cell having a first wall composed of a transparent conductive layer affixed to the first pane and having deposited thereupon an electroactive electro-optically responsive conductive polymer, and a second wall comprised of a transparent conductive layer coated on the second pane, the layer being optionally coated with a second electro-optically responsive polymer, the first and second walls delimiting a cavity containing an ion-conducting electrolyte which contacts opposing surfaces of the first and second walls, and (c) applying a potential between the first and second walls to provide a selected light transmittance upon passage of current therebetween.

Adjustable tint window with electrochromic conductive polymer

A device for monitoring environmental exposure includes an element whose electrical properties change, in a predetermined way, in response to the environmental exposure. The element may be part of a tuned circuit or of a shield for a tuned circuit. In either case, when the tuned circuit is interrogated, preferably by an r.f. or microwave signal, it emits a signal whose intensity depends on the electrical properties of the element. Thus, an incremental environmental exposure can be measured by a change in the signal intensity. The device is particularly useful for monitoring the condition of perishable materials, because it can be located with the perishable inside a packaging material during both storage and interrogation.

Environmental indicator device and method

Conjugated backbone polymers (e.g., polyacetylene), especially formed into a battery electrode, are contacted with a compound MR where M is an alkali metal and R is alkyl of 1-12 carbons, phenyl or alkylphenyl of 7-12 carbons. The method is particularly suited to treatment of battery electrodes to avoid a high initial internal resistance.

Method of forming battery electrode by irreversible donor doping of

Irreversible donor doping of conjugated backbone polymers

Electrically conducting doped poly(paraphenylene) compositions, and process of making such compositions, having direct current conductivities of at least 10.sup.31 3 ohm.sup.-1 cm.sup.-1, at room temperature, and up to 100 ohm.sup.-1 cm.sup.-1 and above; especially wherein the doping agent is a Group IA metal arene, a Group V halide, chlorine, bromine, or a mixture thereof; in particular potassium naphthalene, sodium naphthalene, AsF.sub.5, chlorine, or a mixture thereof. The polymers are useful as electronic devices, as substrates for electroplating, as materials for absorption of solar and of radio frequency radiation, and in general wherever electrical conductivity of the metallic type or of the semiconductor type, and light weight, are desired.

Electrically conducting compositions of doped polyphenylenes and shaped

Polyacetylene doped with potassium or rubidium cations (and optionally with other alkali metal cations) is heat treated at 60.degree.-400.degree. C., preferably 100.degree.-250 .degree. C., to achieve greatly enhanced room temperature conductivity. Products with relative conductivities 150%, 300%, 450% or more of the conductivity prior to heat treating are obtained, with room-temperature conductivities of 300 S/cm, 450 S/cm, or higher.

Enhancing conductivity of donor-doped polyacetylene

Rechargable battery with a conjugated backbone polymer anode which has been coated, when in the reduced state, by contact with a monomer with a reactive oxirane group. Reduced polyacetylene anodes, after reaction with ethylene oxide, offer improved stability to solvents.

Battery having polymeric anode coated with reaction product of oxirane

A polymer solution is formed from a sulfur- or oxygen-containing aromatic polymer solute such as poly(phenylene sulfide) or poly(phenylene oxide), a Lewis Acid solute derivative (dopant) such as arsenic hexafluoride and a strong acid solvent such as sulfuric acid. Solvents such as fluorosulfonic acid may also serve to generate the dopant. The solutions are especially useful for casting polymer articles.

Solution of a chalcogen-containing polymer in acids and process of

Electrically conducting doped poly(paraphenylene) compositions, and process of making such compositions, having direct current conductivities of at least 10.sup.-3 ohm.sup.-1 cm.sup.-1, at room temperature, and up to 100 ohm.sup.1 cm.sup.-1 and above; especially wherein the doping agent is a Group IA metal arene, a Group V halide, chlorine, bromine, or a mixture thereof; in particular potassium naphthalene, sodium naphthalene, AsF.sub.5, chlorine, or a mixture thereof. The polymers are useful as electronic devices, as substrates for electroplating, as materials for absorption of solar and of radio frequency radiation, and in general wherever electrical conductivity of the metallic type or of the semiconductor type, and light weight, are desired.

A recording device is described, useful as an integrated time-temperature or radiation-dosage history indicator. The device contains a substrate having deposited thereon at least two indicating units, one being unreacted and representing zero time of exposure and the other unit being pre-reacted. Each unit is comprised of an acetylenic compound containing at least one --C.tbd.C--C.tbd.C-- group, capable of reacting by 1,4-addition polymerization thereby forming an end-point color after an irreversible, progressive color change upon thermal annealing or exposure to actinic radiation. The end-point color represents an integrated time-temperature history of thermal annealing or radiation-dosage history. Each unit is constructed such that the time required to form the end-point color by thermal annealing at a given temperature or for a known thermal history, or exposure to actinic radiation at a given average radiation dosage rate, is predetermined. A process is also described for using the device as well as an article having the device affixed thereto.

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Morristown, NJ, United States of America

Granville G Miller